Carbon dioxide adsorption recovery method

Abstract

The invention relates to a carbon dioxide adsorption recovery method, and belongs to the field of environment protection. The carbon dioxide adsorption recovery method uses adamantyl porous polymers as a carbon dioxide absorption adsorption material, and comprises the following processes including an absorption adsorption process of contacting the adamantyl porous polymers and treatment objects soas to adsorb carbon dioxide, and a desorption process for of desorbing carbon dioxide from the adamantyl porous polymers adsorbingabsorbed with the carbon dioxide. The adamantyl porous polymers are used; the adsorption recovery of carbon dioxide gas is realized. The adamantyl porous polymers have good carbon dioxide adsorption performance.

Description

technical field

[0001] The invention relates to a method for absorbing and recovering carbon dioxide, which belongs to the field of environmental protection. Background technique

[0002] Carbon dioxide (carbon dioxide), chemical formula CO 2 . It is one of the main components in the air and a common greenhouse gas. A large amount of carbon dioxide gas is emitted into the atmosphere, which will cause climate change, bring about changes in the overall ecosystem, and affect food production and water supply. Therefore, all countries are promoting clean energy and reducing carbon emissions, and recycling captured carbon dioxide for reuse.

[0003] Carbon dioxide has a very wide range of uses. Carbon dioxide is an important raw material for plant photosynthesis; carbon dioxide can be injected into beverages to increase the pressure, make the beverage contain bubbles, and increase the taste when drinking, such as soda and beer. Solid carbon dioxide (or dry ice) will vaporize a...

Examples

Embodiment 1

[0044] (1) Preparation of octavinylsilsesquioxane Add 30 mL of vinyltriethoxysilane, 100 mL of acetone, 80 mL of concentrated hydrochloric acid and 80 mL of distilled water into a 500 mL round bottom flask in sequence. Stir at room temperature for 72 h, filter with suction, wash the filter cake with acetone and methanol several times, and dichloromethane and ethanol solution (V 二氯甲烷 / V 乙醇 =1:1) and dried under vacuum at 60 °C for 24 h to obtain octavinylsilsesquioxane.

[0045] (2) Adamantyl porous polymer: in N 2 In a 50 mL round bottom flask, add 1.00 g 1,3,5,7-tetraphenyladamantane, 1.44 g octavinylsilsesquioxane, 1.22 g anhydrous AlCl 3 and 20 mL of 1,2-dichloroethane, magnetically stirred for 1 h, heated to 80 °C and kept at this temperature for 24 h, filtered with suction, washed with anhydrous methanol successively, and then placed in a Soxhlet extractor, respectively The adamantyl porous polymer HPP-1 was obtained by using methanol and 1,2-dichloromethane as solvent...

Embodiment 2

[0049] (1) Preparation of octavinylsilsesquioxane Add 30 mL of vinyltriethoxysilane, 100 mL of acetone, 80 mL of concentrated hydrochloric acid and 80 mL of distilled water into a 500 mL round bottom flask in sequence. Stir at room temperature for 72 h, filter with suction, wash the filter cake with acetone and methanol several times, and dichloromethane and ethanol solution (V 二氯甲烷 / V 乙醇 =1:1) and dried under vacuum at 60 °C for 24 h to obtain octavinylsilsesquioxane.

[0050] (2) Adamantyl porous polymer: in N 2 Under atmosphere, add 1.00 g 1,3,5,7-tetraphenyladamantane, 2.35 g octavinylsilsesquioxane, 1.00 g anhydrous AlCl to a 50 mL round bottom flask 3 and 20 mL of 1,2-dichloroethane, magnetically stirred for 1 h, heated to 80 °C and kept at this temperature for 24 h, filtered with suction, washed with anhydrous methanol successively, and then placed in a Soxhlet extractor, Purified with methanol and 1,2-dichloromethane as solvents for 48 h respectively, and dried in v...

Embodiment 3

[0053] (1) Preparation of octavinylsilsesquioxane Add 30 mL of vinyltriethoxysilane, 100 mL of acetone, 80 mL of concentrated hydrochloric acid and 80 mL of distilled water into a 500 mL round bottom flask in sequence. Stir at room temperature for 72 h, filter with suction, wash the filter cake with acetone and methanol several times, and dichloromethane and ethanol solution (V 二氯甲烷 / V 乙醇 =1:1) and dried under vacuum at 60 °C for 24 h to obtain octavinylsilsesquioxane.

[0054] (2) Adamantyl porous polymer: in N 2 Under atmosphere, add 1.00 g 1,3,5,7-tetraphenyladamantane, 2.88 g octavinylsilsesquioxane, 0.63 g anhydrous AlCl to a 50 mL round bottom flask 3 and 20 mL of 1,2-dichloroethane, magnetically stirred for 1 h, heated to 80 °C and kept at this temperature for 24 h, filtered with suction, washed with anhydrous methanol successively, and then placed in a Soxhlet extractor, Purified with methanol and 1,2-dichloromethane as solvents for 48 h respectively, and dried in v...

technical field

[0001] The invention relates to a method for absorbing and recovering carbon dioxide, which belongs to the field of environmental protection. Background technique

[0002] Carbon dioxide (carbon dioxide), chemical formula CO 2 . It is one of the main components in the air and a common greenhouse gas. A large amount of carbon dioxide gas is emitted into the atmosphere, which will cause climate change, bring about changes in the overall ecosystem, and affect food production and water supply. Therefore, all countries are promoting clean energy and reducing carbon emissions, and recycling captured carbon dioxide for reuse.

[0003] Carbon dioxide has a very wide range of uses. Carbon dioxide is an important raw material for plant photosynthesis; carbon dioxide can be injected into beverages to increase the pressure, make the beverage contain bubbles, and increase the taste when drinking, such as soda and beer. Solid carbon dioxide (or dry ice) will vaporize a...

Examples

Embodiment 1

[0044] (1) Preparation of octavinylsilsesquioxane Add 30 mL of vinyltriethoxysilane, 100 mL of acetone, 80 mL of concentrated hydrochloric acid and 80 mL of distilled water into a 500 mL round bottom flask in sequence. Stir at room temperature for 72 h, filter with suction, wash the filter cake with acetone and methanol several times, and dichloromethane and ethanol solution (V 二氯甲烷 / V 乙醇 =1:1) and dried under vacuum at 60 °C for 24 h to obtain octavinylsilsesquioxane.

[0045] (2) Adamantyl porous polymer: in N 2 In a 50 mL round bottom flask, add 1.00 g 1,3,5,7-tetraphenyladamantane, 1.44 g octavinylsilsesquioxane, 1.22 g anhydrous AlCl 3 and 20 mL of 1,2-dichloroethane, magnetically stirred for 1 h, heated to 80 °C and kept at this temperature for 24 h, filtered with suction, washed with anhydrous methanol successively, and then placed in a Soxhlet extractor, respectively The adamantyl porous polymer HPP-1 was obtained by using methanol and 1,2-dichloromethane as solvent...

Embodiment 2

[0049] (1) Preparation of octavinylsilsesquioxane Add 30 mL of vinyltriethoxysilane, 100 mL of acetone, 80 mL of concentrated hydrochloric acid and 80 mL of distilled water into a 500 mL round bottom flask in sequence. Stir at room temperature for 72 h, filter with suction, wash the filter cake with acetone and methanol several times, and dichloromethane and ethanol solution (V 二氯甲烷 / V 乙醇 =1:1) and dried under vacuum at 60 °C for 24 h to obtain octavinylsilsesquioxane.

[0050] (2) Adamantyl porous polymer: in N 2 Under atmosphere, add 1.00 g 1,3,5,7-tetraphenyladamantane, 2.35 g octavinylsilsesquioxane, 1.00 g anhydrous AlCl to a 50 mL round bottom flask 3 and 20 mL of 1,2-dichloroethane, magnetically stirred for 1 h, heated to 80 °C and kept at this temperature for 24 h, filtered with suction, washed with anhydrous methanol successively, and then placed in a Soxhlet extractor, Purified with methanol and 1,2-dichloromethane as solvents for 48 h respectively, and dried in v...

Embodiment 3

[0053] (1) Preparation of octavinylsilsesquioxane Add 30 mL of vinyltriethoxysilane, 100 mL of acetone, 80 mL of concentrated hydrochloric acid and 80 mL of distilled water into a 500 mL round bottom flask in sequence. Stir at room temperature for 72 h, filter with suction, wash the filter cake with acetone and methanol several times, and dichloromethane and ethanol solution (V 二氯甲烷 / V 乙醇 =1:1) and dried under vacuum at 60 °C for 24 h to obtain octavinylsilsesquioxane.

[0054] (2) Adamantyl porous polymer: in N 2 Under atmosphere, add 1.00 g 1,3,5,7-tetraphenyladamantane, 2.88 g octavinylsilsesquioxane, 0.63 g anhydrous AlCl to a 50 mL round bottom flask 3 and 20 mL of 1,2-dichloroethane, magnetically stirred for 1 h, heated to 80 °C and kept at this temperature for 24 h, filtered with suction, washed with anhydrous methanol successively, and then placed in a Soxhlet extractor, Purified with methanol and 1,2-dichloromethane as solvents for 48 h respectively, and dried in v...

Images