Herbicidal mixtures containing amine salts of acidic herbicides
A herbicidal composition and herbicide technology, applied in biocides, animal repellents, plant growth regulators, etc.
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Embodiment 1
[0163]Some forms of 2,4-D are prepared by adding an amine (ethylenediamine or 3-(dimethylamino)-1-propylamine (DMAPA)) to water, followed by the addition of 2,4-D acid with stirring until dissolved. A series of solutions of the amine salt resulted in formulations 10047643-1, 10047643-2, 10047643-3. Tables A1-A3 provide the compositional details of each formulation.
[0164] Table A1. Formulation 10047643-1
[0165]
[0166] Table A2. Formulation 10047643-2
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[0168] Table A3. Formulation 10047643-3
[0169]
Embodiment 2
[0171] The formulations in Table B1 were prepared as follows. Add DMAPA to the Erlenmeyer flask and stir. Add 6 grams of glyphosate wet cake while stirring, then add 10 grams of water and heat up to 55°C. A further 75 grams of glyphosate wet cake was added to the stirred solution. The resulting solution thickened and was heated to 85°C for 10 minutes. Then 10 grams of water were added and the solution was heated to 98°C. More glyphosate wet cake was then added, totaling 112 grams, and the solution was stirred for a further 15 minutes at 95°C. The remaining water, totaling 54.8 grams, was added to the resulting unclear solution, which was heated at 100°C. After 10 minutes, a clear yellow solution was obtained which was allowed to cool and poured through a 50 mesh screen and stored in a glass bottle. Using a similar procedure, various formulations were prepared at target loadings of 606 g / l a.e., 620 g / l a.e., 607 g / l a.e. and 584 g / l a.e. Table B2 provides the composition...
Embodiment 3
[0178] A series of premixes of 2,4-D DMAPA and glyphosate DMAPA salts were prepared as follows. Add DMAPA to the water, then add 2,4-D with stirring until dissolved. Then add the glyphosate wet cake and continue stirring until dissolved. ETHOQUAD C12 75DEG was then added and the solution was stirred for half an hour. Tables B3-B5 provide the compositional details of each formulation. In addition, Tables B6-B8 provide similarly prepared formulations additionally containing an oil-based drift reducing or retarding agent (DRA).
[0179] Table B3. Formulation 10048811-1
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[0181] Table B4. Formulation 10048811-2
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[0183] Table B5. Formulation 10048811-3
[0184]
[0185] Table B6. Formulation 10070605-4
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[0187] Table B7. Formulation 10070605-5
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[0189] Table B8. Formulation 10070605-6
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