Bedding prepared from polyester antibacterial masterbatch based on one-dimensional nanometer Ag/C composite material

Abstract

The invention relates to bedding prepared from a polyester antibacterial masterbatch based on a one-dimensional nanometer Ag / C composite material, belonging to the technical field of high-tech functional composite materials. According to the invention, polyester resin which is prepared by blending the polyester antibacterial masterbatch in proportion is subjected to conventional pre-crystallization, drying and melt spinning successively to prepare antibacterial polyester fibers, and the antibacterial polyester fibers are woven or are blended and interwoven with cotton, hemp and other chemicalfibers to form an antibacterial fabric. The polyester antibacterial masterbatch is prepared from polyester, a one-dimensional nanometer Ag / C composite material, micro-nano inorganic powder, an auxiliary agent and the like through blending, plasticizing, mixing, extruding, drawing, cooling and granulation. According to the invention, the one-dimensional nanometer Ag / C composite material is fully and effectively dispersed, so the one-dimensional nanometer Ag / C composite material is prevented from failures due to agglomeration and allowed to maintain long-lasting antibacterial effect; and the prepared bedding fabric has the characteristics of broad-spectrum antibacterial performance, high efficiency, durability, washing resistance, excellent performance, safety to the body, no toxicity, no harm, no allergenicity, environment protection performance, etc.

Description

technical field

[0001] The invention belongs to the field of high-tech functional composite materials, in particular to a bedding prepared from polyester antibacterial masterbatch based on one-dimensional nano Ag / C composite materials. Background technique

[0002] Diseases caused by various pathogenic bacteria, fungi and viruses seriously threaten human health, therefore, various antibacterial materials have become the focus of research. There is also an increasing demand for high molecular polymer materials with antibacterial functions. If it is required to have a permanent antibacterial effect, the preparation method of antibacterial polymer materials can only be added in the form of masterbatches.

[0003] Inorganic antibacterial materials have been used more and more important due to their excellent safety, durability, slow release and chemical stability, and convenient use. However, nano-powders are extremely fine, easy to agglomerate, and are not easy to disperse in...

Examples

Embodiment 1

[0043] A bedding prepared from polyester antibacterial masterbatch based on one-dimensional nano Ag / C composite material, the preparation method comprising:

[0044] Step 1: Preparation of a polyester antibacterial masterbatch based on one-dimensional nano Ag / C composite:

[0045] The raw materials include the following components calculated by weight: 62 parts of polybutylene terephthalate (PBT), 15 parts of one-dimensional nano-Ag / C composite material, 15 parts of inorganic powder, 1.3 parts of surface modifier, dispersion 4 parts of agent, 0.8 part of antioxidant, 1.2 parts of lubricant and 0.7 part of stabilizer.

[0046] PBT resin is fiber grade PBT resin;

[0047] One-dimensional nano-Ag / C composite material: This scheme is self-made.

[0048] The inorganic powder is 3000 mesh calcium carbonate powder, which has been hybridized by this scheme.

[0049] The surface modifier of inorganic powder is a compound of aluminate coupling agent and titanate in a mass ratio of 1:...

Embodiment 2

[0069] A bedding prepared from polyester antibacterial masterbatch based on one-dimensional nano Ag / C composite material, the preparation method comprising:

[0070] Step 1: Preparation of a polyester antibacterial masterbatch based on one-dimensional nano Ag / C composite:

[0071] Preparation of polyester antibacterial masterbatch based on one-dimensional nano Ag / C composite material, raw materials include the following components calculated by weight: 56.2 parts of polytrimethylene terephthalate resin, 20 parts of one-dimensional nano Ag / C composite material , 15 parts of inorganic powder, 1.5 parts of surface modifier, 5 parts of dispersant, 0.9 part of antioxidant, 1.4 parts of lubricant, and 0.5 part of stabilizer.

[0072] Polytrimethylene terephthalate resin is conventional commercially available polytrimethylene terephthalate resin;

[0073] One-dimensional nano-Ag / C composite material: This scheme is self-made.

[0074] The inorganic powder is 2500 mesh calcium carbo...

Embodiment 3

[0095] A bedding prepared from polyester antibacterial masterbatch based on one-dimensional nano Ag / C composite material, the preparation method comprising:

[0096] Step 1: Preparation of a polyester antibacterial masterbatch based on one-dimensional nano Ag / C composite:

[0097] Preparation of polyester antibacterial masterbatch based on one-dimensional nano Ag / C composite material, raw materials include the following components calculated by weight: 88 parts of polyethylene terephthalate resin, one-dimensional nano Ag / C composite material 20 parts, 25 parts of inorganic powder, 0.6 parts of surface modifier, 1 part of dispersant, 2 parts of antioxidant, 4 parts of lubricant, 5 parts of stabilizer.

[0098] Polyethylene terephthalate is conventional commercially available polyethylene terephthalate;

[0099] One-dimensional nano-Ag / C composite material: This scheme is self-made.

[0100] The inorganic powder is a mixture of 2500 mesh calcium carbonate powder and 3000 mesh ...

technical field

[0001] The invention belongs to the field of high-tech functional composite materials, in particular to a bedding prepared from polyester antibacterial masterbatch based on one-dimensional nano Ag / C composite materials. Background technique

[0002] Diseases caused by various pathogenic bacteria, fungi and viruses seriously threaten human health, therefore, various antibacterial materials have become the focus of research. There is also an increasing demand for high molecular polymer materials with antibacterial functions. If it is required to have a permanent antibacterial effect, the preparation method of antibacterial polymer materials can only be added in the form of masterbatches.

[0003] Inorganic antibacterial materials have been used more and more important due to their excellent safety, durability, slow release and chemical stability, and convenient use. However, nano-powders are extremely fine, easy to agglomerate, and are not easy to disperse in...

Examples

Embodiment 1

[0043] A bedding prepared from polyester antibacterial masterbatch based on one-dimensional nano Ag / C composite material, the preparation method comprising:

[0044] Step 1: Preparation of a polyester antibacterial masterbatch based on one-dimensional nano Ag / C composite:

[0045] The raw materials include the following components calculated by weight: 62 parts of polybutylene terephthalate (PBT), 15 parts of one-dimensional nano-Ag / C composite material, 15 parts of inorganic powder, 1.3 parts of surface modifier, dispersion 4 parts of agent, 0.8 part of antioxidant, 1.2 parts of lubricant and 0.7 part of stabilizer.

[0046] PBT resin is fiber grade PBT resin;

[0047] One-dimensional nano-Ag / C composite material: This scheme is self-made.

[0048] The inorganic powder is 3000 mesh calcium carbonate powder, which has been hybridized by this scheme.

[0049] The surface modifier of inorganic powder is a compound of aluminate coupling agent and titanate in a mass ratio of 1:...

Embodiment 2

[0069] A bedding prepared from polyester antibacterial masterbatch based on one-dimensional nano Ag / C composite material, the preparation method comprising:

[0070] Step 1: Preparation of a polyester antibacterial masterbatch based on one-dimensional nano Ag / C composite:

[0071] Preparation of polyester antibacterial masterbatch based on one-dimensional nano Ag / C composite material, raw materials include the following components calculated by weight: 56.2 parts of polytrimethylene terephthalate resin, 20 parts of one-dimensional nano Ag / C composite material , 15 parts of inorganic powder, 1.5 parts of surface modifier, 5 parts of dispersant, 0.9 part of antioxidant, 1.4 parts of lubricant, and 0.5 part of stabilizer.

[0072] Polytrimethylene terephthalate resin is conventional commercially available polytrimethylene terephthalate resin;

[0073] One-dimensional nano-Ag / C composite material: This scheme is self-made.

[0074] The inorganic powder is 2500 mesh calcium carbo...

Embodiment 3

[0095] A bedding prepared from polyester antibacterial masterbatch based on one-dimensional nano Ag / C composite material, the preparation method comprising:

[0096] Step 1: Preparation of a polyester antibacterial masterbatch based on one-dimensional nano Ag / C composite:

[0097] Preparation of polyester antibacterial masterbatch based on one-dimensional nano Ag / C composite material, raw materials include the following components calculated by weight: 88 parts of polyethylene terephthalate resin, one-dimensional nano Ag / C composite material 20 parts, 25 parts of inorganic powder, 0.6 parts of surface modifier, 1 part of dispersant, 2 parts of antioxidant, 4 parts of lubricant, 5 parts of stabilizer.

[0098] Polyethylene terephthalate is conventional commercially available polyethylene terephthalate;

[0099] One-dimensional nano-Ag / C composite material: This scheme is self-made.

[0100] The inorganic powder is a mixture of 2500 mesh calcium carbonate powder and 3000 mesh ...

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