The invention provides a method for preparing a nanoporous amorphous electrocatalytic electrode, which relates to the field of electrochemical catalysis. The method comprises the following steps: Step 1: Feed metal raw materials and non-metallic raw materials according to the ratio, stir evenly after melting, and cool down to obtain an electrocatalytic electrode alloy; the metal elements in the metal raw materials are iron, cobalt, nickel, copper, and zinc One or more of titanium, magnesium and molybdenum, the non-metallic element in the non-metallic raw material is one or more of silicon, phosphorus, nitrogen, boron and carbon; step 2: the obtained in step 1 The alloy is melted again and quenched to obtain an amorphous electrocatalytic electrode; Step 3: soak the amorphous electrocatalytic electrode obtained in step 2 in an etchant for reaction to obtain a nanoporous amorphous electrocatalytic electrode . The nanoporous amorphous electrocatalytic electrode prepared by the invention has a three-dimensional porous structure, a relatively high specific surface area, a highly active core-shell structure, and excellent electrocatalytic activity and electrical conductivity.