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This invention discloses a waterborne epoxy curing agent, its preparation method, and its application, belonging to the field of waterborne epoxy coating technology. It solves the problems of slow drying speed, poor flash rust resistance, inadequate water and salt spray resistance, and reliance on organic solvents in existing waterborne epoxy curing agents. The preparation method includes the following steps: adding an aliphatic polyamine to a reaction vessel, heating to 70-80°C, and then adding a mixture of epoxy resin and polyethylene glycol diglycidyl ether dropwise for an addition reaction; maintaining the temperature after the addition is complete, and then performing vacuum distillation; adding maleic anhydride oil to the product after vacuum distillation, and heating to 90-95°C for a reaction; cooling after the reaction, and then adding deionized water dropwise for emulsification to obtain the waterborne epoxy curing agent. This invention utilizes green, solvent-free production, and the resulting curing agent exhibits fast drying speed, excellent flash rust resistance, water resistance, and salt spray resistance.