Metallocene polyethene (PE) rich mineral paper and making method thereof

Abstract

The invention relates to metallocene polyethene (PE) rich mineral paper and a making method thereof. The metallocene polyethene (PE) rich mineral paper consists of an upper surface layer, a middle layer and a lower surface layer; the master batch of the upper surface layer comprises the following components in percentage by weight: 40 to 60 percent of titanium dioxide, 35 to 55 percent of metallocene PE, 0.5 to 1 percent of coupling agent, 0.5 to 1 percent of dispersing agent, 0.5 to 1 percent of flame retardant, 0.5 to 1 percent of compatilizer and 0.5 to 1 percent of slipping agent; the master batch of the middle layer comprises the following components: 40 to 60 percent of calcium carbonate powder, 35 to 55 percent of metallocene PE, 0.5 to 1 percent of titanate coupling agent, 0.5 to 1 percent of dispersing agent, 0.5 to 1 percent of flame retardant, 0.5 to 1 percent of compatilizer and 0.5 to 1 percent of slipping agent; and three-layer composited rich mineral paper is made by a three-layer calendering process. The metallocene PE rich mineral paper has the advantages of high tensile strength, moisture resistance, waterproofness, high dimensional stability, tearing and foldingresistance, stable physical dimension, high printing definition and the like.

Description

technical field

[0001] The invention relates to a stone paper and a manufacturing method thereof, in particular to a metallocene PE stone paper and a manufacturing method thereof. Background technique

[0002] Traditional paper is made of plant fibers such as wood, which does not have the properties of moisture resistance, corrosion resistance and mechanical processing, and cannot meet many special requirements. In the 1950s, plastics and calcium carbonate had appeared. Environmentally friendly synthetic paper produced by blown film method and casting method. Stone paper is the abbreviation of inorganic powder environmental protection stone paper. It is called "synthetic paper" in the paper industry. Calcium carbonate as the main raw material of the mineral resources, with polymer materials and a variety of inorganic substances as auxiliary raw materials, using the principle of polymer interface chemistry and filling modification technology, a reversible recycling process p...

Examples

preparation example Construction

[0055] (1) Preparation of surface layer masterbatch: first preheat the mixing pot to 100-110°C, then add titanium dioxide powder and metallocene PE, stir with a stirrer at low speed for 3-5 minutes, the speed of the stirrer is 80-150r / min , and then according to the order of coupling agent, dispersant, flame retardant, compatibilizer, and smooth agent, add them to the mixing pot every 3-5 minutes, adjust the speed of the agitator and stir at high speed for 8-10 minutes, the mixer The rotation speed of the kneading machine is 200-250r / min; then it is transferred to a vacuum kneader with a set temperature for kneading, the temperature of the kneader is set at 105-110°C, and the kneading time is 8-10 minutes. Put it into the mixing and granulating machine for mixing and granulation to obtain the surface layer masterbatch;

[0056] (2) Preparation of intermediate layer masterbatch: Preheat the mixing pot to 100-110°C, then add calcium carbonate powder and metallocene PE, stir with...

Embodiment 1

[0077] Follow the steps above, where

[0078] (1) The composition and formula of the surface layer masterbatch are calculated by weight percentage:

[0079] Titanium dioxide 40%

[0080] Metallocene PE 55%

[0081] Titanate coupling agent 1%

[0082] Dispersant 1%

[0083] Flame retardant 1%

[0084] Compatibilizer 0.5%

[0085] Slippery agent 0.5%;

[0086] (2) The composition and formula of the masterbatch of the middle layer are calculated by weight percentage:

[0087] Calcium carbonate powder 40%

[0088] Metallocene PE 55%

[0089] Titanate coupling agent 1%

[0090] Dispersant 1%

[0091] Flame retardant 1%

[0092] Compatibilizer 1%

[0093] Slippery agent 1%;

[0094] The weight of the surface layer masterbatch in the upper surface layer accounts for 3-8% of the total weight of the masterbatch, the weight of the surface layer masterbatch in the lower surface layer accounts for...

Embodiment 2

[0096] Follow the steps above, where

[0097] Described surface layer masterbatch composition and formula are calculated by weight percentage as:

[0098] Titanium dioxide 50%

[0099] Metallocene PE 47.2%

[0100] Titanate coupling agent 0.8%

[0101] Dispersant 0.5%

[0102] Flame retardant 0.5%

[0103] Compatibilizer 0.5%

[0104] Slippery agent 0.5%;

[0105] Described middle layer masterbatch composition and formula are calculated as by weight percentage:

[0106] Calcium carbonate powder 50%

[0107] Metallocene PE 47.2%

[0108] Titanate coupling agent 0.8%

[0109] Dispersant 0.5%

[0110]Flame retardant 0.5%

[0111] Compatibilizer 0.5%

[0112] Slip agent 0.5%.

[0113] The weight of the surface masterbatch in the upper surface layer accounts for 5% of the total weight of the masterbatch, the weight of the surface masterbatch in the lower surface layer accounts for 5% of t...

technical field

[0001] The invention relates to a stone paper and a manufacturing method thereof, in particular to a metallocene PE stone paper and a manufacturing method thereof. Background technique

[0002] Traditional paper is made of plant fibers such as wood, which does not have the properties of moisture resistance, corrosion resistance and mechanical processing, and cannot meet many special requirements. In the 1950s, plastics and calcium carbonate had appeared. Environmentally friendly synthetic paper produced by blown film method and casting method. Stone paper is the abbreviation of inorganic powder environmental protection stone paper. It is called "synthetic paper" in the paper industry. Calcium carbonate as the main raw material of the mineral resources, with polymer materials and a variety of inorganic substances as auxiliary raw materials, using the principle of polymer interface chemistry and filling modification technology, a reversible recycling process p...

Examples

preparation example Construction

[0055] (1) Preparation of surface layer masterbatch: first preheat the mixing pot to 100-110°C, then add titanium dioxide powder and metallocene PE, stir with a stirrer at low speed for 3-5 minutes, the speed of the stirrer is 80-150r / min , and then according to the order of coupling agent, dispersant, flame retardant, compatibilizer, and smooth agent, add them to the mixing pot every 3-5 minutes, adjust the speed of the agitator and stir at high speed for 8-10 minutes, the mixer The rotation speed of the kneading machine is 200-250r / min; then it is transferred to a vacuum kneader with a set temperature for kneading, the temperature of the kneader is set at 105-110°C, and the kneading time is 8-10 minutes. Put it into the mixing and granulating machine for mixing and granulation to obtain the surface layer masterbatch;

[0056] (2) Preparation of intermediate layer masterbatch: Preheat the mixing pot to 100-110°C, then add calcium carbonate powder and metallocene PE, stir with...

Embodiment 1

[0077] Follow the steps above, where

[0078] (1) The composition and formula of the surface layer masterbatch are calculated by weight percentage:

[0079] Titanium dioxide 40%

[0080] Metallocene PE 55%

[0081] Titanate coupling agent 1%

[0082] Dispersant 1%

[0083] Flame retardant 1%

[0084] Compatibilizer 0.5%

[0085] Slippery agent 0.5%;

[0086] (2) The composition and formula of the masterbatch of the middle layer are calculated by weight percentage:

[0087] Calcium carbonate powder 40%

[0088] Metallocene PE 55%

[0089] Titanate coupling agent 1%

[0090] Dispersant 1%

[0091] Flame retardant 1%

[0092] Compatibilizer 1%

[0093] Slippery agent 1%;

[0094] The weight of the surface layer masterbatch in the upper surface layer accounts for 3-8% of the total weight of the masterbatch, the weight of the surface layer masterbatch in the lower surface layer accounts for...

Embodiment 2

[0096] Follow the steps above, where

[0097] Described surface layer masterbatch composition and formula are calculated by weight percentage as:

[0098] Titanium dioxide 50%

[0099] Metallocene PE 47.2%

[0100] Titanate coupling agent 0.8%

[0101] Dispersant 0.5%

[0102] Flame retardant 0.5%

[0103] Compatibilizer 0.5%

[0104] Slippery agent 0.5%;

[0105] Described middle layer masterbatch composition and formula are calculated as by weight percentage:

[0106] Calcium carbonate powder 50%

[0107] Metallocene PE 47.2%

[0108] Titanate coupling agent 0.8%

[0109] Dispersant 0.5%

[0110]Flame retardant 0.5%

[0111] Compatibilizer 0.5%

[0112] Slip agent 0.5%.

[0113] The weight of the surface masterbatch in the upper surface layer accounts for 5% of the total weight of the masterbatch, the weight of the surface masterbatch in the lower surface layer accounts for 5% of t...