The invention belongs to the technical field of extraction of
lithium from oilfield brine, and discloses a purification method and
system for extraction of
lithium from oilfield brine and high-
impurity lithium-rich liquid. The purification method comprises the following steps: step 1, adding a
sodium hydroxide solution into the high-
impurity lithium-rich liquid to adjust the pH value, then adding a
sodium carbonate solution, carrying out stirring reaction, and carrying out plate-frame pressure
filtration to obtain filter residues and filtrate; step 2, performing
ceramic ultrafiltration on the filtrate to obtain
produced water and concentrated water, and returning the concentrated water to the step 1 to participate in the stirring reaction again; and step 3, regulating the pH value of the
produced water with
hydrochloric acid, using the regulated
produced water as an adsorption
stock solution, and adsorbing and desorbing the adsorption
stock solution with an aluminum adsorbent to obtain a purified lithium-rich solution. According to the method, aiming at the situation that a large amount of
divalent metal ion impurities such as
calcium and
manganese are contained in the
oil field brine lithium extraction lithium-rich liquid, after preliminary
impurity removal is carried out through chemical
precipitation, deep impurity removal is carried out in combination with
ceramic ultrafiltration and the aluminum adsorbent, the service life of the
ceramic ultrafiltration and the aluminum adsorbent can be effectively prolonged, and the recycling of ceramic ultrafiltration concentrated water can also improve the yield of lithium ions.