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A method for improving the yield of 2,5-furan dicarboxylic acid

ActiveCN118290372Breduce manufacturing costPromote carboxylation reactionFuranCarboxyl radical
The application provides a method for improving the yield of 2,5-furan dicarboxylic acid, wherein a proper amount of Lewis acid salt is added in the reaction process of promoting the carboxylation reaction of 2-furan carboxylic acid and CO2 to generate 2,5-furan dicarboxylic acid by alkali metal carbonate; the Lewis acid salt and furan molecules are activated by adsorption coordination on H on the furan ring molecule, which is beneficial to promote the C-H deprotonation process of the furan ring molecule. The activation of the Lewis acid is utilized, and it is found that the Lewis acid and the alkali metal carbonate have a promoting effect in the carboxylation reaction of furfuryl acid and CO2, and have an improving effect on the yield of the reaction product 2,5-furan dicarboxylic acid.
Owner:ZHENGZHOU UNIV