Probe for measuring chlorine dioxide by adopting spectrum

By designing a spectral probe for chlorine dioxide solution and directly inserting it into the solution for spectral measurement, the existing detection methods are solved, and the existing detection methods are inefficient and complicated, achieving rapid and accurate concentration detection and avoiding solution contamination.

CN222599510UActive Publication Date: 2025-03-11NANJING PRECISION INT CORP
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Patent Information

Application Number
CN202421012413.7
Authority / Receiving Office
CN · China
Patent Type
Utility models(China)
Current Assignee / Owner
Filing Date
2024-05-11
Publication Date
2025-03-11
Estimated Expiration
2034-05-11

AI Technical Summary

Technical Problem

The existing chlorine dioxide concentration detection methods are inefficient and complicated, and there is a risk of solution contamination.

Method used

A probe is designed using spectral technology. By inserting the probe directly into the chlorine dioxide solution, and spectral measurements are performed using a light source and a detector to achieve rapid and accurate concentration detection.

Benefits of technology

It improves the efficiency of chlorine dioxide concentration detection, simplifies the operation process, avoids solution contamination, and at the same time, the device structure is simple and installation is convenient.

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Abstract

The utility model relates to the technical field of chlorine dioxide concentration detection, in particular to a probe for measuring chlorine dioxide by adopting a spectrum, which comprises a first mounting seat and a second mounting seat, the inner side of the first mounting seat is provided with a mounting groove and is embedded with a light source body, and the outer side of the first mounting seat is provided with a connecting frame in a threaded manner; the top of the connecting frame is fixedly connected with the bottom of a second mounting seat, a mounting groove is formed in the inner side of the second mounting seat, a detector body is embedded in the mounting groove, and the detector further comprises a first threading pipe and a second threading pipe; the second threading pipe is communicated with the bottom end of the light source body; the end, away from the light source body, of the second threading pipe communicates with a second wiring bin. The first threading pipe is mounted on one side of the detector body in a communicating manner; the end, away from the detector body, of the first threading pipe is provided with a first wiring bin in a communicating mode. The chlorine dioxide concentration detection device solves the problems of low efficiency and tedious use steps when the concentration of chlorine dioxide is detected at the present stage.
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Description

Technical Field

[0001] The utility model relates to the technical field of chlorine dioxide concentration detection, in particular to a probe which uses a spectrum to measure chlorine dioxide. Background Art

[0002] Chlorine dioxide (ClO2) is an oxidant and disinfectant commonly used in water treatment, wastewater treatment, food processing and disinfection. It has strong oxidizing properties and can effectively kill bacteria, viruses and other microorganisms without producing toxic byproducts.

[0003] Chinese utility model patent: Publication number CN201752653U, discloses a real-time control device for chlorine dioxide concentration, including a chlorine dioxide concentration meter, a feeding device, a liquid level meter, and a control system. The control system is respectively connected to the chlorine dioxide concentration meter, the feeding device, and the liquid level meter. The feeding device is provided with two material tanks and a valve. The two material tanks are connected to the storage tank through the valve. The chlorine dioxide concentration meter and the liquid level meter are installed in the storage tank.

[0004] In the existing technology, when CN201752653U is used, the concentration of chlorine dioxide is controlled in real time, and the concentration of chlorine dioxide is kept constant during use by adding liquid, thereby delaying the discharge time.

[0005] However, when measuring the concentration of chlorine dioxide, the detection methods currently used mostly adopt liquid chromatography, reagent method or electrochemical method. Among them, the reagent method or electrochemical method may cause pollution to chlorine dioxide when detecting the concentration of chlorine dioxide. Therefore, liquid chromatography has great advantages in detection. However, when detecting by liquid chromatography, the sample needs to be pre-treated and separated by a chromatographic column, which makes the operation more cumbersome and requires regular sampling. For this reason, a probe that uses spectroscopy to measure chlorine dioxide is proposed. By directly inserting the probe into a chlorine dioxide solution, the concentration of the chlorine dioxide solution can be detected, thereby improving the operating efficiency and avoiding the solution from being contaminated. At the same time, the device has a simple structure and is easy to operate when assembled. Utility Model Content

[0006] The utility model aims to provide a probe for measuring chlorine dioxide using a spectrum, which has the advantages of improving the efficiency of chlorine dioxide concentration detection and being easy and quick to install, and solves the problems of low efficiency and complicated use steps when performing concentration detection of chlorine dioxide at the current stage.

[0007] To achieve the above-mentioned purpose, the utility model provides the following technical solutions: a probe for measuring chlorine dioxide using a spectrum, comprising a first mounting seat and a second mounting seat, wherein the first mounting seat has a mounting groove on the inner side and a light source body is embedded and installed, a connecting frame is threadedly installed on the outer side of the first mounting seat, the top of the connecting frame is fixedly connected to the bottom of the second mounting seat, the second mounting seat has a mounting groove on the inner side and a detector body is embedded and installed, and further comprises a first threading tube and a second threading tube;

[0008] The second threading tube is connected and installed at the bottom end of the light source body;

[0009] Wherein, one end of the second threading tube away from the light source body is connected and installed with a second wiring compartment;

[0010] The first threading tube is connected and installed on one side of the detector body;

[0011] Wherein, one end of the first threading tube away from the detector body is connected and installed with a first wiring compartment;

[0012] The second wiring compartment and the first wiring compartment have matching sizes and are fixedly connected by mounting screws.

[0013] When using a probe that uses spectroscopy to measure chlorine dioxide in the technical solution, the connecting wire on the detector body is connected to the connecting wire on the light source body, and the wiring terminal is located on the opposite side of the first wiring compartment and the second wiring compartment. At this time, the first mounting seat is threadedly installed on the inner side of the connecting frame, and the first wiring compartment and the second wiring compartment are fixedly connected by installing screws, so as to protect the wiring terminal of the connecting wire. At the same time, the signal lead wire of the detector body is passed through the third threading tube and extended into the fourth threading tube. Thereafter, the signal lead wire enters the riser and is led out from the top of the riser and connected to the display device. When installing the riser, through The connector installs the vertical pipe thread on the top of the detector body, and connects and installs the third threading tube and the fourth threading tube through the installation screws. When testing the chlorine dioxide concentration, after cleaning the outside of the device, directly hold the vertical pipe to place the device in the chlorine dioxide solution. By determining the best spectral range for measuring chlorine dioxide in advance and starting the light source body, the light passes through the chlorine dioxide solution and is sensed by the detector body. At this time, a series of chlorine dioxide standard solutions with known concentrations are used to measure their absorbance using the selected detector body. A standard curve is drawn based on the measurement results to convert the absorbance of unknown samples into chlorine dioxide concentrations.

[0014] Preferably, the first mounting seat is designed with a soft rubber material, and a limiting ring is hot-melt-installed on the upper outer side of the first mounting seat, and the limiting ring is located below the connecting frame.

[0015] A limiting ring is installed by hot-melting on the outer side of the first mounting seat, so that the screwing depth of the first mounting seat in the connecting frame is limited by the limiting ring.

[0016] Preferably, the light source body is designed with UVVis light source material, a sapphire lens is provided on the top of the light source body, and the sapphire lens is embedded and installed on the top of the first mounting seat.

[0017] By arranging a sapphire lens on the top of the light source body and embedding the sapphire lens on the top of the first mounting seat, the light source body is protected without affecting the passage of ultraviolet rays.

[0018] Preferably, the connecting frame includes a connecting ring and upright poles, the upright poles are fixedly mounted on the upper surface of the connecting ring in a circular array, and the connecting ring and the upright poles are both designed with stainless steel material.

[0019] By designing the connecting ring and the vertical rod on the connecting frame to be made of stainless steel, the corrosion resistance of the connecting frame can be increased.

[0020] Preferably, the second mounting seat is designed with a soft rubber material, the outer side of the lower surface of the second mounting seat is an annular opening, and the top of the vertical rod on the connecting frame is embedded in the opening on the lower surface of the second mounting seat.

[0021] The second mounting seat can be fixedly connected to the connecting frame by embedding the top of the vertical rod on the connecting frame into the opening on the lower surface of the second mounting seat.

[0022] Preferably, the detector body has a built-in photodiode, a sapphire lens is provided at the bottom of the detector body, the sapphire lens is embedded and installed at the bottom of the second mounting seat, the top of the detector body passes through the second mounting seat and is provided with a screw hole, and a hole is opened on the other side of the detector body and is connected to and installed with a third wire threading tube.

[0023] A sapphire lens is provided at the bottom of the detector body, and the sapphire lens is embedded and installed at the bottom of the second mounting seat, so that the detector body is protected by the sapphire lens without affecting the detector body's perception of ultraviolet rays.

[0024] Preferably, a connector is threadedly installed on the top of the detector body through a screw hole, a standpipe is fixedly installed on the top of the connector, and a reserved hole is provided below the outer wall of the standpipe.

[0025] A connector is threadedly installed on the top of the detector body through a screw hole, and a standpipe is fixedly installed on the top of the connector, so that during operation, the device can be placed in a chlorine dioxide solution by holding the handle.

[0026] Preferably, one end of the third threading tube away from the detector body is connected to a fourth threading tube via a mounting screw, and one end of the fourth threading tube away from the third threading tube is connected to and installed at a reserved hole on the outer wall of the vertical pipe.

[0027] A fourth threading tube is installed on one end of the third threading tube away from the detector body through an installation screw, and one end of the fourth threading tube away from the third threading tube is installed at the reserved hole on the outer wall of the vertical pipe, so that the third threading tube and the fourth threading tube are connected, and the signal lead line on the detector body can be inserted into the vertical pipe.

[0028] Preferably, a grip ring is fixedly installed on the top of the stand pipe, and the stand pipe is designed with stainless steel material.

[0029] By fixing a grip ring on the top of the riser, the grip ring can be easily held by an operator and prevent the riser from slipping.

[0030] Preferably, the first threading tube and the second threading tube are both designed with stainless steel, connecting wires pass through the first threading tube and the second threading tube, and the connecting wire connector is located on the opposite side of the second wiring compartment and the first wiring compartment.

[0031] By arranging the connecting wire connector on the opposite side of the second wiring compartment and the first wiring compartment, the light source body and the detector body can be conveniently electrically connected during installation, and the reserved space is sufficient for connecting the lines.

[0032] Compared with the prior art, the beneficial effects of the utility model are as follows:

[0033] The utility model provides a first threading tube and a second threading tube, and the second threading tube is connected and installed at the bottom end of the light source body, and a second wiring compartment is connected and installed at the end of the second threading tube away from the light source body, and the first threading tube is connected and installed on one side of the detector body, and the first wiring compartment is connected and installed at the end of the first threading tube away from the detector body, and the second wiring compartment and the first wiring compartment are matched in size and fixedly connected by installing screws. When performing specific operations, the connecting wires on the detector body are connected with the connecting wires on the light source body, and the wiring terminals are located on the opposite sides of the first wiring compartment and the second wiring compartment. At this time, the first mounting seat is threadedly installed on the inner side of the connecting frame, and the first wiring compartment and the second wiring compartment are fixedly connected by installing screws, so as to protect the wiring terminals of the connecting wires. At the same time, the signal lead wires of the detector body are passed out from the third threading tube and extended into the fourth threading tube. The signal lead wire enters the riser and is led out from the top of the riser and connected to the display device. When installing the riser, the riser thread is installed on the top of the detector body through the connector, and the third threading tube and the fourth threading tube are connected and installed through the mounting screws. When detecting the concentration of chlorine dioxide, after cleaning the outside of the device, the riser is directly held by hand to place the device in the chlorine dioxide solution. The best spectral range for measuring chlorine dioxide is determined in advance, and the light source body is started, so that the light passes through the chlorine dioxide solution and is sensed by the detector body. At this time, a series of chlorine dioxide standard solutions with known concentrations are used to measure their absorbance using the selected detector body. A standard curve is drawn according to the measurement results to convert the absorbance of unknown samples into chlorine dioxide concentrations, thereby achieving the effect of improving the efficiency of chlorine dioxide concentration detection and convenient and quick installation. BRIEF DESCRIPTION OF THE DRAWINGS

[0034] Figure 1 This is a schematic diagram of the main structure of the utility model;

[0035] Figure 2 It is a schematic diagram of the cross-sectional structure of the utility model;

[0036] Figure 3 This is a schematic diagram of the first threading pipe connection structure of the utility model;

[0037] Figure 4 This is a schematic diagram of the connection structure of the connection frame of the utility model;

[0038] Figure 5 It is a schematic diagram of the second threading tube connection structure of the utility model.

[0039] In the figure: 1. grip ring; 2. riser; 3. connector; 4. first threading tube; 5. first wiring compartment; 6. second wiring compartment; 7. second threading tube; 8. first mounting seat; 9. connecting frame; 10. light source body; 11. second mounting seat; 12. third threading tube; 13. fourth threading tube; 14. detector body; 15. screw hole; 16. mounting groove. DETAILED DESCRIPTION

[0040] The following will be combined with the drawings in the embodiments of the utility model to clearly and completely describe the technical solutions in the embodiments of the utility model. Obviously, the described embodiments are only part of the embodiments of the utility model, not all of the embodiments. Based on the embodiments in the utility model, all other embodiments obtained by ordinary technicians in this field without creative work are within the scope of protection of the utility model.

[0041] Embodiment 1

[0042] like Figure 1 and Figure 2 As shown, the utility model provides an embodiment: a probe for measuring chlorine dioxide using spectroscopy, comprising a first mounting seat 8 and a second mounting seat 11, the first mounting seat 8 is designed with a soft rubber material, a limit ring is installed by hot-melting on the upper outer side of the first mounting seat 8, and the limit ring is located below the connecting frame 9. By hot-melting the limit ring on the upper outer side of the first mounting seat 8, the screwing depth of the first mounting seat 8 in the connecting frame 9 is limited by the limit ring.

[0043] The first mounting seat 8 has a mounting groove 16 formed inside and a light source body 10 embedded therein. The light source body 10 is designed with UV-Vis light source material. A sapphire lens is provided on the top of the light source body 10, and the sapphire lens is embedded and installed on the top of the first mounting seat 8. By providing a sapphire lens on the top of the light source body 10 and embedding the sapphire lens on the top of the first mounting seat 8, the light source body 10 is protected without affecting the passage of ultraviolet rays.

[0044] The inner side of the second mounting seat 11 is provided with a mounting groove 16 and the detector body 14 is embedded and installed. The detector body 14 is equipped with a built-in photodiode, and a sapphire lens is provided at the bottom of the detector body 14, which is embedded and installed at the bottom of the second mounting seat 11. The top of the detector body 14 passes through the second mounting seat 11 and is provided with a screw hole 15. The other side of the detector body 14 is provided with a hole and connected and installed with a third threading tube 12. By providing a sapphire lens at the bottom of the detector body 14 and embedding and installing the sapphire lens at the bottom of the second mounting seat 11, the detector body 14 is protected by the sapphire lens, and the detector body 14 is not affected by the perception of ultraviolet rays by the detector body 14. The end of the third threading tube 12 away from the detector body 14 is connected and installed with a fourth threading tube 13 through an installation screw, and the end of the fourth threading tube 13 away from the third threading tube 12 is connected and installed at the reserved hole on the outer wall of the vertical pipe 2. A fourth threading tube 13 is installed at one end of the third threading tube 12 away from the detector body 14 through an installation screw, and one end of the fourth threading tube 13 away from the third threading tube 12 is installed at the reserved hole on the outer wall of the vertical pipe 2, so that the third threading tube 12 and the fourth threading tube 13 are connected, and the signal lead line on the detector body 14 can be inserted into the vertical pipe 2.

[0045] A connector 3 is threadedly installed through a screw hole 15 on the top of the detector body 14, a standpipe 2 is fixedly installed on the top of the connector 3, and a reserved hole is provided below the outer wall of the standpipe 2. By threading the connector 3 through the screw hole 15 on the top of the detector body 14, and fixing the standpipe 2 on the top of the connector 3, the device can be placed in the chlorine dioxide solution by holding the handle during operation. A grip ring 1 is fixedly installed on the top of the standpipe 2, and the standpipe 2 is designed with stainless steel. By fixing the grip ring 1 on the top of the standpipe 2, the setting of the grip ring 1 can facilitate the operator to hold and prevent the standpipe 2 from slipping.

[0046] Embodiment 2

[0047] like Figure 3 and 5As shown, the utility model provides an embodiment: a probe for measuring chlorine dioxide using a spectrum, comprising a first threading tube 4 and a second threading tube 7, the second threading tube 7 is connected and installed at the bottom of the light source body 10; wherein the second threading tube 7 is connected and installed with a second wiring compartment 6 at one end away from the light source body 10; the first threading tube 4 is connected and installed on one side of the detector body 14; wherein the first threading tube 4 is connected and installed with a first wiring compartment 5 at one end away from the detector body 14; wherein the second wiring compartment 6 and the first wiring compartment 5 are matched in size and are fixedly connected by mounting screws. The first threading tube 4 and the second threading tube 7 are both designed with stainless steel, and connecting wires are passed through the first threading tube 4 and the second threading tube 7, and the connecting wire connector is located on the opposite side of the second wiring compartment 6 and the first wiring compartment 5. By setting the connecting wire connector on the opposite side of the second wiring compartment 6 and the first wiring compartment 5, the light source body and the detector body can be conveniently electrically connected during installation, and the reserved space is sufficient for connecting the lines.

[0048] Embodiment 3

[0049] like Figure 4 As shown, the utility model provides an embodiment: a probe for measuring chlorine dioxide using spectroscopy, comprising a first mounting seat 8 and a second mounting seat 11, a connecting frame 9 is threadedly mounted on the outer side of the first mounting seat 8, the connecting frame 9 comprises a connecting ring and a vertical rod, the vertical rod is fixedly mounted on the upper surface of the connecting ring in an annular array, and the connecting ring and the vertical rod are both designed with stainless steel. By designing the connecting ring and the vertical rod on the connecting frame 9 with stainless steel, the corrosion resistance of the connecting frame 9 can be increased.

[0050] The top of the connecting frame 9 is fixedly connected to the bottom of the second mounting seat 11. The second mounting seat 11 is designed with a soft rubber material, and the outer side of the lower surface of the second mounting seat 11 is an annular opening, and the top of the vertical rod on the connecting frame 9 is embedded in the opening on the lower surface of the second mounting seat 11. By embedding the top of the vertical rod on the connecting frame 9 in the opening on the lower surface of the second mounting seat 11, the second mounting seat 11 can be fixedly connected to the connecting frame 9.

[0051] When the utility model is used, the connection wires on the detector body 14 are connected to the connection wires on the light source body 10, and the connection terminals are located on the opposite sides of the first connection compartment 5 and the second connection compartment 6. At this time, the first mounting seat 8 is threadedly mounted on the inner side of the connecting frame 9, and the first connection compartment 5 and the second connection compartment 6 are fixedly connected by installing screws, so as to protect the connection terminals of the connection wires. At the same time, the signal lead wires of the detector body 14 are passed through the third threading tube 12 and extended into the fourth threading tube 13. After that, the signal lead wires enter the riser 2 and are led out from the top of the riser 2 and connected to the display device. When installing the riser 2, the riser 2 is connected through the connector 3. 2 is threadedly installed on the top of the detector body 14, and the third threading tube 12 and the fourth threading tube 13 are connected and installed by installing screws. When performing chlorine dioxide concentration detection, after cleaning the outside of the device, the standpipe 2 is directly held by hand to place the device in the chlorine dioxide solution. By determining the optimal spectral range for measuring chlorine dioxide in advance and starting the light source body 10, the light passes through the chlorine dioxide solution and is sensed by the detector body 14. At this time, a series of chlorine dioxide standard solutions with known concentrations are used to measure their absorbance using the selected detector body 14, and a standard curve is drawn according to the measurement results to convert the absorbance of unknown samples into chlorine dioxide concentrations.

[0052] It is obvious to those skilled in the art that the present invention is not limited to the details of the exemplary embodiments described above, and that the present invention can be implemented in other specific forms without departing from the spirit or essential features of the present invention. Therefore, the embodiments should be regarded as exemplary and non-restrictive from any point of view, and the scope of the present invention is defined by the appended claims rather than the above description, and it is intended that all changes falling within the meaning and scope of the equivalent elements of the claims be included in the present invention. Any reference numeral in a claim should not be regarded as limiting the claim to which it relates.

Claims

1. A probe for measuring chlorine dioxide using spectroscopy, comprising a first mounting seat (8) and a second mounting seat (11), wherein the first mounting seat (8) has a mounting groove (16) on its inner side and a light source body (10) is embedded and installed therein, a connecting frame (9) is threadedly installed on the outer side of the first mounting seat (8), the top of the connecting frame (9) is fixedly connected to the bottom of the second mounting seat (11), the second mounting seat (11) has a mounting groove (16) on its inner side and a detector body (14) is embedded and installed therein, characterized in that: Also includes: A second threading tube (7) is connected and installed at the bottom end of the light source body (10); Wherein, one end of the second threading tube (7) away from the light source body (10) is connected to and installed with a second wiring compartment (6); A first threading tube (4) is connected and installed on one side of the detector body (14); The end of the first threading tube (4) away from the detector body (14) is connected to and installed with a first wiring compartment (5); The second wiring compartment (6) and the first wiring compartment (5) have matching sizes and are fixedly connected by mounting screws.

2. A probe for measuring chlorine dioxide using a spectrum according to claim 1, characterized in that: The first mounting seat (8) is designed with a soft rubber material, and a limit ring is hot-melt-installed on the upper outer side of the first mounting seat (8), and the limit ring is located below the connecting frame (9).

3. A probe for measuring chlorine dioxide using a spectrum according to claim 1, characterized in that: The light source body (10) is designed with UV-Vis light source material, and a sapphire lens is provided on the top of the light source body (10), and the sapphire lens is embedded and installed on the top of the first mounting seat (8).

4. A probe for measuring chlorine dioxide using a spectrum according to claim 1, characterized in that: The connecting frame (9) comprises a connecting ring and upright poles, wherein the upright poles are fixedly mounted on the upper surface of the connecting ring in a circular array, and the connecting ring and the upright poles are both made of stainless steel.

5. A probe for measuring chlorine dioxide using spectroscopy according to claim 1, characterized in that: The second mounting seat (11) is designed with a soft rubber material, the outer side of the lower surface of the second mounting seat (11) is an annular opening, and the top of the vertical rod on the connecting frame (9) is embedded in the opening on the lower surface of the second mounting seat (11).

6. A probe for measuring chlorine dioxide using a spectrum according to claim 1, characterized in that: The detector body (14) has a built-in photodiode, a sapphire lens is provided at the bottom of the detector body (14), and the sapphire lens is embedded and installed at the bottom of the second mounting seat (11). The top of the detector body (14) passes through the second mounting seat (11) and is provided with a screw hole (15), and a hole is opened on the other side of the detector body (14) and is connected to and installed with a third threading tube (12).

7. A probe for measuring chlorine dioxide using spectroscopy according to claim 6, characterized in that: A connector (3) is threadedly mounted on the top of the detector body (14) through a screw hole (15), a standpipe (2) is fixedly mounted on the top of the connector (3), and a reserved hole is provided below the outer wall of the standpipe (2).

8. A probe for measuring chlorine dioxide using spectroscopy according to claim 6, characterized in that: The end of the third threading tube (12) away from the detector body (14) is connected to the fourth threading tube (13) via a mounting screw, and the end of the fourth threading tube (13) away from the third threading tube (12) is connected to the reserved hole on the outer wall of the standpipe (2).

9. A probe for measuring chlorine dioxide using spectroscopy according to claim 7, characterized in that: A grip ring (1) is fixedly mounted on the top of the stand pipe (2), and the stand pipe (2) is made of stainless steel.

10. A probe for measuring chlorine dioxide using spectroscopy according to claim 1, characterized in that: The first threading tube (4) and the second threading tube (7) are both made of stainless steel. Connecting wires pass through the first threading tube (4) and the second threading tube (7), and the connecting wire connector is located on the opposite side of the second wiring compartment (6) and the first wiring compartment (5).

Citation Information

Patent Citations

  • Real-time chlorine dioxide concentration control device

    CN201752653U