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Preparation method of modified glass fiber reinforced polypropylene composite material

A glass fiber and composite material technology, which is applied in the field of composite materials, can solve the problems of reducing the oxidation resistance, mechanical properties and hydrolysis resistance of modified polypropylene materials, and achieve the effect of improving oxidation resistance.

Inactive Publication Date: 2017-06-13
雷笑天
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The technical problem to be solved by the present invention: Aiming at the problem that the current glass fiber reinforced polypropylene material additives easily lead to the reduction of the oxidation resistance, mechanical properties and hydrolysis resistance of the modified polypropylene material, the present invention provides a method using wollastonite and calcium Feldspar is used as a base material, mixed by ball milling, soaked in sulfuric acid to obtain a mesoporous silica mixture, polyvinylpyrrolidone is used as a structure-directing agent, and oxalic acid is used as a crystal form regulator to form calcium sulfate whis

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0019] According to the mass ratio of 1:3, put wollastonite and anorthite into a ball mill, add steel balls with a diameter of 100 mm that are 4 times the mass of anorthite, and ball mill for 2 hours at 300 r / min to collect the ball milling mixture. According to a mass ratio of 1: 4. Put the ball mill mixture and sulfuric acid solution with a mass fraction of 70% into a container, heat the container in a microwave oven, heat it to 90°C, and keep it warm for 3 hours; after the above heat preservation is completed, add the above ball mill into the container respectively Water with twice the mass of the mixture, polyvinylpyrrolidone with 20% mass of the above-mentioned ball-milled mixture, and oxalic acid with 3% mass of the above-mentioned ball-milled mixture, after stirring evenly, continue to keep warm for 30 minutes, then put the mixture in the container into the reaction kettle, set the temperature 130°C, pressure 1.2MPa, heat preservation 6h; after the above heat preservatio...

example 2

[0022]According to the mass ratio of 1:3, put wollastonite and anorthite into a ball mill, add steel balls with a diameter of 100 mm that are 6 times the mass of anorthite, and ball mill for 3 hours at 300 r / min to collect the ball milling mixture, according to a mass ratio of 1: 4. Put the ball mill mixture and sulfuric acid solution with a mass fraction of 70% into a container, heat the container in a microwave oven, heat it to 95°C, and keep it warm for 5 hours; after the above heat preservation is completed, add the above ball mill into the container respectively Water with 3 times the mass of the mixture, polyvinylpyrrolidone with 30% mass of the above-mentioned ball-milled mixture, and oxalic acid with 5% mass of the above-mentioned ball-milled mixture, stir well and continue to keep warm for 40 minutes, then put the mixture in the container into the reaction kettle, set the temperature 150°C, pressure 1.5MPa, heat preservation 9h; after the above heat preservation is com...

example 3

[0025] According to the mass ratio of 1:3, put wollastonite and anorthite into a ball mill, add steel balls with a diameter of 100mm that are 5 times the mass of anorthite, and ball mill for 3 hours at 300r / min, collect the ball milling mixture, and press the mass ratio of 1: 4. Put the ball mill mixture and sulfuric acid solution with a mass fraction of 70% into a container, heat the container in a microwave oven, heat it to 92°C, and keep it warm for 4 hours; after the above heat preservation is completed, add the above ball mill Water with 3 times the mass of the mixture, polyvinylpyrrolidone with 25% mass of the above-mentioned ball-milled mixture, and oxalic acid with 4% mass of the above-mentioned ball-milled mixture, stir well and continue to keep warm for 35 minutes, then put the mixture in the container into the reaction kettle, set the temperature 140°C, pressure 1.3MPa, heat preservation 7h; after the above heat preservation is over, reduce the pressure to standard a...

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Abstract

The invention relates to a preparation method of a modified glass fiber reinforced polypropylene composite material, which belongs to the technical field of composite materials. The invention provides a mesoporous silica mixture obtained by using wollastonite and anorthite as a base material, mixing by ball milling, soaking in sulfuric acid, using polyvinylpyrrolidone as a structure-directing agent, and oxalic acid as a crystal form regulator , so that the calcium sulfate whiskers in the mixture are loaded and fixed in mesoporous silica to provide mechanical properties, and then melted and mixed with alumina and coupling agents to improve the oxidation resistance, and finally mixed with polypropylene, in calcium sulfate Under the initiation of whiskers and the catalysis of titanium, the crystallinity of polypropylene is increased, and the thermal oxidation resistance is further improved, thereby obtaining a modified glass fiber reinforced polypropylene composite material. The modified glass fiber reinforced polypropylene composite material prepared by the present invention Good mechanical properties, high oxidation resistance and hydrolysis resistance.

Description

technical field [0001] The invention relates to a preparation method of a modified glass fiber reinforced polypropylene composite material, which belongs to the technical field of composite materials. Background technique [0002] Modified polypropylene materials play an irreplaceable role in other materials in terms of automobile beauty, comfort, safety, anti-corrosion, light weight and large design freedom. Among many filled polypropylene materials, glass fiber reinforced PP composite materials have the advantages of high rigidity, heat resistance, chemical corrosion resistance, weather resistance and dimensional stability, and can replace copper, steel, nylon, etc. within a certain range. Used in automobiles, electrical appliances, motors, home appliances and other fields. As a general-purpose engineering plastic, glass fiber-reinforced polypropylene material has high strength, high stiffness, rigid impact strength, low density, low warpage creep, and excellent dynamic f...

Claims

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Application Information

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IPC IPC(8): C08L23/12C08K9/06C08K9/04C08K9/02C08K7/14
CPCC08K9/06C08K7/14C08K9/02C08K9/04C08L2201/08
Inventor 雷笑天宋昊
Owner 雷笑天