Rare-earth modified aqueous alkyd resin antibacterial luminescent coating material

Abstract

The invention relates to a rare-earth modified aqueous alkyd resin antibacterial luminescent coating material. The rare-earth modified aqueous alkyd resin antibacterial luminescent coating material isprepared from the ingredients in parts by weight: 35.0-55.0 parts of rare-earth modified aqueous alkyd resin, 15.0-25.0 parts of fluorine modified aqueous alkyd resin, 0.0-25.0 parts of fillers, 1.2-6.0 parts of auxiliaries, 2.5-6.5 parts of solid glass micro-beads, 3.5-6.5 parts of film forming assistant and 10.0-30.0 parts of deionized water, wherein the rare-earth modified aqueous alkyd resinis mainly prepared from vegetable oil, an organic acid anhydride, a carboxylic acid Schiff base, polyol, benzoic acid, bis(hydroxymethyl)propionic acid, a rare-earth ethanol solution, a sodium ethoxide ethanol solution and a neutralizer through a reaction. The rare-earth modified aqueous alkyd resin antibacterial luminescent coating material disclosed by the invention has no need of adding luminescent powder and an antibacterial agent and has the characteristics of good aging resistance, difficulty in powdering, durable antibacterial performance, long luminescence duration and the like.

Description

technical field

[0001] The invention relates to the preparation of a water-based paint, in particular to a rare-earth modified water-based alkyd resin antibacterial luminous paint and a preparation method thereof, belonging to the technical field of water-based functional paints. Background technique

[0002] With the rapid development of my country's economy, coatings have been more and more widely used in industry and agriculture, national defense, scientific research and people's lives. Coatings are a kind of coating that is coated on the surface of objects and forms a film under certain conditions to protect and decorate. It is a kind of liquid or fixed material with specific functions. At present, there are some shortcomings in coatings, such as the surface of the decorated object is dull and unchanged, and the luminous effect cannot be displayed at night. Some raw materials are toxic or flammable and explosive, and have no environmental protection performance. Production...

Examples

Embodiment 1

[0035] A rare earth modified water-based alkyd resin X, the steps are as follows:

[0036] a) In the multifunctional reaction kettle, add 8.5 parts of dehydrated linseed oil, 7.8 parts of maleic anhydride, 2.2 parts of 1,4-butanediol, 5.8 parts of trimethylolpropane, dimethylol 1.8 parts of propionic acid and 8.0 parts of xylene, N 2 , to remove the O in the reactor 2 ;

[0037] b) Heat up to 105-110°C to reflux, keep it warm for 0.5h, remove part of the water, quickly raise the temperature to 150-160°C, stir fully until the material is dissolved, then stir and keep warm at a speed of 200-400 r / min for 1h , then heat up to 180°C at a speed of 20°C / h for 1 hour, add 1.4 parts of benzoic acid, continue to heat for 1 to 1.5 hours, heat up to 210 to 220°C at a speed of 20°C / h, and heat for 3.0 to 3.5 hours , until the measured acid value is consistent with the design value, the water produced by the reaction is separated by a water separator;

[0038]c) Cool down to 160°C at a...

Embodiment 2

[0041] A rare earth modified water-based alkyd resin Y, the steps are as follows:

[0042] a) In the multifunctional reaction kettle, add 9.5 parts of dehydrated soybean oil, 2.8 parts of acetic anhydride, 7.2 parts of adipic acid, 3.2 parts of neopentyl glycol, 5.3 parts of pentaerythritol, and dimethylol propane in order according to the weight of the formula. 1.6 parts of acid and 9.0 parts of xylene, N 2 , to remove the O in the reactor 2 ;

[0043] b) Heat up to 105-110°C to reflux, keep it warm for 0.5h, remove part of the water, quickly raise the temperature to 150-160°C, stir fully until the material is dissolved, then stir and keep warm at a speed of 200-400 r / min for 1h , then heat up to 180°C at a speed of 20°C / h for 1 hour, add 1.5 parts of benzoic acid, continue to heat for 1 to 1.5 hours, heat up to 210 to 220°C at a speed of 20°C / h, and heat for 3.0 to 3.5 hours , until the measured acid value is consistent with the design value, the water produced by the rea...

Embodiment 3

[0047] A rare earth modified water-based alkyd resin antibacterial luminous coating, which consists of: 40.0 parts of rare earth modified water-based alkyd resin X, 18.0 parts of fluorine-modified water-based alkyd resin, 4.5 parts of diatomaceous earth, titanium 5.5 parts of white powder, 3.5 parts of solid glass beads, 0.3 parts of leveling agent, 0.5 parts of wetting agent, 0.8 parts of dispersing agent, 0.6 parts of defoaming agent, 0.3 parts of anti-settling rheological agent, 2.5 parts of pH regulator, film forming 4.0 parts of additives, 19.5 parts of deionized water.

technical field

[0001] The invention relates to the preparation of a water-based paint, in particular to a rare-earth modified water-based alkyd resin antibacterial luminous paint and a preparation method thereof, belonging to the technical field of water-based functional paints. Background technique

[0002] With the rapid development of my country's economy, coatings have been more and more widely used in industry and agriculture, national defense, scientific research and people's lives. Coatings are a kind of coating that is coated on the surface of objects and forms a film under certain conditions to protect and decorate. It is a kind of liquid or fixed material with specific functions. At present, there are some shortcomings in coatings, such as the surface of the decorated object is dull and unchanged, and the luminous effect cannot be displayed at night. Some raw materials are toxic or flammable and explosive, and have no environmental protection performance. Production...

Examples

Embodiment 1

[0035] A rare earth modified water-based alkyd resin X, the steps are as follows:

[0036] a) In the multifunctional reaction kettle, add 8.5 parts of dehydrated linseed oil, 7.8 parts of maleic anhydride, 2.2 parts of 1,4-butanediol, 5.8 parts of trimethylolpropane, dimethylol 1.8 parts of propionic acid and 8.0 parts of xylene, N 2 , to remove the O in the reactor 2 ;

[0037] b) Heat up to 105-110°C to reflux, keep it warm for 0.5h, remove part of the water, quickly raise the temperature to 150-160°C, stir fully until the material is dissolved, then stir and keep warm at a speed of 200-400 r / min for 1h , then heat up to 180°C at a speed of 20°C / h for 1 hour, add 1.4 parts of benzoic acid, continue to heat for 1 to 1.5 hours, heat up to 210 to 220°C at a speed of 20°C / h, and heat for 3.0 to 3.5 hours , until the measured acid value is consistent with the design value, the water produced by the reaction is separated by a water separator;

[0038]c) Cool down to 160°C at a...

Embodiment 2

[0041] A rare earth modified water-based alkyd resin Y, the steps are as follows:

[0042] a) In the multifunctional reaction kettle, add 9.5 parts of dehydrated soybean oil, 2.8 parts of acetic anhydride, 7.2 parts of adipic acid, 3.2 parts of neopentyl glycol, 5.3 parts of pentaerythritol, and dimethylol propane in order according to the weight of the formula. 1.6 parts of acid and 9.0 parts of xylene, N 2 , to remove the O in the reactor 2 ;

[0043] b) Heat up to 105-110°C to reflux, keep it warm for 0.5h, remove part of the water, quickly raise the temperature to 150-160°C, stir fully until the material is dissolved, then stir and keep warm at a speed of 200-400 r / min for 1h , then heat up to 180°C at a speed of 20°C / h for 1 hour, add 1.5 parts of benzoic acid, continue to heat for 1 to 1.5 hours, heat up to 210 to 220°C at a speed of 20°C / h, and heat for 3.0 to 3.5 hours , until the measured acid value is consistent with the design value, the water produced by the rea...

Embodiment 3

[0047] A rare earth modified water-based alkyd resin antibacterial luminous coating, which consists of: 40.0 parts of rare earth modified water-based alkyd resin X, 18.0 parts of fluorine-modified water-based alkyd resin, 4.5 parts of diatomaceous earth, titanium 5.5 parts of white powder, 3.5 parts of solid glass beads, 0.3 parts of leveling agent, 0.5 parts of wetting agent, 0.8 parts of dispersing agent, 0.6 parts of defoaming agent, 0.3 parts of anti-settling rheological agent, 2.5 parts of pH regulator, film forming 4.0 parts of additives, 19.5 parts of deionized water.

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