The invention discloses a raspberry structure Pd-Sn-O / Pd-Sn
composite material, which is obtained by taking stannous mono-sulphate and
palladium chloride as raw materials through
hydrothermal reaction and
calcination, the components are PdO, SnO2 and Pd2Sn, the
microstructure is a raspberry structure, and the size of a single
nanoparticle is 15-20 nm. The preparation method comprises the following steps: 1, preparing Pd / Sn-MOF; and 2, synthesis of PdO / SnO2 / Pd2Sn is carried out. A gas sensor based on Pd-Sn-O / Pd-Sn is characterized in that under the conditions that the test temperature is 77.32 DEG C and the test
humidity is 5%, the response rate to 2000 ppm H2 is 25000-30000%, the
response time is 1-2 s, and the
recovery time is 180-190 s; the detection gases are respectively H2, NO2, CO, NH3, H2S and CH4; under the condition that the concentration of the tested gas is the same, the selectivity to H2 is extremely high under the condition that the concentration of the tested gas is 1000 ppm, and the response rate of 1000 ppm H2 is 7000-8000%; according to the invention, under the condition that the
humidity is 0-90%, the response rate to H2 is achieved, that is, the
humidity resistance is achieved, and under the condition that the humidity is 90%, the response rate to H2 reaches 5000-6000%.