Process for preparing polyester resins and fibers comprising regenerated bis (2-hydroxyethyl) terephthalate

CN119137183APending Publication Date: 2024-12-13SK CHEMICALS CO LTD
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Patent Information

Application Number
CN202380037788.0
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Priority Date
2022-05-09
Filing Date
2023-05-03
Publication Date
2024-12-13

AI Technical Summary

Technical Problem

The depolymerization reaction products of existing polyester resins contain a large amount of oligomers, resulting in the formation of side reaction products of diethylene glycol esters, affecting polymerization performance and product quality, and being difficult to control purity, limiting its use in packaging materials and fiber applications. Use of

Method used

Through multi-stage depolymerization reaction, combined with high performance liquid chromatography (HPLC) determination and compression polycondensation reaction, the content of diethylene glycol esters is controlled to be less than 2%, significantly reducing the formation of side reaction products, and preparing high-purity terephthalene diphenyl diphenyl Bis(2-hydroxyethyl) formate was carried out and polycondensation reaction was carried out under low vacuum to prepare polyester resin.

Benefits of technology

Recovery of high-purity bis(2-hydroxyethyl) terephthalate is achieved, and polyester resins and fibers with excellent heat resistance and quality are prepared, improving their performance in packaging and fiber applications.

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Abstract

The polyester resin of the present invention contains regenerated bis (2-hydroxyethyl) terephthalate of high purity, which contains a diethylene glycol ester content of a certain level or less, and thus has heat resistance and quality comparable to that of a native resin even if the polyester resin is regenerated by chemical recovery. In particular, the polyester fiber comprising the polyester resin of the present invention has excellent strength, elongation and processability, and thus can be used as an environmentally friendly fiber product.
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