High-performance cerium-zirconium oxide and its production method

Abstract

The invention relates to a solid liquid supported catalyst and in particular relates to high-performance cerium zirconium oxide. The high-performance cerium zirconium oxide is prepared from the following chemical ingredients in parts by weight: cerium oxide, zirconium oxide, aluminum oxide, praseodymium oxide, lanthanum oxide, neodymium oxide, yttrium oxide, samarium oxide, vanadium oxide, chromic oxide, manganese oxide, iron oxide, cobalt oxide, copper oxide, manganese oxide, nickel oxide and the like. The invention also provides a preparation method of the high-performance cerium zirconium oxide. The preparation method comprises the steps of mixing all raw materials, adding surface active agents, regulating pH value to be 8-10 to obtain gelatinous precipitates, and calcinating to obtain the cerium zirconium oxide. The solid liquid supported catalyst can overcome the doping defect caused by doping in the cerium zirconium carrier and can improve the thermal stability, the aged specific surface area and the oxygen storage capacity of the supported catalyst; and the preparation method is simple, the technological process is simple and the method facilitates large-scale industrial production.

Description

technical field [0001] The invention relates to a solid solution carrier catalyst, in particular to a high-performance cerium-zirconium oxide and a production method thereof. Background technique [0002] As an important catalyst carrier, cerium oxide has unique oxygen storage capacity and other excellent properties. Cerium ions generate Ce in an oxidizing or reducing atmosphere 3+ and Ce 4+ Oxidation-reduction reaction between them, so as to realize the function of oxygen storage and oxygen release, which is helpful to realize the catalytic conversion of automobile exhaust, etc., but pure cerium oxide is very easy to sinter at high temperature, resulting in a decline in the ability to store and release oxygen. Doping an appropriate amount of zirconium to form a cerium-zirconium-based oxide solid solution can greatly improve the high-temperature aging resistance and oxygen storage and release properties of cerium oxide. Therefore, research on the synthesis of cerium-zircon...

AI Technical Summary

Problems solved by technology

Cerium ions generate Ce in an oxidizing or reducing atmosphere 3+ and Ce 4+ Oxidation-reduction reaction between them, so as to realize the function of oxygen storage and oxygen release, which is helpful to realize the catalytic conversion of automobile exhaust, etc., but pure cerium oxide is very easy to sinter at high temperature, resulting in a decline in the ability to store and release oxygen. Doping an appropriate amount of zirconium to form a cerium-zirconium-based oxide solid solution can greatly improve the high-temperature aging resistance and oxygen storage and release properties of cerium oxide. Therefore, research on the synthesis of cerium-zirconium-based oxide solid solutions has attracted widespread attention.

However, the existing cerium oxide supported catalysts have defects such as high production cost, serious powder agglomeration, and small specific surface area.

[0003] In the prior art, cerium carbonate, cerium hydroxide, cerium ammonium chloride, and tetravalent cerium chloride are mostly used as the main raw materials for the production of cerium oxide. These raw materials have the defects of high production cost and serious environmental pollution, so it is difficult to realize industrialization Furthermore, most of the current research is still in the field of high-pressure reaction, microwave reaction and mesoporous reaction. This experimental scheme has large investment, high production cost, high risk factor, cumbersome process control, and is not easy to realize industrialization.

[0004] Pure CeO 2 Sintering and particle growth are prone to occur at high temperatures, resulting in a decrease in the specific surface area, thereby reducing the oxygen storage capacity, and interacting with alumina to form CeAlO 3 , so that the oxygen storage capacity decreases, thus improving the CeO 2 The thermal stability is very important