Combustion gas turbine co-combustion system coupled with solar ammonia doping and ammonia plasma and using method
Through the gas turbine mixed combustion system that couples solar energy and ammonia plasma, the low efficiency and high emission problems of ammonia mixed in the gas turbine are solved, the ammonia utilization rate and gas turbine efficiency are improved, and the effective treatment of exhaust gas and the stability of grid power are achieved. Replenish.
Patent Information
- Application Number
- CN202411313432.8
- Authority / Receiving Office
- CN · China
- Patent Type
- Applications(China)
- Current Assignee / Owner
- Priority Date
- 2024-08-16
- Filing Date
- 2024-09-20
- Publication Date
- 2024-12-10
AI Technical Summary
The existing gas turbines doped with ammonia gas have problems such as low ammonia utilization, high NOx emission, high ammonia escape rate, high heat demand and failure to effectively utilize other energy sources.
The gas turbine mixing system that uses a gas turbine coupled with solar energy and ammonia plasma is used to generate ammonia gas through a urea heat exchange pyrolyzer, and the plasma generator is used to fully burn ammonia gas, combining solar photothermal power generation components to optimize gas mixing in the combustion chamber Proportion and exhaust gas treatment to reduce NOx and carbon oxide emissions.
It improves the utilization rate of ammonia and the efficiency of the gas turbine, reduces NOx and carbon oxide emissions, achieves more efficient utilization of exhaust gas, and replenishes the grid's electrical energy through solar energy, ensuring stable power generation.
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Figure CN119102882A_ABST
Abstract
Description
Technical Field
[0001] The present invention belongs to the technical field of gas turbines, and in particular relates to a gas turbine co-combustion system coupled with solar ammonia and ammonia plasma and a use method thereof. Background Art
[0002] Heavy-duty gas turbines are the most efficient heat-to-power conversion power generation equipment to date. With the development of gas turbines, carbon emission reduction technologies are also gradually following up. Reducing carbon oxide emissions is a problem and challenge, so adding other zero-carbon combustible gases is one of the solutions. Ammonia, as a zero-carbon fuel, has significant advantages in calorific value, production, etc., so blending ammonia can reduce carbon oxide emissions. In the current relevant technical field, most of the ammonia is blended in boilers, and less in gas turbines.
[0003] Patent CN115234905B discloses a combustion system and method for producing hydrogen by decomposing ammonia and burning ammonia. Hydrogen is produced by using an ammonia decomposition and hydrogen purification device. Ammonia and hydrogen in different proportions are mixed as fuel. NH3 in the rich fuel mixture is used to generate NO x However, when this invention uses ammonia as the combustion gas, ammonia will still escape, resulting in the presence of NO in the exhaust gas. x , and the device is not coupled with other energy sources, resulting in high energy consumption.
[0004] However, there are still many problems with the current gas turbines that use ammonia: 1. Most of the current gas turbines that use ammonia are to directly gasify and burn liquid ammonia, or to crack liquid ammonia to produce hydrogen and nitrogen for combustion, and the utilization rate of ammonia is low; 2. Although using ammonia as a fuel reduces carbon oxides, it also increases NO x The emission of ammonia is also high, which will still cause pollution; 3. The exhaust gas produced after combustion is not used more efficiently; 4. Other energy sources are rarely combined with gas turbines to maximize the utilization of energy; 5. There are also few cases of co-combustion of co-combustion gas into plasma. Summary of the invention
[0005] The purpose of the present invention is to solve at least one of the above problems and provide a gas turbine co-combustion system coupled with solar ammonia and ammonia plasma and a method of use, so as to solve the problems of low ammonia utilization rate in the prior art and NO in the tail gas when ammonia is burned as fuel. x This solution maximizes the use of ammonia, uses solar energy to make ammonia participate in gas combustion in the form of gas and plasma, makes the gas turbine more efficient, and makes ammonia burn more stably and more efficiently. It also uses ammonia to treat the tail gas after work to reduce carbon oxides and NOx emissions, and when combined with solar energy, it can transmit electricity to the grid stably and continuously.
[0006] The purpose of the present invention is achieved through the following technical solutions:
[0007] One of the technical solutions of the present invention is to provide a gas turbine co-combustion system coupled with solar ammonia and ammonia plasma, including a gas turbine power generation component, a pyrolysis ammonia production component and a solar thermal power generation component;
[0008] The gas turbine power generation assembly comprises a compressor, a combustion chamber, a turbine and a generator a;
[0009] The pyrolysis ammonia production component includes a urea heat exchange pyrolyzer a, a urea heat exchange pyrolyzer b and a plasma generator;
[0010] The solar power generation assembly includes a solar collector, a steam turbine, a generator b and a storage battery which are electrically connected in sequence;
[0011] The output end of the compressor is connected to the input end of the combustion chamber to input compressed gas into the combustion chamber, and the combustion chamber also inputs natural gas. The output end of the combustion chamber is connected to the input end of the turbine. The compressor, turbine and generator a are connected through a shaft;
[0012] The urea heat exchange pyrolyzer a and the urea heat exchange pyrolyzer b are used to pyrolyze urea to obtain ammonia. The heat source of the urea heat exchange pyrolyzer a is the tail gas discharged from the combustion chamber, and the heat source of the urea heat exchange pyrolyzer b comes from the solar thermal power generation component. The ammonia is then input into the plasma generator and the combustion chamber respectively, and the output end of the plasma generator is connected to the input end of the combustion chamber;
[0013] The solar thermal power generation component is connected to the pyrolysis ammonia production component and is used for heat exchange and power supply for the pyrolysis ammonia production component.
[0014] Furthermore, compressed gas delivered by a compressor, ammonia delivered by an ammonia gas collecting box, and ammonia plasma delivered by a plasma generator are introduced into the combustion chamber, and then natural gas is introduced and mixed and burned in the combustion chamber. Using ammonia as a combustion gas can reduce the emission of carbon oxides. Adding ammonia plasma can more fully burn the ammonia generated by the thermal decomposition of urea. The ammonia and ammonia plasma themselves carry heat, which can also reduce the heat demand.
[0015] Furthermore, the blending ratio of natural gas, ammonia and ammonia plasma is (5-7):(3-2):(2-1), preferably (6):(2):(2).
[0016] Furthermore, the heat exchange between urea and tail gas in urea heat exchanger pyrolyzer a recovers the heat in the tail gas, while urea heat exchanger pyrolyzer b produces ammonia by utilizing solar energy to pyrolyze urea, thereby ensuring a stable and sufficient supply of ammonia.
[0017] Furthermore, the tail gas is introduced into the hot flow inlet of the urea heat exchange pyrolyzer a, and is discharged from the hot flow outlet after heat exchange with urea, and urea is introduced into the cold flow inlet, and ammonia after pyrolysis is discharged from the hot flow outlet.
[0018] Furthermore, the gas turbine co-firing system also includes an ammonia gas collecting box, which is respectively connected to the urea heat exchange pyrolyzer a, the urea heat exchange pyrolyzer b, the plasma generator and the combustion chamber. The ammonia obtained by pyrolyzing urea is first collected in the ammonia gas collecting box and then respectively input into the plasma generator and the combustion chamber.
[0019] Furthermore, part of the ammonia in the ammonia collecting box is output to the plasma generator, and the remaining part is output to the combustion chamber for direct combustion. The electric energy provided by the generator b causes the ammonia to react in the plasma generator to generate ammonia plasma, which is then output to the combustion chamber for combustion. The ammonia plasma can not only better carry out the combustion reaction, but also ignite the ammonia.
[0020] Furthermore, the gas turbine co-firing system further comprises a urea solution storage tank, which is respectively connected to the urea heat exchange pyrolyzer a and the urea heat exchange pyrolyzer b to provide urea.
[0021] Furthermore, the gas turbine co-firing system also includes a waste heat furnace, the input end of which is respectively connected to the hot flow output end and the cold flow output end of the urea heat exchange pyrolyzer a, and the tail gas is treated by SCR flue gas denitrification.
[0022] Furthermore, the urea heat exchange pyrolyzer a passes the tail gas into the waste heat furnace through the cold flow output end. In addition to passing a part of the ammonia generated by the pyrolysis of the urea heat exchange pyrolyzer a to the ammonia gas collecting box, the other part is passed to the waste heat furnace for ammonia spraying. The ammonia in the waste heat furnace passes through the ammonia spray grid to the SCR reaction module equipped with a catalyst to react with the tail gas and then discharged into the atmosphere.
[0023] Furthermore, the solar thermal power generation assembly is connected to a plasma generator, and the solar thermal power generation assembly supplies power to the plasma generator.
[0024] Furthermore, the solar collector outputs heat to the steam turbine; the steam turbine and the generator b convert the thermal energy into electrical energy; the generator b is electrically connected to the plasma generator, and the generator b provides electrical energy for the plasma generator and the storage battery.
[0025] Furthermore, the generator a and the storage battery are respectively connected to the power grid to supply power to the power grid, and the storage battery is used to provide electrical energy to the power grid when the power supply of the generator a does not reach the standard power supply.
[0026] Furthermore, the solar thermal power generation energy provided by solar energy can fully compensate for the power generation of the power grid from gas turbines. When the sunlight is insufficient, the production of ammonia generated by solar heat exchange will decrease, and the amount of ammonia burned will inevitably decrease. At this time, the storage battery can provide part of the electricity for the power grid to compensate for the energy conversion generated by the combustion of ammonia due to the lack of heat exchange.
[0027] Furthermore, the turbine is connected to the hot flow inlet of the urea heat exchanger pyrolyzer a through a high-temperature fan, so as to transport the tail gas to the urea heat exchanger pyrolyzer a.
[0028] The second technical solution of the present invention is to provide a method for using a gas turbine co-combustion system coupled with solar ammonia and ammonia plasma, specifically: the urea solution storage tank inputs urea into the urea heat exchange pyrolyzer a and the urea heat exchange pyrolyzer b, the heat source of the urea heat exchange pyrolyzer a comes from the exhaust gas of the combustion chamber, and the heat source of the urea heat exchange pyrolyzer b comes from the solar thermal power generation component. After urea heat exchange, ammonia is generated and output to the ammonia gas collecting box, and then output to the plasma generator and the combustion chamber respectively. The plasma generator generates ammonia plasma and inputs it into the combustion chamber. The ammonia plasma and ammonia are burned together with the compressed gas from the compressor and the natural gas in the combustion chamber, and drive the turbine and the generator a to generate electricity. The exhaust gas after work is passed into the urea heat exchange pyrolyzer a to recover heat, and finally discharged after being treated with part of the ammonia through the SCR denitration technology.
[0029] Compared with the prior art, the present invention has the following advantages:
[0030] 1. Since the propagation flame of ammonia is low, there may be incomplete combustion and ammonia escape. The arc generated by the plasma generator can ionize the ammonia. In addition to fully burning the ammonia plasma, the high-temperature jet characteristics can also be used to ignite the ammonia with a high ignition point, so that it can be fully burned in the combustion chamber, thereby improving the efficiency of the gas turbine. The utilization rate of ammonia is further improved by generating ammonia plasma;
[0031] 2. Air enters from the compressor and then passes to the combustion chamber. Natural gas directly passes to the combustion chamber. Part of the ammonia produced by pyrolysis is directly transported to the combustion chamber. The ammonia plasma produced after ammonia ionization is transported to the combustion chamber for combustion. The heat carried by the ammonia itself can increase the temperature of the combustion chamber and reduce the heat demand.
[0032] 3. The present invention uses ammonia to replace part of the natural gas combustion, and also allows the gas generated by the combustion of ammonia to be fully treated. The exhaust gas discharged after work is sprayed to the SCR reaction module equipped with a catalyst through the ammonia spray grid in the waste heat furnace, and reacts with NO in the exhaust gas under the action of the catalyst. x A reduction reaction occurs to generate nitrogen and water, and the exhaust gas is finally discharged with less carbon oxides and NO x Emissions meet environmental protection requirements;
[0033] 4. The heat sources of the urea heat exchanger pyrolyzer include the heat of the exhaust gas and solar energy. It recovers the heat in the exhaust gas and saves energy. It also makes the source of ammonia sufficient, ensuring the subsequent combustion of ammonia and the power generation of the gas turbine. In addition to being used for power generation, the exhaust gas of the gas turbine can also be used to achieve better thermal cycle efficiency of the gas turbine.
[0034] 5. The collector, steam turbine, and generator b generate electricity through solar thermal power. Generator a and storage batteries provide electrical energy for the plasma generator, ensuring the power generation of the gas turbine. The storage battery stores the electrical energy converted by the solar collector. On cloudy days, the heat energy converted by solar energy is relatively reduced, and the production of ammonia is reduced. At this time, the electrical energy converted by solar energy from thermal power generation can be compensated by the storage battery to meet the requirements of power transmission of the power grid. The power supply of the plasma generator can also be provided by the storage battery. BRIEF DESCRIPTION OF THE DRAWINGS
[0035] Figure 1 The schematic diagram of the structure of the gas turbine co-combustion system coupled with solar ammonia and ammonia plasma;
[0036] In the figure: 1-compressor; 2-combustion chamber; 3-turbine; 4-generator a; 5-power grid; 6-urea heat exchange pyrolyzer a; 7-urea heat exchange pyrolyzer b; 8-urea solution storage tank; 9-solar collector; 10-storage battery; 11-plasma generator; 12-ammonia gas collecting box; 13-high temperature fan; 14-waste heat furnace; 15-steam turbine; 16-generator b. DETAILED DESCRIPTION
[0037] The present invention is described in detail below in conjunction with the accompanying drawings and specific embodiments. This embodiment is implemented based on the technical solution of the present invention, and provides a detailed implementation method and specific operation process, but the protection scope of the present invention is not limited to the following embodiments.
[0038] See also Figure 1 To illustrate this embodiment, a gas turbine co-combustion system coupled with solar ammonia and ammonia plasma includes a gas turbine power generation component, a pyrolysis ammonia production component and a solar thermal power generation component;
[0039] The gas turbine power generation assembly comprises a compressor 1, a combustion chamber 2, a turbine 3 and a generator a 4;
[0040] The pyrolysis ammonia production component includes a urea heat exchange pyrolyzer a 6, a urea heat exchange pyrolyzer b 7 and a plasma generator 11;
[0041] The solar power generation assembly includes a solar collector 9, a steam turbine 15, a generator b16 and a storage battery 10 which are electrically connected in sequence;
[0042] The gas turbine co-combustion system further includes an ammonia gas collecting box 12, a waste heat furnace 14 and a high-temperature fan 13;
[0043] The output end of the compressor 1 is connected to the input end of the combustion chamber 2 to input the compressed gas into the combustion chamber 2. The combustion chamber 2 also inputs natural gas. The output end of the combustion chamber 2 is connected to the input end of the turbine 3. The compressor 1, the turbine 3 and the generator a 4 are connected through a shaft.
[0044] The urea heat exchange pyrolyzer a6 and the urea heat exchange pyrolyzer b7 are used for pyrolyzing urea to obtain ammonia. The heat source of the urea heat exchange pyrolyzer a6 is the tail gas discharged from the combustion chamber 2, and the heat source of the urea heat exchange pyrolyzer b7 comes from the heat collected by the solar collector 9. The ammonia is then respectively input into the plasma generator 11 and the combustion chamber 2; the output end of the plasma generator 11 is connected to the input end of the combustion chamber 2;
[0045] The solar thermal power generation component is connected to the pyrolysis ammonia production component, and is used for heat exchange and power supply for the pyrolysis ammonia production component. The solar collector 9 outputs heat to the urea heat exchange pyrolyzer b7 and the steam turbine 15; the steam turbine 15 and the generator b16 convert thermal energy into electrical energy; the generator b16 is electrically connected to the plasma generator 11, and the generator b16 provides electrical energy for the plasma generator 11 and the storage battery 10.
[0046] The combustion chamber 2 is introduced with compressed gas delivered by the compressor 1 , ammonia delivered by the ammonia gas collecting box 12 , and ammonia plasma delivered by the plasma generator 11 , and then natural gas is introduced and mixed and burned in the combustion chamber 2 .
[0047] The blending ratio of natural gas, ammonia and ammonia plasma is (5-7):(3-2):(2-1), preferably (6):(2):(2).
[0048] The heat exchange between urea and tail gas in urea heat exchanger pyrolyzer a 6 recovers the heat in the tail gas, while urea heat exchanger pyrolyzer b 7 produces ammonia by utilizing solar energy to pyrolyze urea, thus ensuring a stable and sufficient supply of ammonia.
[0049] The tail gas is introduced into the hot flow inlet of the urea heat exchange pyrolyzer a6, and is discharged from the hot flow outlet after heat exchange with urea. Urea is introduced into the cold flow inlet, and ammonia after pyrolysis is discharged from the hot flow outlet.
[0050] The ammonia gas collecting box 12 is respectively connected to the urea heat exchange pyrolyzer a 6, the urea heat exchange pyrolyzer b 7, the plasma generator 11 and the combustion chamber 2. The ammonia obtained by pyrolyzing urea is first collected in the ammonia gas collecting box 12 and then respectively input into the plasma generator 11 and the combustion chamber 2.
[0051] A portion of the ammonia in the ammonia collecting box 12 is output to the plasma generator 11, and the remaining portion is output to the combustion chamber 2 for direct combustion. The electric energy provided by the generator b 16 causes the ammonia to react in the plasma generator 11 to generate ammonia plasma, which is then output to the combustion chamber 2 for combustion.
[0052] The urea solution storage tank 8 is connected to the urea heat exchange pyrolyzer a 6 and the urea heat exchange pyrolyzer b 7 respectively to provide urea.
[0053] The input end of the waste heat furnace 14 is respectively connected to the hot flow output end and the cold flow output end of the urea heat exchange pyrolyzer a6, and the tail gas is treated by SCR flue gas denitration, specifically: ammonia is sprayed to the SCR reaction module equipped with a catalyst through the ammonia spray grid, and reacts with NO in the tail gas under the action of the catalyst. x A reduction reaction occurs, generating nitrogen and water which are discharged into the atmosphere.
[0054] The urea heat exchange pyrolyzer a6 passes the tail gas into the waste heat furnace 14 through the cold flow output end. In addition to passing a part of the ammonia generated by the pyrolysis of the urea heat exchange pyrolyzer a6 to the ammonia gas collecting box 12, the other part is passed to the waste heat furnace 14 for ammonia spraying. The ammonia in the waste heat furnace 14 passes through the ammonia spraying grid to the SCR reaction module equipped with a catalyst to react with the tail gas and then discharged into the atmosphere.
[0055] The solar thermal power generation assembly is connected to the plasma generator 11 , and the solar thermal power generation assembly provides power for the plasma generator 11 .
[0056] The generator a 4 and the storage battery 10 are respectively connected to the power grid 5 to supply power to the power grid 5, and the storage battery 10 is used to provide power to the power grid 5 when the power supply of the generator a 4 does not reach the standard power supply.
[0057] In one embodiment, when the power generation of the generator a 4 is 80%-90% of the average power generation, the standard power supply is not reached, and the storage battery 10 and the generator a 4 jointly provide power to the power grid 5 .
[0058] The solar thermal power generation energy provided by the solar energy can fully compensate for the power generation of the power grid 5 from the gas turbine. When the sunlight is insufficient, the production of ammonia used for solar heat exchange is reduced, and the amount of ammonia burned is bound to decrease, but the storage battery 10 can provide partial electricity for the power grid 5 to compensate for the energy conversion generated by the combustion of ammonia due to the lack of heat exchange.
[0059] The turbine 3 is connected to the hot flow inlet of the urea heat exchanger pyrolyzer a6 through the high-temperature fan 13, and is used to transport the exhaust gas to the urea heat exchanger pyrolyzer a6.
[0060] refer to Figure 1 It can be seen that when the gas turbine power generation system of the present invention is in operation,
[0061] First, the solar collector 9 absorbs solar energy and transfers it to the urea heat exchange pyrolyzer b7 and the steam turbine 15. The steam turbine 15 and the generator b16 convert the heat energy into electrical energy. The generator 16 uses the electrical energy to supply the plasma generator 11 and store it in the storage battery 10. The urea solution storage tank 8 inputs urea into the urea heat exchange pyrolyzer a6 and the urea heat exchange pyrolyzer b7. In the urea heat exchange pyrolyzer a6, the urea and the tail gas are heat exchanged and pyrolyzed. The urea heat exchange pyrolyzer b7 pyrolyzes urea under the action of the heat transferred by the solar collector 9. The urea heat exchange pyrolysis produces ammonia, which is output to the ammonia gas collecting box 12 for mixing. The ammonia gas collecting box 12 outputs the ammonia to the plasma generator 11 and the combustion chamber 2 respectively. The plasma generator 11 generates ammonia plasma and inputs it into the combustion chamber 2. The compressor 1 transports the compressed gas to the combustion chamber 2, and natural gas is introduced into the combustion chamber 2 at the same time. Ammonia plasma, ammonia, compressed gas and natural gas are burned together in the combustion chamber 2, and drive the turbine 3 to work and the generator a 4 to generate electricity. The exhaust gas after work is passed into the urea heat exchange pyrolyzer a 6 through the high-temperature fan 13 to recover heat, and finally transported to the waste heat furnace 14 together with part of the ammonia in the urea heat exchange pyrolyzer a 6. After being treated by the SCR denitrification technology, nitrogen and water are generated and discharged. The generator a 4 supplies power to the power grid 5. When the power supply of the generator a 4 does not reach the standard power supply, the storage battery 10 provides power to the power grid 5.
[0062] The above description of the embodiments is to facilitate the understanding and use of the invention by those skilled in the art. It is obvious that those skilled in the art can easily make various modifications to these embodiments and apply the general principles described herein to other embodiments without creative work. Therefore, the present invention is not limited to the above embodiments, and improvements and modifications made by those skilled in the art based on the disclosure of the present invention without departing from the scope of the present invention should be within the scope of protection of the present invention.
Claims
1. A gas turbine co-combustion system coupled with solar ammonia and ammonia plasma, It is characterized in that Including gas turbine power generation components, pyrolysis ammonia production components and solar thermal power generation components; The gas turbine power generation assembly comprises a compressor (1), a combustion chamber (2), a turbine (3) and a generator a (4); The output end of the compressor (1) is connected to the input end of the combustion chamber (2) to input compressed gas into the combustion chamber (2). The combustion chamber (2) also inputs natural gas. The output end of the combustion chamber (2) is connected to the input end of the turbine (3). The turbine (3) is connected to a generator a (4) via a shaft. The pyrolysis ammonia production component comprises a urea heat exchange pyrolyzer a (6), a urea heat exchange pyrolyzer b (7) and a plasma generator (11); The urea heat exchange pyrolyzer a (6) and the urea heat exchange pyrolyzer b (7) are used to pyrolyze urea to obtain ammonia, the heat source of the urea heat exchange pyrolyzer a (6) is the tail gas discharged from the combustion chamber (2), and the heat source of the urea heat exchange pyrolyzer b (7) comes from a solar thermal power generation assembly; the ammonia is then respectively input into a plasma generator (11) and the combustion chamber (2), and the output end of the plasma generator (11) is connected to the input end of the combustion chamber (2); The solar thermal power generation component is connected to the pyrolysis ammonia production component and is used for heat exchange and power supply for the pyrolysis ammonia production component.
2. A gas turbine co-combustion system coupled with solar ammonia and ammonia plasma according to claim 1, It is characterized in that The mixing ratio of natural gas, ammonia and ammonia plasma in the combustion chamber (2) is (5-7): (3-2): (2-1).
3. A gas turbine co-combustion system coupled with solar ammonia and ammonia plasma according to claim 1, It is characterized in that The system further comprises an ammonia gas collecting box (12), wherein the ammonia gas collecting box (12) is respectively connected to the urea heat exchange pyrolyzer a (6), the urea heat exchange pyrolyzer b (7), the plasma generator (11) and the combustion chamber (2); ammonia gas obtained by pyrolyzing urea is first collected in the ammonia gas collecting box (12) and then respectively input into the plasma generator (11) and the combustion chamber (2).
4. A gas turbine co-combustion system coupled with solar ammonia and ammonia plasma according to claim 1, It is characterized in that The system further comprises a urea solution storage tank (8), which is respectively connected to the urea heat exchange pyrolyzer a (6) and the urea heat exchange pyrolyzer b (7) for providing urea.
5. A gas turbine co-combustion system coupled with solar ammonia and ammonia plasma according to claim 1, It is characterized in that The solar thermal power generation component is also connected to the plasma generator (11), and the solar thermal power generation component supplies power to the plasma generator (11).
6. A gas turbine co-combustion system coupled with solar ammonia and ammonia plasma according to claim 1, It is characterized in that The gas turbine co-firing system further comprises a waste heat furnace (14), the input end of which is respectively connected to the hot flow output end and the cold flow output end of the urea heat exchange pyrolyzer a (6), and the tail gas is treated by SCR flue gas denitration.
7. A gas turbine co-combustion system coupled with solar ammonia and ammonia plasma according to claim 1, It is characterized in that The solar power generation assembly comprises a solar thermal collector (9), a steam turbine (15), a generator b (16) and a storage battery (10) which are electrically connected in sequence; The generator b (16) is also electrically connected to the plasma generator (11), and the generator b (16) provides electrical energy to the plasma generator (11) and the storage battery (10).
8. A gas turbine co-combustion system coupled with solar ammonia and ammonia plasma according to any one of claim 7, It is characterized in that The generator a (4) and the storage battery (10) are respectively connected to the power grid (5) and supply power to the power grid (5); the storage battery (10) is used to provide electric energy to the power grid (5) when the power supply of the generator a (4) does not reach the standard power supply.
9. A gas turbine co-combustion system coupled with solar ammonia and ammonia plasma according to claim 1, It is characterized in that The turbine (3) is connected to the hot flow inlet of the urea heat exchanger pyrolyzer a (6) through a high-temperature fan (13) and is used to transport the tail gas to the urea heat exchanger pyrolyzer a (6).
10. A method for using a gas turbine co-combustion system coupled with solar ammonia and ammonia plasma as claimed in claim 1, It is characterized in that Urea is respectively input into a urea heat exchange pyrolyzer a (6) and a urea heat exchange pyrolyzer b (7) for heat exchange and cracking. The heat source of the urea heat exchange pyrolyzer a (6) comes from the tail gas in the combustion chamber (2), and the heat source of the urea heat exchange pyrolyzer b (7) comes from the solar thermal power generation assembly. Urea is cracked to generate ammonia, which is then output to a plasma generator (11) and a combustion chamber (2) respectively. The plasma generator (11) generates ammonia plasma and inputs it into the combustion chamber (2). The ammonia plasma and the ammonia are burned together with compressed gas from a compressor (1) and natural gas in the combustion chamber (2). The generated tail gas is input into a turbine (3) to perform work and drive a generator a (4) to generate electricity. The tail gas after the work is introduced into the urea heat exchange pyrolyzer a (6) to recover heat, and is finally discharged after being depleted by an SCR.
