Method for producing carbon dioxide from high-concentration carbon dioxide and special device thereof

Abstract

The invention discloses a method for producing carbon dioxide from high-concentration carbon dioxide and a special device thereof, and belongs to the technical field of air pollution prevention and new energy. According to the technical scheme, the method comprises the following steps: inputting high-concentration carbon dioxide into a special device, and cracking water under the action of a ferroheme molecular dimer to generate electrons, hydrogen protons and oxygen; carbon dioxide reacts with electrons and hydrogen protons to generate carbon monoxide and water, and an energy field is generated; carbon monoxide continues to react with electrons and hydrogen protons to generate elemental carbon and water, and an energy field is generated; and reacting the elemental carbon with carbon monoxide under the action of an energy field to generate carbon dioxide. Compared with the prior art, the method has the prominent substantive characteristics and remarkable progress of being novel in technical scheme, reliable in technology, free of secondary pollution, high in investment efficiency and quick in effect taking.

Description

Technical Field

[0001] The present invention relates to the field of air pollution prevention and control and new energy technology, and in particular to a method for producing carbon dioxide from high-concentration carbon dioxide and a special device thereof. Background Art

[0002] As a byproduct of fossil fuel combustion, carbon dioxide has brought about negative effects on humans and the ecological environment on which they depend for survival. According to statistics from the US NOAA, the concentration of carbon dioxide has continued to rise over the past 50 years, from 315ppm in 1958 to 408ppm in 2020; the amount of carbon dioxide emitted into the atmosphere by the combustion of various mineral fuels (such as coal, oil, and natural gas) around the world is as high as 18.5 to 24.2 billion tons per year, while the utilization rate is less than 1%. Such a low utilization rate is not only a waste of resources for carbon dioxide, which has a wide range of application value in industry and various sectors of the national economy, but also exacerbates the trend of global warming on which humans depend for survival.

[0003] At present, the concept of carbon dioxide capture, recycling and reuse is receiving more and more attention from experts in related fields. In September 2021, a scientific research team from the Tianjin Institute of Industrial Biotechnology, Chinese Academy of Sciences, used carbon dioxide as raw material for the first time in the laboratory, without relying on plant photosynthesis, to directly synthesize starch artificially, realizing the de novo synthesis of carbon dioxide to starch, and increasing the energy utilization efficiency to 3.5 times the working efficiency of plants. In 2017, the research team of the Dalian Institute of Chemical Physics of the Chinese Academy of Sciences developed a technology for hydrogenating carbon dioxide to gasoline, and in March 2022, the world's first 1,000 tons / year carbon dioxide hydrogenation to gasoline plant developed using this technology was successfully started up in Zoucheng Industrial Park, Shandong, and produced clean gasoline products that meet the National VI standard. The relevant technologies currently recorded for existing carbon dioxide are: C 3 O 2 It is a colorless gas with a high refractive index; density 1.114 g / cm 3 (0℃); melting point -111.3℃; boiling point 6.8℃; refractive index 1.4538; easy to polymerize and decompose when heated; generates malonic acid when in contact with water; reacts with ammonia to generate malonamide; needs to be stored below 13.3kPa pressure; is produced by thermal decomposition of malonic acid; is used to make malonate, improve fiber dyeing properties, etc. Therefore, how to effectively treat high-concentration carbon dioxide and produce carbon dioxide that can be used as a resource is still a technical problem that needs to be solved by those skilled in the art. Summary of the invention

[0004] The technical problem to be solved by the present invention is to overcome the deficiencies of the prior art and provide a new method for producing carbon dioxide from high-concentration carbon dioxide that is technically reliable, has no secondary pollution, has high investment efficiency and quick results.

[0005] Another technical problem to be solved by the present invention is to overcome the deficiencies of the prior art and provide a new, technically reliable, secondary pollution-free, high investment efficiency, and quick-acting special device for the method of producing carbon dioxide from carbon dioxide.

[0006] To solve the above technical problems, the present invention adopts the following technical scheme: a method for producing tricarbon dioxide from high-concentration carbon dioxide, which is special in that: the method comprises inputting high-concentration carbon dioxide into a special device, and water is cracked to generate electrons, hydrogen protons and oxygen under the action of ferrous heme molecule dimers; carbon dioxide reacts with electrons and hydrogen protons to generate carbon monoxide and water under the action of a cuprous catalyst, generating an energy field; carbon monoxide continues to react with electrons and hydrogen protons to generate elemental carbon and water under the action of a cuprous catalyst, generating an energy field; and elemental carbon reacts with carbon monoxide under the action of the energy field to generate tricarbon dioxide.

[0007] To further solve the above technical problems, the preferred solution of the above technical solution is: The above-mentioned heme molecule dimer is obtained by polymerizing the heme molecule and then adsorbing it on the surface of an activated carbon carrier, and the activated carbon carrier is placed in a reaction treatment body cavity in a dedicated device containing an electrolyte.

[0008] The process of water being cracked to generate electrons, hydrogen protons and oxygen under the action of the heme molecule dimer is as follows: an appropriate amount of water is introduced into a special device through a pipeline, and the water level is higher than the height of the activated carbon carrier to ensure that the activated carbon carrier is completely immersed in water; carbon dioxide is introduced into the special device through a fan, and is adsorbed by the heme molecules when passing through the activated carbon carrier. Under the induction of the chemical energy of carbon dioxide, resonance is generated between the heme molecule dimers; under the action of the resonance force, the divalent iron realizes electron migration to become trivalent iron, forming an electron hole; under the action of the resonance force, the trivalent iron seizes the extranuclear electrons of the hydrogen atoms of the water molecules to become divalent iron, thereby realizing the cracking of water, and the reaction formula is: The water molecules split into electrons, hydrogen protons and oxygen.

[0009] The carbon dioxide described above reacts with electrons and hydrogen protons under the action of cuprous catalyst to generate carbon monoxide and water. The process of generating the energy field is as follows: carbon dioxide moves from the bottom to the top of the dedicated device under the action of the fan, is adsorbed by the heme molecules when passing through the activated carbon carrier, and reacts with the electrons and hydrogen protons generated by water splitting under the action of cuprous catalyst. The reaction formula is: Generates carbon monoxide and water, creating an energy field.

[0010] The carbon monoxide described above continues to react with electrons and hydrogen protons under the action of cuprous catalyst to generate elemental carbon and water. The process of generating the energy field is as follows: carbon monoxide continues to react with electrons and hydrogen protons under the action of cuprous catalyst in the reaction disposal body cavity of the special device, and the reaction formula is: Generates elemental carbon and water, creating an energy field.

[0011] The process of the above-mentioned elemental carbon reacting with carbon monoxide to generate tricarbon dioxide under the action of an energy field is as follows: the elemental carbon reacts with carbon monoxide under the action of an energy field in a special device, and the reaction formula is: This generates carbon dioxide gas.

[0012] The high concentration of carbon dioxide mentioned above refers to a volume concentration greater than 30%.

[0013] To further solve the above-mentioned technical problems, the special device for producing tricarbon dioxide from high-concentration carbon dioxide described in the present invention comprises a vertical cylindrical canned body structure in which an upper tank body, a reaction disposal body and a lower tank body are fixedly connected as one. The special feature of the special device is that the special device is provided with a gas input system, a water cracking system, a gas reaction system, a gas output system and a water circulation system; the lower tank body is a carbon dioxide buffer zone, the upper tank body is a tricarbon dioxide buffer zone, and the reaction disposal body is a reaction disposal zone of a water cracking system and a gas reaction system; the reaction disposal zone of the water cracking system and the gas reaction system is set as 8 reaction disposal partitions with equal spacing and the same structure in the inner cavity of the reaction disposal body, each reaction disposal partition being fastened together by upper and lower disposal partitions, and its cavity is fully loaded with activated carbon that adsorbs heme molecule dimers, and a number of vents with a diameter of 5 mm are evenly distributed on the upper and lower disposal partitions.

[0014] To solve the above technical problems, the preferred solution of the above technical solution is: The gas input system described above is a carbon dioxide input pipeline with an inverted ∩-shaped structure and arranged parallel to the outer wall of the tank body, a fan is arranged on the top, the top of the fan is slightly lower than the upper end surface of the tank top, the inlet of the fan is connected to the air inlet pipe of the input pipeline, an air inlet detection valve is arranged on the wall of the air inlet pipe of the input pipeline, a valve is arranged at the interface end of the air inlet pipe, the fan outlet is connected to the air inlet pipe connecting pipe at the lower end of the tank body through an input pipeline equipped with a valve, the air inlet pipe connecting pipe is arranged perpendicular to the center line of the tank body, and its end is a closed structure, and a plurality of air outlet holes are arranged on its upper pipe wall; the gas output system is a gas output pipeline arranged at the top of the upper box body near the center of the box body, one end of which is connected to the inner cavity of the tank body, and the other end is connected to the arranged The inlet end of the induced draft fan is connected; the outlet end of the induced draft fan is connected to an output pipe connection, a gas detection valve is installed on the pipe wall, and a flange interface connected to the output pipeline is arranged at the end; the water circulation system is arranged that a water outlet pipe communicating with the inner cavity of the lower tank body is arranged on the outer side of the bottom box body of the lower tank body, a valve and a pressure pump are installed and connected to the water spray pipe arranged in parallel with the inner cavity of the upper tank body through a pipeline; a liquid level gauge parallel to the axis line is arranged in the inner cavity of the upper tank body, a submersible pump is arranged in the inner cavity of the upper tank body opposite to the liquid level gauge, the output end of the submersible pump is fixedly connected to an output connection pipe, and the output connection pipe is connected to a water inlet pipe arranged on the outer side of the bottom lower tank body communicating with the inner cavity of the lower tank body through a pipeline; valves and water outlet valves are arranged on the pipelines.

[0015] The method and special device for producing tricarbon dioxide from high-concentration carbon dioxide described in the present invention are special in that the method and special device are used as high-concentration carbon dioxide in new energy materials.

[0016] The method for producing tricarbon dioxide from high-concentration carbon dioxide and its special device described in the present invention are a gaseous product discovered by the applicant in the process of research and development of high-concentration carbon dioxide resource application. On August 27, 2024, the applicant submitted a test sample of "high-concentration carbon dioxide resource utilization conversion product" to Hefei Guangce Product Testing Institute Co., Ltd. On September 2, 2024, Hefei Guangce Product Testing Institute Co., Ltd. issued a test report with a report number of GC202409020010. The report records that the tricarbon dioxide content is 12.6%. In the process of research and development of high-concentration carbon dioxide resource application, the applicant reacts and treats the high-concentration carbon dioxide gas in a special device according to the method for producing tricarbon dioxide from high-concentration carbon dioxide described in the present invention, and then directly burns the produced product with the coal in the combustion furnace. According to the applicant's rough calculation, the fuel saving is between 30-50%, which not only shows that the tricarbon dioxide produced by high-concentration carbon dioxide described in the present invention is a new fuel for the fossil fuel industry, but also its energy-saving effect after combustion is very good, and it has a good prospect for promotion and application. This fully demonstrates that the method and device for producing tricarbon dioxide from high-concentration carbon dioxide of the present invention have the following outstanding substantive features and significant progress compared with the prior art, and the reasons are: One is the method for producing tricarbon dioxide from high-concentration carbon dioxide described in the present invention. The method described is that high-concentration carbon dioxide is input into a special device, water is cracked under the action of heme dimer to generate electrons, hydrogen protons and oxygen; carbon dioxide reacts with electrons and hydrogen protons under the action of cuprous catalyst to generate carbon monoxide and water, generating an energy field; carbon monoxide continues to react with electrons and hydrogen protons under the action of cuprous catalyst to generate elemental carbon and water, generating an energy field; elemental carbon reacts with carbon monoxide under the action of energy field to generate tricarbon dioxide. Compared with the existing technology, it is a novel, reliable technical measure, no secondary pollution, safe and environmentally friendly technical solution. This technical solution provides a reliable technical support for improving the living environment, reducing carbon dioxide emissions, processing the captured high-concentration carbon dioxide, and providing new energy. The implementation of this technical solution not only solves a storage technical problem for the captured high-concentration carbon dioxide, but also plays a positive role in reducing carbon dioxide emissions for related enterprises, providing new energy and reducing production costs, improving corporate economic benefits, and promoting national economic growth. At the same time, it creates necessary conditions for improving the atmospheric environment and human living environment, especially for reducing carbon dioxide emissions, solving the greenhouse effect, and creating a better living environment for human beings. Compared with the existing technology, it has the following outstanding substantive features and significant progress: The second is a special device for producing carbon dioxide from high-concentration carbon dioxide described in the present invention, including a vertical cylindrical canned body structure in which an upper tank body, a reaction disposal body and a lower tank body are fixedly connected as one body. The special feature of the device is that the special device is provided with a gas input system, a water splitting system, a gas reaction system, a gas output system and a water circulation system; the lower tank body is a carbon dioxide buffer zone, the upper tank body is a carbon dioxide buffer zone, the reaction disposal body is a reaction disposal zone of a water splitting system and a gas reaction system; the reaction disposal zone of the water splitting system and the gas reaction system is set as 8 reaction disposal interlayers with equal spacing and the same structure in the cavity of the reaction disposal body. Each reaction disposal partition is fastened together by the upper and lower disposal partitions, and its cavity is fully loaded with activated carbon that adsorbs heme molecule dimers. The upper and lower disposal partitions are evenly distributed with a number of 5mm diameter vents. This technical solution provides a reliable special device technical guarantee for the method of producing carbon dioxide from high-concentration carbon dioxide. Moreover, the implementation of this technical solution provides a new and technically reliable solution to avoid secondary pollution caused by air pollution and bring a new energy source to mankind. This is the special device for producing carbon dioxide from high-concentration carbon dioxide described in the present invention. Compared with the prior art, it has more prominent substantial characteristics and positive progress. BRIEF DESCRIPTION OF THE DRAWINGS

[0017] The accompanying drawings are included to provide a further understanding of the present invention, and are incorporated in and constitute a part of this specification. The accompanying drawings illustrate embodiments of the present invention and together with the description serve to explain the principles of the present invention. The same reference numerals in the drawings represent the same components.

[0018] In the attached picture: Figure 1 The figure is a schematic diagram of the overall structure of a special device for producing carbon dioxide from high-concentration carbon dioxide according to the present invention.

[0019] Figure 2 for Figure 1 Side view of .

[0020] Figure 3 for Figure 1 Another side view of .

[0021] Figure 4 This is a top view of a special device for producing carbon dioxide from high-concentration carbon dioxide according to the present invention.

[0022] The accompanying drawings are marked as follows: 1-liquid level gauge 2-upper tank body 3-maintenance window 4-water output pipe 5-water spray pipe 6-submersible pump 7-upper flange 8-reaction and treatment partition 8.1-upper treatment partition 8.2-activated carbon 8.3-lower treatment partition 8.4-vent 9-input water pipeline 10-boosting pump 11-input water valve 12-water outlet pipe 13-lower tank body 14-air outlet 15-intake pipe pipe 16-electrolyzed water observation port 17-lower flange 18-intake input pipeline 19-intake blower 20-gas output pipe pipe 21-gas outlet detection valve 22-gas output pipeline 23-intake detection valve 24-intake pipe valve 25-input pipeline intake pipe 26-reaction and treatment partition detection port 27-induced draft fan 28-circulating water detection valve 29-output water valve 30-circulating water output pipeline. DETAILED DESCRIPTION

[0023] The specific structure and implementation process of the method for producing tricarbon dioxide from high-concentration carbon dioxide and its special device of the present invention are described in detail below in conjunction with the embodiments, which shall not be understood as limiting the claims of the present invention in any sense.

[0024] Embodiment 1: Embodiment 1 of the present invention provides a method for producing tricarbon dioxide from high-concentration carbon dioxide, wherein the method is as follows: high-concentration carbon dioxide is input into a dedicated device, water is decomposed to generate electrons, hydrogen protons and oxygen under the action of a ferrous heme molecule dimer; carbon dioxide reacts with electrons and hydrogen protons under the action of a cuprous catalyst to generate carbon monoxide and water, generating an energy field; carbon monoxide continues to react with electrons and hydrogen protons under the action of a cuprous catalyst to generate elemental carbon and water, generating an energy field; elemental carbon then reacts with carbon monoxide under the action of the energy field to generate tricarbon dioxide.

[0025] To further solve the above technical problems, the preferred solution of the above technical solution is: The above-mentioned heme molecule dimer is obtained by polymerizing the heme molecule and then adsorbing it on the surface of an activated carbon carrier, and the activated carbon carrier is placed in a reaction treatment body cavity in a dedicated device containing an electrolyte.

[0026] The process of water being cracked to generate electrons, hydrogen protons and oxygen under the action of the heme molecule dimer is as follows: an appropriate amount of water is introduced into a special device through a pipeline, and the water level is higher than the height of the activated carbon carrier to ensure that the activated carbon carrier is completely immersed in water; carbon dioxide is introduced into the special device through a fan, and is adsorbed by the heme molecules when passing through the activated carbon carrier. Under the induction of the chemical energy of carbon dioxide, resonance is generated between the heme molecule dimers; under the action of the resonance force, the divalent iron realizes electron migration to become trivalent iron, forming an electron hole; under the action of the resonance force, the trivalent iron seizes the extranuclear electrons of the hydrogen atoms of the water molecules to become divalent iron, thereby realizing the cracking of water, and the reaction formula is: The water molecules split into electrons, hydrogen protons and oxygen.

[0027] The carbon dioxide described above reacts with electrons and hydrogen protons under the action of cuprous catalyst to generate carbon monoxide and water. The process of generating the energy field is as follows: carbon dioxide moves from the bottom to the top of the dedicated device under the action of the fan, is adsorbed by the heme molecules when passing through the activated carbon carrier, and reacts with the electrons and hydrogen protons generated by water splitting under the action of cuprous catalyst. The reaction formula is: Generates carbon monoxide and water, creating an energy field.

[0028] The carbon monoxide described above continues to react with electrons and hydrogen protons under the action of cuprous catalyst to generate elemental carbon and water. The process of generating the energy field is as follows: carbon monoxide continues to react with electrons and hydrogen protons under the action of cuprous catalyst in the reaction disposal body cavity of the special device, and the reaction formula is: Generates elemental carbon and water, creating an energy field.

[0029] The process of the above-mentioned elemental carbon reacting with carbon monoxide to generate tricarbon dioxide under the action of an energy field is as follows: the elemental carbon reacts with carbon monoxide under the action of an energy field in a special device, and the reaction formula is: This generates carbon dioxide gas.

[0030] The high concentration of carbon dioxide mentioned above refers to a volume concentration greater than 30%.

[0031] In order to further solve the above technical problems, the special device for producing carbon dioxide from high concentration carbon dioxide of the present invention (see Figure 1 , Figure 2 , Figure 3 , Figure 4), including a vertical cylindrical tank body structure in which an upper tank body 2, a reaction disposal body and a lower tank body 13 are fixedly connected as a whole through upper and lower flanges 7 and 17. The special device is provided with a gas input system, a water splitting system, a gas collision reaction system, a gas output system and a water circulation system on the vertical cylindrical tank body; in addition, a maintenance window 3 is provided on the tank top of the upper tank body 2; and pressure and temperature detection devices communicating with the inner cavity are respectively provided on the tube wall of the device. The water splitting system and the gas collision reaction system are arranged in the inner cavity of the reaction disposal body, and are provided with 8 reaction disposal partitions 8 with equal spacing and the same structure. The area close to the lower tank body 13 is the carbon dioxide buffer zone, and the area close to the upper tank body 2 is the carbon dioxide buffer zone. The areas of the 8 reaction disposal partitions 8 in the inner cavity of the reaction disposal body are the reaction disposal areas of the water splitting system and the gas reaction system; the 8 reaction disposal partitions 8 with equal spacing and the same structure are each reaction disposal partition 8 fastened together by an upper disposal partition 8.1 and a lower disposal partition 8.3, and the cavity is fully loaded with activated carbon 8.2 that adsorbs ferrous heme molecule dimers, and a plurality of vents 8.4 with a diameter of 5 mm are evenly distributed on the upper disposal partition 8.1 and the lower disposal partition 8.3.

[0032] To solve the above technical problems, the preferred solution of the above technical solution is: The gas input system described above is a carbon dioxide input pipeline with an inverted ∩-shaped structure and arranged parallel to the outer wall of the tank body. An air intake blower 19 with an input speed ≥35 m / s and an input pressure of 30-40 KPa is arranged on the top of the pipeline. The top of the air intake blower 19 is slightly lower than the upper end surface of the tank top. The inlet of the air intake blower 19 is connected to the air intake pipe 24 of the input pipeline. An air intake detection valve 23 is arranged on the wall of the air intake pipe 24 of the input pipeline. An air intake pipe valve 24 is arranged at the interface end of the air intake pipe. The outlet of the air intake blower 19 is connected to the air intake pipe connecting pipe 15 at the lower end of the tank body through an air intake pipeline 18 equipped with a valve. The air intake pipe connecting pipe 15 is arranged perpendicular to the center line of the tank body, and its end is a closed structure with a plurality of air outlet holes 14 on its upper pipe wall.

[0033] The above-mentioned gas output system is a gas output pipeline 22 provided at the top of the upper tank body 2 near the center of the tank body, one end of which is connected to the inner cavity of the tank body, and the other end is connected to the inlet end of the induced draft fan 27; the outlet end of the induced draft fan 27 is connected to an output pipe connection 20, a gas detection valve 21 is installed on the pipe wall, and a flange interface connected to the output pipeline is provided at the end.

[0034] The above-mentioned water circulation system is arranged in that a water outlet pipe 12 communicating with the inner cavity of the lower tank body is arranged on the outer side of the bottom tank body of the lower tank body 13, and an input water valve 11 and a pressure pump 10 are installed and connected to a water spray pipe 5 arranged parallel to the inner cavity of the upper tank body 2 through an input water pipeline 9; a liquid level gauge 1 parallel to the axis line is arranged in the inner cavity of the upper tank body 2, and a submersible pump 6 is arranged in the inner cavity of the upper tank body 2 opposite to the liquid level gauge 1, and a circulating water output pipe 4 is fixedly connected to the output end of the submersible pump 6, and the circulating water output pipe 4 is connected to a circulating water inlet pipe arranged on the outer side of the bottom communicating with the inner cavity of the lower tank body through a circulating water output pipeline 30.

[0035] The method for producing tricarbon dioxide from high-concentration carbon dioxide and the dedicated device described in Example 1 of the present invention are more suitable for conditions where the volume concentration of high-concentration carbon dioxide is 70-75% and the output of high-concentration carbon dioxide gas is 500-600 cubic meters / hour and needs to be treated.

[0036] The above is a method for producing carbon dioxide from high-concentration carbon dioxide and the specific structure of its dedicated device and a scheme for implementing the application process of Example 1 of the present invention.

[0037] Embodiment 2: Embodiment 2 of the present invention provides a method for producing tricarbon dioxide from high-concentration carbon dioxide, wherein the method described is as follows: high-concentration carbon dioxide is input into a dedicated device, water is decomposed to generate electrons, hydrogen protons and oxygen under the action of a ferrous heme molecule dimer; carbon dioxide reacts with electrons and hydrogen protons under the action of a cuprous catalyst to generate carbon monoxide and water, generating an energy field; carbon monoxide continues to react with electrons and hydrogen protons under the action of a cuprous catalyst to generate elemental carbon and water, generating an energy field; elemental carbon then reacts with carbon monoxide under the action of the energy field to generate tricarbon dioxide.

[0038] To further solve the above technical problems, the preferred solution of the above technical solution is: The above-mentioned heme molecule dimer is obtained by polymerizing the heme molecule and then adsorbing it on the surface of an activated carbon carrier, and the activated carbon carrier is placed in a reaction treatment body cavity in a dedicated device containing an electrolyte.

[0039] The process of water being cracked to generate electrons, hydrogen protons and oxygen under the action of the heme molecule dimer is as follows: an appropriate amount of water is introduced into a special device through a pipeline, and the water level is higher than the height of the activated carbon carrier to ensure that the activated carbon carrier is completely immersed in water; carbon dioxide is introduced into the special device through a fan, and is adsorbed by the heme molecules when passing through the activated carbon carrier. Under the induction of the chemical energy of carbon dioxide, resonance is generated between the heme molecule dimers; under the action of the resonance force, the divalent iron realizes electron migration to become trivalent iron, forming an electron hole; under the action of the resonance force, the trivalent iron seizes the extranuclear electrons of the hydrogen atoms of the water molecules to become divalent iron, thereby realizing the cracking of water, and the reaction formula is: The water molecules split into electrons, hydrogen protons and oxygen.

[0040] The carbon dioxide described above reacts with electrons and hydrogen protons under the action of cuprous catalyst to generate carbon monoxide and water. The process of generating the energy field is as follows: carbon dioxide moves from the bottom to the top of the dedicated device under the action of the fan, is adsorbed by the heme molecules when passing through the activated carbon carrier, and reacts with the electrons and hydrogen protons generated by water splitting under the action of cuprous catalyst. The reaction formula is: Generates carbon monoxide and water, creating an energy field.

[0041] The carbon monoxide described above continues to react with electrons and hydrogen protons under the action of cuprous catalyst to generate elemental carbon and water. The process of generating the energy field is as follows: carbon monoxide continues to react with electrons and hydrogen protons under the action of cuprous catalyst in the reaction disposal body cavity of the special device, and the reaction formula is: Generates elemental carbon and water, creating an energy field.

[0042] The process of the above-mentioned elemental carbon reacting with carbon monoxide to generate tricarbon dioxide under the action of an energy field is as follows: the elemental carbon reacts with carbon monoxide under the action of an energy field in a special device, and the reaction formula is: This generates carbon dioxide gas.

[0043] The high concentration of carbon dioxide mentioned above refers to a volume concentration greater than 30%.

[0044] In order to further solve the above technical problems, the special device for producing carbon dioxide from high concentration carbon dioxide of the present invention (see Figure 1 , Figure 2 , Figure 3 , Figure 4), including a vertical cylindrical tank body structure in which an upper tank body 2, a reaction disposal body and a lower tank body 13 are fixedly connected as a whole through upper and lower flanges 7 and 17. The special device is provided with a gas input system, a water splitting system, a gas collision reaction system, a gas output system and a water circulation system on the vertical cylindrical tank body; in addition, a maintenance window 3 is provided on the tank top of the upper tank body 2; and pressure and temperature detection devices communicating with the inner cavity are respectively provided on the tube wall of the device. The water splitting system and the gas collision reaction system are arranged in the inner cavity of the reaction disposal body, and are provided with 8 reaction disposal partitions 8 with equal spacing and the same structure. The area close to the lower tank body 13 is the carbon dioxide buffer zone, and the area close to the upper tank body 2 is the carbon dioxide buffer zone. The areas of the 8 reaction disposal partitions 8 in the inner cavity of the reaction disposal body are the reaction disposal areas of the water splitting system and the gas reaction system; the 8 reaction disposal partitions 8 with equal spacing and the same structure are each reaction disposal partition 8 fastened together by an upper disposal partition 8.1 and a lower disposal partition 8.3, and the cavity is fully loaded with activated carbon 8.2 that adsorbs ferrous heme molecule dimers, and a plurality of vents 8.4 with a diameter of 5 mm are evenly distributed on the upper disposal partition 8.1 and the lower disposal partition 8.3.

[0045] To solve the above technical problems, the preferred solution of the above technical solution is: The gas input system described above is a carbon dioxide input pipeline with an inverted ∩-shaped structure and arranged parallel to the outer wall of the tank body. An air intake blower 19 with an input speed ≥35 m / s and an input pressure of 30-40 KPa is arranged on the top of the pipeline. The top of the air intake blower 19 is slightly lower than the upper end surface of the tank top. The inlet of the air intake blower 19 is connected to the air intake pipe 24 of the input pipeline. An air intake detection valve 23 is arranged on the wall of the air intake pipe 24 of the input pipeline. An air intake pipe valve 24 is arranged at the interface end of the air intake pipe. The outlet of the air intake blower 19 is connected to the air intake pipe connecting pipe 15 at the lower end of the tank body through an air intake pipeline 18 equipped with a valve. The air intake pipe connecting pipe 15 is arranged perpendicular to the center line of the tank body, and its end is a closed structure with a plurality of air outlet holes 14 on its upper pipe wall.

[0046] The above-mentioned gas output system is a gas output pipeline 22 provided at the top of the upper tank body 2 near the center of the tank body, one end of which is connected to the inner cavity of the tank body, and the other end is connected to the inlet end of the induced draft fan 27; the outlet end of the induced draft fan 27 is connected to an output pipe connection 20, a gas detection valve 21 is installed on the pipe wall, and a flange interface connected to the output pipeline is provided at the end.

[0047] The above-mentioned water circulation system is arranged in that a water outlet pipe 12 communicating with the inner cavity of the lower tank body is arranged on the outer side of the bottom tank body of the lower tank body 13, and an input water valve 11 and a pressure pump 10 are installed and connected to a water spray pipe 5 arranged parallel to the inner cavity of the upper tank body 2 through an input water pipeline 9; a liquid level gauge 1 parallel to the axis line is arranged in the inner cavity of the upper tank body 2, and a submersible pump 6 is arranged in the inner cavity of the upper tank body 2 opposite to the liquid level gauge 1, and a circulating water output pipe 4 is fixedly connected to the output end of the submersible pump 6, and the circulating water output pipe 4 is connected to a circulating water inlet pipe arranged on the outer side of the bottom communicating with the inner cavity of the lower tank body through a circulating water output pipeline 30.

[0048] The method for producing tricarbon dioxide from high-concentration carbon dioxide and its special device described in Example 2 of the present invention are more suitable for medium carbon dioxide capture efficiency, and can provide production conditions with a high-concentration carbon dioxide volume content of not less than 75-80% and an output of high-concentration carbon dioxide gas of 800-900 cubic meters / hour.

[0049] The above is a method for producing carbon dioxide from high-concentration carbon dioxide and the specific structure of its dedicated device and a scheme for implementing the application process of Example 2 of the present invention.

[0050] Example 3 A method for producing tricarbon dioxide from high-concentration carbon dioxide is described in Example 3 of the present invention. The method described is that high-concentration carbon dioxide is input into a special device, and water is cracked to generate electrons, hydrogen protons and oxygen under the action of ferrous heme molecule dimers; carbon dioxide reacts with electrons and hydrogen protons under the action of a cuprous catalyst to generate carbon monoxide and water, generating an energy field; carbon monoxide continues to react with electrons and hydrogen protons under the action of a cuprous catalyst to generate elemental carbon and water, generating an energy field; elemental carbon then reacts with carbon monoxide under the action of the energy field to generate tricarbon dioxide.

[0051] To further solve the above technical problems, the preferred solution of the above technical solution is: The above-mentioned heme molecule dimer is obtained by polymerizing the heme molecule and then adsorbing it on the surface of an activated carbon carrier, and the activated carbon carrier is placed in a reaction treatment body cavity in a dedicated device containing an electrolyte.

[0052] The above-mentioned process of splitting water to generate electrons, hydrogen protons and oxygen is as follows: an appropriate amount of water is introduced into a special device through a pipeline, and the water level is higher than the height of the activated carbon carrier to ensure that the activated carbon carrier is completely immersed in water; carbon dioxide is introduced into the special device through a fan, and is adsorbed by the heme molecules when passing through the activated carbon carrier. Under the induction of the chemical energy of carbon dioxide, resonance is generated between the heme dimers; under the action of the resonance force, the divalent iron realizes electron migration to become trivalent iron, forming an electron hole; under the action of the resonance force, the trivalent iron seizes the extranuclear electrons of the hydrogen atoms of the water molecules to become divalent iron, thereby achieving water splitting, and the reaction formula is: The water molecules split into electrons, hydrogen protons and oxygen.

[0053] The process of the reaction of carbon dioxide with electrons and hydrogen protons described above is as follows: carbon dioxide moves from the bottom to the top of the dedicated device under the action of the fan, is adsorbed by the heme molecules when passing through the activated carbon carrier, and reacts with the electrons and hydrogen protons generated by water splitting under the action of the cuprous catalyst. The reaction formula is: Generates carbon monoxide and water, creating an energy field.

[0054] The process of the carbon monoxide continuing to react with the electrons and hydrogen protons generated by the cracking of water is as follows: the carbon monoxide continues to react with the electrons and hydrogen protons in the reaction disposal body cavity of the special device under the action of the cuprous catalyst, and the reaction formula is: Generates elemental carbon and water, creating an energy field.

[0055] The process of the above-mentioned elemental carbon reacting with carbon monoxide to generate tricarbon dioxide is as follows: the elemental carbon reacts with carbon monoxide in a special device under the action of an energy field, and the reaction formula is: This produces carbon dioxide gas.

[0056] The high-concentration carbon dioxide described in the above-mentioned method for producing tricarbon dioxide from high-concentration carbon dioxide has a volume concentration greater than 30%.

[0057] In order to further solve the above technical problems, the special device for producing carbon dioxide from high concentration carbon dioxide of the present invention (see Figure 1 , Figure 2 , Figure 3 , Figure 4), including a vertical cylindrical tank body structure in which an upper tank body 2, a reaction disposal body and a lower tank body 13 are fixedly connected as a whole through upper and lower flanges 7 and 17. The special device is provided with a gas input system, a water splitting system, a gas collision reaction system, a gas output system and a water circulation system on the vertical cylindrical tank body; in addition, a maintenance window 3 is provided on the tank top of the upper tank body 2; and pressure and temperature detection devices communicating with the inner cavity are respectively provided on the tube wall of the device. The water splitting system and the gas collision reaction system are arranged in the inner cavity of the reaction disposal body, and are provided with 8 reaction disposal partitions 8 with equal spacing and the same structure. The area close to the lower tank body 13 is the carbon dioxide buffer zone, and the area close to the upper tank body 2 is the carbon dioxide buffer zone. The areas of the 8 reaction disposal partitions 8 in the inner cavity of the reaction disposal body are the reaction disposal areas of the water splitting system and the gas reaction system; the 8 reaction disposal partitions 8 with equal spacing and the same structure are each reaction disposal partition 8 fastened together by an upper disposal partition 8.1 and a lower disposal partition 8.3, and the cavity is fully loaded with activated carbon 8.2 that adsorbs ferrous heme molecule dimers, and a plurality of vents 8.4 with a diameter of 5 mm are evenly distributed on the upper disposal partition 8.1 and the lower disposal partition 8.3.

[0058] To solve the above technical problems, the preferred solution of the above technical solution is: The gas input system described above is a carbon dioxide input pipeline with an inverted ∩-shaped structure and arranged parallel to the outer wall of the tank body. An air intake blower 19 with an input speed ≥35 m / s and an input pressure of 30-40 KPa is arranged on the top of the pipeline. The top of the air intake blower 19 is slightly lower than the upper end surface of the tank top. The inlet of the air intake blower 19 is connected to the air intake pipe 24 of the input pipeline. An air intake detection valve 23 is arranged on the wall of the air intake pipe 24 of the input pipeline. An air intake pipe valve 24 is arranged at the interface end of the air intake pipe. The outlet of the air intake blower 19 is connected to the air intake pipe connecting pipe 15 at the lower end of the tank body through an air intake pipeline 18 equipped with a valve. The air intake pipe connecting pipe 15 is arranged perpendicular to the center line of the tank body, and its end is a closed structure with a plurality of air outlet holes 14 on its upper pipe wall.

[0059] The above-mentioned gas output system is a gas output pipeline 22 provided at the top of the upper tank body 2 near the center of the tank body, one end of which is connected to the inner cavity of the tank body, and the other end is connected to the inlet end of the induced draft fan 27; the outlet end of the induced draft fan 27 is connected to an output pipe connection 20, a gas detection valve 21 is installed on the pipe wall, and a flange interface connected to the output pipeline is provided at the end.

[0060] The above-mentioned water circulation system is arranged in that a water outlet pipe 12 communicating with the inner cavity of the lower tank body is arranged on the outer side of the bottom tank body of the lower tank body 13, and an input water valve 11 and a pressure pump 10 are installed and connected to a water spray pipe 5 arranged parallel to the inner cavity of the upper tank body 2 through an input water pipeline 9; a liquid level gauge 1 parallel to the axis line is arranged in the inner cavity of the upper tank body 2, and a submersible pump 6 is arranged in the inner cavity of the upper tank body 2 opposite to the liquid level gauge 1, and a circulating water output pipe 4 is fixedly connected to the output end of the submersible pump 6, and the circulating water output pipe 4 is connected to a circulating water inlet pipe arranged on the outer side of the bottom communicating with the inner cavity of the lower tank body through a circulating water output pipeline 30.

[0061] The method for producing tricarbon dioxide from high-concentration carbon dioxide and its special device described in Example 3 of the present invention are more suitable for carbon dioxide capture efficiency, and can provide production conditions with a high-concentration carbon dioxide content of not less than 85-90% and an output of high-concentration carbon dioxide gas of 900 to 1000 cubic meters per hour.

[0062] The above is a method for producing carbon dioxide from high-concentration carbon dioxide and the specific structure of its dedicated device and a scheme for implementing the application process of Example 3 of the present invention.

Claims

1. A method for producing tricarbon dioxide from high-concentration carbon dioxide, characterized in that: The method described is as follows: high-concentration carbon dioxide is input into a special device, water is decomposed to generate electrons, hydrogen protons and oxygen under the action of ferrous heme molecule dimers; carbon dioxide reacts with electrons and hydrogen protons to generate carbon monoxide and water under the action of a cuprous catalyst, generating an energy field; carbon monoxide continues to react with electrons and hydrogen protons to generate elemental carbon and water under the action of a cuprous catalyst, generating an energy field; elemental carbon then reacts with carbon monoxide under the action of the energy field to generate tricarbon dioxide.

2. The method for producing tricarbon dioxide from high concentration carbon dioxide according to claim 1, characterized in that: The heme molecule dimer is obtained by polymerizing the heme molecule and then adsorbing it on the surface of an activated carbon carrier, and the activated carbon carrier is placed in a reaction treatment body cavity in a special device containing an electrolyte.

3. The method for producing tricarbon dioxide from high concentration carbon dioxide according to claim 1 or 2, characterized in that: The process of water splitting to generate electrons, hydrogen protons and oxygen under the action of heme dimers is as follows: a proper amount of water is input into a special device through a pipeline, and the water level is higher than the height of the activated carbon carrier to ensure that the activated carbon carrier is completely immersed in water; carbon dioxide is input into the special device through a fan, and is adsorbed by heme molecules when passing through the activated carbon carrier. Under the induction of the chemical energy of carbon dioxide, resonance is generated between heme dimers; under the action of the resonance force, divalent iron realizes electron migration to become trivalent iron, forming electron holes; under the action of the resonance force, trivalent iron seizes the extranuclear electrons of hydrogen atoms of water molecules to become divalent iron, thereby realizing the splitting of water, and the reaction formula is: The water molecules split into electrons, hydrogen protons and oxygen.

4. The method for producing tricarbon dioxide from high concentration carbon dioxide according to claim 1, characterized in that: The carbon dioxide reacts with electrons and hydrogen protons under the action of cuprous catalyst to generate carbon monoxide and water. The process of generating the energy field is as follows: the carbon dioxide moves from the bottom to the top of the special device under the action of the fan, is adsorbed by the heme molecules when passing through the activated carbon carrier, and reacts with the electrons and hydrogen protons generated by water splitting under the action of cuprous catalyst. The reaction formula is: Generates carbon monoxide and water, creating an energy field.

5. The method for producing tricarbon dioxide from high concentration carbon dioxide according to claim 1, characterized in that: The carbon monoxide continues to react with electrons and hydrogen protons under the action of the cuprous catalyst to generate elemental carbon and water. The process of generating the energy field is as follows: carbon monoxide continues to react with electrons and hydrogen protons under the action of the cuprous catalyst in the reaction disposal body cavity of the special device, and the reaction formula is: Generates elemental carbon and water, creating an energy field.

6. The method for producing tricarbon dioxide from high-concentration carbon dioxide according to claim 1, characterized in that: The process of the elemental carbon reacting with carbon monoxide to generate tricarbon dioxide under the action of the energy field is as follows: the elemental carbon reacts with carbon monoxide under the action of the energy field in a special device, and the reaction formula is: This generates carbon dioxide gas.

7. The method for producing tricarbon dioxide from high concentration carbon dioxide according to claims 1-6, characterized in that: The high concentration of carbon dioxide has a volume concentration greater than 30%.

8. A special device for producing carbon dioxide from high-concentration carbon dioxide as described in any one of claims 1 to 7, comprising a vertical cylindrical canned body structure in which an upper tank body, a reaction disposal body and a lower tank body are fixedly connected as one, and its special feature is that the special device is provided with a gas input system, a water splitting system, a gas reaction system, a gas output system, and a water circulation system; the lower tank body is a carbon dioxide buffer zone, the upper tank body is a carbon dioxide buffer zone, and the reaction disposal body is a reaction disposal zone of the water splitting system and the gas reaction system; the reaction disposal zone of the water splitting system and the gas reaction system is set as 8 reaction disposal interlayers with equal spacing and the same structure in the inner cavity of the reaction disposal body, each reaction disposal interlayer is fastened as one by upper and lower disposal partitions, and its cavity is fully loaded with activated carbon that adsorbs heme molecule dimers, and a plurality of vents with a diameter of 5 mm are evenly distributed on the upper and lower disposal partitions.

9. The special device for producing tricarbon dioxide from high-concentration carbon dioxide according to claim 8, characterized in that: The gas input system is a carbon dioxide input pipeline with an inverted ∩-shaped structure and arranged parallel to the outer wall of the tank body. A fan is arranged on the top of the pipeline, and the top of the fan is slightly lower than the upper end surface of the tank top. The inlet of the fan is connected to the air inlet pipe of the input pipeline. An air inlet detection valve is arranged on the wall of the air inlet pipe of the input pipeline. A valve is arranged at the interface end of the air inlet pipe. The fan outlet is connected to the air inlet pipe connecting pipe at the lower end of the tank body through an input pipeline equipped with a valve. The air inlet pipe connecting pipe is arranged perpendicular to the center line of the tank body, and its end is a closed structure with a plurality of air outlet holes on its upper pipe wall. The gas output system is a gas output pipeline arranged at the top of the upper box body near the center of the box body, one end of which is connected to the inner cavity of the tank body, and the other end is connected to the inlet pipe arranged The inlet end of the fan is connected; the outlet end of the induced draft fan is connected to an output pipe connection, a gas detection valve is installed on the pipe wall, and a flange interface connected to the output pipeline is provided at the end; the water circulation system is configured such that a water outlet pipe communicating with the inner cavity of the lower tank body is provided on the outer side of the bottom box body of the lower tank body, a valve and a pressure pump are installed and the water spray pipe arranged in parallel with the inner cavity of the upper tank body is connected through a pipeline; a liquid level gauge parallel to the axis line is provided in the inner cavity of the upper tank body, a submersible pump is provided in the inner cavity of the upper tank body opposite to the liquid level gauge, the output end of the submersible pump is fixedly connected to an output connection pipe, and the output connection pipe is connected to a water inlet pipe arranged on the outer side of the bottom lower tank body communicating with the inner cavity of the lower tank body through a pipeline; valves and water outlet valves are provided on the pipelines.

10. A method and a special device for producing carbon dioxide from high-concentration carbon dioxide according to any one of claims 1 to 9, characterized in that The method and the special device are used as the application of high concentration carbon dioxide in new energy materials.

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