237 results about "Luminous paint" patented technology

The invention discloses a preparation method of a light-emitting composite paint. The preparation method comprises the following steps: (1) preparing a graphene / long afterglow phosphor composite; and (2) dispersing 3-6 parts of graphene / kaolin / SiO2 composite material and 2-4 parts of a graphene / calcium carbonate / SiO2 composite into 15-20 parts of deionized water, processing for 90-120 minutes so as to form a solution A3, dispersing 1-5 parts of graphene / red-emit phosphor / SiO2 composite into 15-20 parts of deionized water, processing for 90-120 minutes so as to form a solution B3, dispersing 1-5 parts of graphene / long afterflow phosphor composite into 15-20 parts of deionized water, processing for 90-120 minutes so as to obtain a solution C1, respectively and slowly dropwise adding solutions B3 and C1 in the solution A3 until a mixed solution is formed under conditions of performing ultrasonic shaking at a frequency of 200-400KW and stirring at a centrifugal speed of 500-800r / min, adding 70-80 parts of film forming matter, and mixing and stirring uniformly, so as to obtain the light-emitting composite paint. The preparation method is capable of obviously improving the luminous intensity and luminous uniformity of a water-borne luminous paint, and further improving the dispersibility of phosphor in the paint and the construction performance and storage stability of the paint.

Flexible luminescent paints are prepared from physical blends of hybrid epoxy acrylic resins, cementicious acrylic resins and optionally pure acrylic coating resins together with monopropylene glycol, suspension additives, rheological additives and photoluminescent pigments. The luminescent paints exhibit bright, even and long-lasting photoluminescent afterglow, excellent flexibility in both thin and thick layers, and are suitable for spraying, brushing, rolling and screen printing. Optional fluorescent pigments may be utilized to give daylight coloration and up-convert the photoluminescent emissions to the fluorescent emissions color.

Luminous water paint containing long-lasting phosphorescence material coated with nano titanium dioxide and a preparation method thereof are disclosed, belonging to luminous water paint field and inorganic luminous paint and particularly luminous paint coating treatment technique. The preparation method includes the following steps: firstly, coating the long-lasting phosphorescence material with nano titanium dioxide, then preparing the water paint from the coated long-lasting phosphorescence material, film-forming emulsion resin, filler, addition agent and water. The luminous water paint has good stability to hydrolysis and good adhesive attraction; the paint film is of good water resistance, alkali resistance, weather resistance, high brightness and long after time. The luminous water paint is applicable in door and out of door and applicable to boats and road signs and is particularly suitable for underwater signs and road signs in pluvial regions.

The invention discloses a method for preparing multi-color long afterglow water borne luminescent coatings. The coating is prepared by taking a high molecular polymer formed by mutual polyreaction of three monomers through initiating agents as acrylic emulsion, taking the synthetic acrylic emulsion as a base resin of the coating and adding luminescent powder, auxiliary agents and fillers; the prepared multi-color long afterglow water borne luminescent coatings have good luminescent property, wear-resisting property, adhesion property and the like. The coatings feature simple preparation process and convenient construction, and compared with the traditional oil soluble luminescent coatings, the coatings discharge no noxious solvents and enjoy environment-friendly production process.

The invention relates to an alkali soil phosphate long afterglow emitting material and the method to manufacture that belongs to emitting material field. it is made up from weighting according to the ratio and grinding to equal, sintering for 5-12h under 950-1200 degree centigrade or 3-6h under 300-600 degree centigrade, cooling to room temperature, grinding again and sintering for 5-12h in reducing atmosphere to gain compounding. The emitting light could be from magenta to blue, and the afterglow could last for 5 hours.

The present invention relates to a energy-storing water-borne luminescent paint. Said invention adopts strontium aluminate activated by bivalent europium as luminescent powder, adopts the acrylic resin process or polyethylene wax process to make coating treatment of luminescent powder surface, so that it can raise the hydrolysis stability of luminescent powder. Said invention uses water epoxy resin emulsion as base material, and matches it with filling material, adjuvant and solidifying agent so as to obtain the invented luminescent paint. After the surface of body is coated with said paint, and dried, a luminescent coating layer is formed, after which is irradiated by UV ray, sun light and fluorescent lamp, the light energy can be stored by it, after the light source is removed.

The invention relates to multifunctional water borne luminescent coating. The weight portions of main raw materials of the coating are: 20 to 50 portions of water-soluble polymer emulsion, 20 to 50 portions of chitosan-acetic acid solution, 10 to 50 portions of coating-type long-afterglow luminescent powder, 0.2 to 1.0 portion of dispersant, 0.2 to 1.0 portion of thickener, 1.0 to 3.0 portions of film-forming additive and 0.1 to 0.3 portion of antifoaming agent. The luminescent coating which adopts the coating-type long-afterglow luminescent powder can ensure the long-term stable uniform distribution of the long-afterglow luminescent powder in water borne coating. The long-afterglow luminescent powder are bonded into a surface coating material polymer through chemical bonding action, which not only effectively improves the hydrolysis stability of the luminescent powder, but also further solves the deficiencies that inorganic luminescent powder is easy to precipitate and lose effectiveness in the water borne luminescent coating. In addition, the water borne luminescent coating has mildewproof and bactericidal effects, and the application range of the water borne luminescent coating is expanded.

The invention discloses a high-brightness long-afterglow luminescent indicator plate and a preparation method thereof. The preparation method comprises the following steps: pasting a reflective film on the front face of a substrate; spray-printing a luminous coating on the reflective film so as to form a graphical silkscreen; coating a diphenylethene-biphenyl sodium disulfonate fluorescent layer on the silkscreen; and coating a radiation-proof UV (ultraviolet) gloss oil protective layer on the reflective film which is not covered with graphs as well as the fluorescent layer. The preparation method of the luminous coating comprises the following steps: firstly pouring one third of a cristobalite transparent filler into a mixing tank, adding special light-transmitting resin, PE (polyethylene) resin and dioctyl phthalate (DOP), and then evenly stirring; and sequentially adding pigment, a nano rare-earth luminescent material, glass microspheres and the residual cristobalite transparent filler while stirring, and then evenly stirring for use. For the high-brightness long-afterglow luminescent indicator plate obtained by the preparation method, the brightness can reach 19,800mcd / m<2>, luminescence time can reach 10-14 hours in the case of single light absorption for 30 minutes, the minimum retro-reflection coefficient is cd.1*x<-1>m<-2> for various colors, the observation angle is 0.2 degree, and the incident angle is -4 degree. The high-brightness long-afterglow luminescent indicator plate has the advantages of endless cyclic energy storage, aging resistance, corrosion resistance, flame retardance, no toxicity, no harm, no radiation and energy conservation and is environmentally-friendly.

The nanometer modified long-afterglow energy-accumulating luminous paint features that it is prepared with nanometer titania 0.05-30 wt%, luminous pigment 10-50 wt%, filming material 30-60 wt%, pigment and stuffing 0-10 wt%, solvent 0-5 wt%, dispersant 0.01-5 wt% and other assistants 0-8 wt%. Its preparation process includes dispersing nanometer titania and dispersant inside partial solvent; adding luminous pigment powder, solvent, filming material and pigment and stuffing in certain proportion via stirring for 30-60 min; and adding other assistants and dispersing for other 10-30 min; and filteing. The nanometer modified long-afterglow energy-accumulating luminous paint has wide application in emergency lighting, indication mark and decoration engineering.

The invention relates to the field of paints and coatings, in particular to novel energy-storage luminous emulsion paint comprising a component A and a component B. The component A is prepared by mixing water, hydroxyethyl cellulose dispersing agents, defoamers, wetting agents, ammonia water, fungicide, coalescing agents, ethylene glycol, rutile titanium powder, luminescent powder, sericite powder, wollastonite powder, epoxy resin emulsion and thickening agents by mass parts. The component B is prepared by mixing water-based polyamide curing agents and deionized water by mass parts. The component A and the component B are mixed and prepared according to a weight ratio. The water-based epoxy resin emulsion is used as a base of the novel energy-storage luminous emulsion paint, so that the novel energy-storage luminous emulsion paint is nontoxic and incombustible and is safe and convenient to use. As the paint film has good curing performance, high luminous intensity with afterglow lasting for over 12 hours and zero radioactivity, the paint is environment-friendly energy-storage luminous paint. Since the energy-storage luminous powder subjected to treatments of coating has good hydrolytic stability, the water-based luminous paint is stable in preservation.

A ground level illumination system such as a road stud comprises a light source (12) positioned below ground level (8). An optics block (9) and a top block (2) transmit light from the source (12) to the exterior, the light rising at a shallow angle as a collimated beam in the top block (2) to emerge at a window (4) above the ground level (8). The window (4) is shaped to refract the light into a beam (16) that descends at a shallow angle relative to the ground level (8). The emerging beam (16) may be used to illuminate road markings (26) formed from luminous paint that can be re-charged by the illumination system. A feedback mechanism (82) can measure reflected light levels to maintain the optimal “charge” in the paint. A further element (84) of the system may also compare the intensity of reflected light at different wavelengths to detect the presence of fog.

The invention discloses a luminous paint for jet-printed advertisements, which consists of the following components in part by weight: 2 to 4 parts of toluene diisocynate; 6 to 8 parts of rare earth luminescent powder; 35 to 40 parts of acrylic resin, 0.1 to 0.2 part of organic argil; 5 to 10 parts of methylbenzene; 4 to 5 parts of butyl acetate; 2 to 8 parts of propylene glycol; 2 to 8 parts of n-butyl alcohol; 0.2 to 0.4 part of dioctyl phthalate; and 0.4 to 0.6 part of fatty acid polyglycol ester. The components are uniformly mixed, are milled in a ball mill for 1 to 2 hours and are then dispersed in a high-speed dispersion machine for 10 to 20 minutes, and thereby the luminous paint for jet-printed advertisements is prepared. The cost of the luminous paint for jet-printed advertisements is low, and the luminous paint for jet-printed advertisements can emit light at night.

The invention belongs to the field of construction coating and particularly discloses light-storing long-afterglow light-emitting coating and a preparation method thereof. The light-storing long-afterglow light-emitting coating comprises a light emitting layer and a light reflecting layer. The light emitting layer comprises, by weight, 20-60 parts of organic resin, 15-25 parts of ethanol, 10-50 parts of light-storing powder, 0.3-1.7 parts of octadecanamide, 0.5-5 parts of powdered PED wax, 0.1-1.5 parts of coupling agent, 0.2-1.6 parts of stabilizing agent, 0.1-1.5 parts of antioxidant, 5-25 parts of fluorescent whitening agent, 1-5 parts of fumed silica and 1-5 parts of sodium tripolyphosphate. The light reflecting layer comprises, by weight, 10-30 parts of epoxy resin, 30-60 parts of filler, 0.2-2 parts of film-forming auxiliary, 0.5-4 parts of pigment, 5-20 parts of quartz material, 2-4 parts of organic bentonite and 5-15 parts of dimethyl benzene. The light-storing long-afterglow light-emitting coating is long in light emitting time, fast in drying and high in brightness.

The present invention discloses a water energy-storing luminescent paint. It is a building paint made up by using water-soluble macromolecular resin, long-afterglow rare earth luminescent material, silicone sol, dispersing agent, film-forming adjuvant, defoaming agent and thickening agent through the processes of grinding, mixing and stirring. Said invented product paint does not precipitate and does not laminate, is non-toxic and harmless, contains no any radiation elements, can continuously stably luminesce for above 12 hr, and can be used as paint for building and marking plate.

The invention provides energy-storage light-emitting coating and a preparation method thereof. The energy-storage light-emitting coating comprises, by mass percentage, 15-25% of energy-storage light-emitting powder, 60-70% of waterborne resin, 1-2% of polyamide wax and the balance solvent, wherein the energy-storage light-emitting powder comprises, by mass percentage, 15-40% of strontium carbonate, 20-40% of barium meta-aluminate, 30-50% of aluminum oxide, 1.5-2.5% of dysprosium oxide and 1-2% of europium oxide. The preparation method includes: dissolving the polyamide wax into n-butyl alcohol, then mixing with the energy-storage light-emitting powder, performing ball milling and drying to obtain coated energy-storage light-emitting powder, and mixing the coated energy-storage light-emitting powder with the other components to obtain the energy-storage light-emitting coating. The energy-storage light-emitting coating is high in luminance and long in afterglow time after excitation, good in weather resistance and applicable to indoor and outdoor places such as city roads, tunnel walls, human landscapes, underground garages and building outer walls.

The invention discloses a method for preparing special pearl nuclei for cultivating blister pearls. The method comprises the following step of: coating colored luminous paint, luminous and fluorescent paint and magnetic paint on conventional blister pearl nuclei serving as seed nuclei to form colored luminous blister pearl nuclei, luminous blister pearl nuclei and magnetic luminous pearl nuclei respectively. The pearl nuclei are safe and non-toxic. High-quality special blister pearls can be cultivated by treating the pearl nuclei with an immunizing agent and performing nucleus insertion. The technology can greatly increase the additional value of the blister pearls.

The invention relates to a preparation method of an ultraviolet curing luminous coating which is prepared by the following formula according to the weight percentage: 1 percent to 20 percent of rare earth superlong afterglow luminescent material which is carried out the surface modification by vinylsilane coupling agent, 40 percent to 70 percent film-forming substance, 1 percent to 10 percent photoinitiator, 5 percent to 25 percent pigment and filler, 0 percent to 5 percent organic solvent or water, 0.01 percent to 5 percent dispersant, 0.01 percent to 5 percent defoamer and 1 percent to 8 percent other auxiliary agents. The preparation method has the advantages that: 1. the surface modified rare earth superlong afterglow luminescent material has better compatibility and simultaneously improves the luminous intensity of the luminous coating and prolongs the luminescence time; 2. the ultraviolet curing luminous coating not only has the luminous performance as the ordinary luminous coating, but is also characterized by rapid curing, good coating performance, no greatly volatile solvent, and the like; and 3. the preparation method is beneficial to the elimination of the environmental pollution and the saving of the organic solvent.

The invention discloses luminous paint for spray painted advertisements. The luminous paint for the spray painted advertisements comprises, by weight, 10-30 parts of epoxy resin, 10-30 parts of perchloro-ethylene resin, 5-8 parts of toluene diisocynate, 4-8 parts of kaolin, 2-10 parts of luminescent powder, 1-3 parts of titanium dioxide, 0.4-1 part of nanosilicon dioxide, 4-8 parts of butyl silicate, 0.5-3 parts of coalescing agents, 0.2-2 parts of anti-pollutant degerming agent and 15-35 parts of solvent. The luminous paint for the spray painted advertisements has the good anti-pollutant corrosion-resistant effect and especially has the anti-bacterial effect, and a formed paint film has high impact resistance.

The invention discloses a hyperbranched polyester rare earth complex containing a nitrogen heterocyclic terminal group, and a preparation method and a use thereof, wherein the hyperbranched polyester rare earth complex containing the nitrogen heterocyclic terminal group has the structural formula represented by the formula (I). The preparation method comprises the following steps: (1) hydroxyl-terminated hyperbranched polyester is modified by a modifier, the nitrogen heterocyclic terminal group is connected on a terminal hydroxyl, and thus hyperbranched polyester containing the nitrogen heterocyclic terminal group is obtained; and (2) the hyperbranched polyester containing the nitrogen heterocyclic terminal group, a second ligand and a rare earth soluble salt are dissolved in an organic solvent and undergo a reaction, and after the completion of the reaction, the hyperbranched polyester rare earth complex containing the nitrogen heterocyclic terminal group is obtained by separating from the reaction solution. With utilization of a coordination reaction of nitrogen atoms of the nitrogen heterocyclic group of the hyperbranched polyester with rare earth ions, the hyperbranched polyester rare earth complex containing the nitrogen heterocyclic terminal group is prepared; the rare earth complex is simple in synthesis method, is easy to process and mold, high in luminescent intensity and long in fluorescent lifetime, and can be used in the fields of display materials or luminous paints and the like.

The invention relates to a waterborne colorful luminous paint. The waterborne colorful luminous paint is characterized by comprising, by mass, 20.0 to 50.0% of emulsion, 2.0 to 3.0% of a film-forming aid, 1.0 to 2.0% of an anti-freezing agent, 0.15 to 0.5% of an antiseptic, 10.0 to 15.0% of a pigment filling material, 0.5 to 1.5% of a light-emitting agent, 10.0 to 25.0% of a protection glue solution, 0.3 to 0.5% of a dispersive wetting agent, 0.1 to 0.2% of an organosilicon antifoaming agent, 1.5 to 2.0% of a thickening agent, 0.1 to 0.2% of a neutralizing agent and 10.5 to 60.0% of water. The invention also provides a preparation method for the waterborne colorful luminous paint. The waterborne colorful luminous paint has decorative and protective functions on an exterior wall and has, even more beautiful, exterior wall decoration effect at night.

The preparation method of strontium aluminate series light-storing long-afterglow luminescent powder body material is characterized by that it uses industrial aluminium as raw material and makes it into alkoxy aluminium, then according to the sol-gel characteristics of alcohol salt makes the strontium carbonate, excitation agent and sensitizing agent produce reaction and implement latex covering treatment instead of traditional solid ball-grinding mixing process of make the luminescent precursor material obtain nano or molecular level combination, then makes the above-mentioned material undergo the processes of drying and calcination so as to obtain the invented product.

The invention discloses a carboxyl-terminated hyperbranched polyester rare earth complex as well as a preparation method and an application thereof. The carboxyl-terminated hyperbranched polyester rare earth complex is represented by a formula (I). The preparation method comprises steps as follows: carboxyl-terminated hyperbranched polyester, second ligands and rare-earth chloride or nitrate are dissolved in an organic solvent for a reaction, and the carboxyl-terminated hyperbranched polyester rare earth complex is separated from a reaction liquid after the reaction. The preparation method of the carboxyl-terminated hyperbranched polyester rare earth complex is simple, higher characteristic fluorescence of rare earth ions can be emitted, the fluorescence lifetime is longer, and the complex as a functional luminescent material can be used in the fields of a display material, a light amplification material or luminous paint and the like; compared with traditional fluorescent powder, the carboxyl-terminated hyperbranched polyester rare earth complex has better dispersibility and compatibility when added to epoxy resin.

The invention discloses a green lighting method for highway tunnels which effectively utilizes light energy. The inner wall of the tunnel is sprayed with energy-storage luminescent paint made of energy-storage luminescent materials, and the energy-storage luminescent reflective material is arranged in the tunnel along the contour of the tunnel. The energy-storage light-emitting reflective ring is equipped with energy-storage light-emitting reflective markings made of energy-storage light-emitting reflective materials on the tunnel road surface, and energy-storage light-emitting reflective protruding road signs made of energy-storage light-emitting reflective materials are set on the center line and both sides of the road surface. Energy-storage luminous reflective delineators made of energy-storage luminescent reflective materials are arranged on the tunnel walls on both sides. It has the characteristics of high efficiency, energy saving, environmental protection, safety and comfort, and compared with the tunnel mains lighting system, its facilities are simple, the construction is convenient, the cost is low, and it is easy to popularize and apply.

The invention relates to the field of coatings, in particular to a water-based acrylic acid energy-storage luminescent coating and a preparation method thereof. The water-based acrylic energy-storageluminescent coating comprises the following components, by weight, 20 to 30 parts of water, 0.1 to 0.3 part of dispersing agent, 0.1 to 0.3 part of a wetting agent, 0.01 to 0.1 part of an antifoamingagent, 10 to 30 parts of rare earth doped aluminate type long-acting luminescent powder, 5 to 10 parts of a luminescent powder pretreatment agent, 30 to 50 parts of an acrylic emulsion, 0 to 20 partsof a filling material, 0.2 to 0.5 part of a thickening agent A and 0.2 to 0.5 part of a thickening agent B. According to the invention, the water-based acrylic acid energy-storage luminescent coatingis prepared by limiting the compatibility of the water-based acrylic energy-storage luminescent coating, so that the hydrolysis stability of luminescent powder is improved, and the obtained water-based acrylic energy-storage luminescent coating is low in VOC content, non-flammable, safe and convenient to construct, high in paint film adhesion, good in weather resistance and high in luminescent intensity, and the afterglow time reaches 12 h or longer.

The invention discloses an ultraviolet cured rare earth polymer material and a preparation method thereof. The ultraviolet cured rare earth polymer material includes the following components in percentage by weight: 1%-20% of rare earth and acrylic acid complex, 40%-60% of urethane acrylate, 30-50% of active diluent, 1%-10% of photoinitiator and the balance of auxiliaries. The ultraviolet cured rare earth polymer material has the advantages that the rare earth and acrylic acid complex and the matrix resin are subjected to polymerization reaction, thus being good in consistency; the rare earth and acrylic acid complex modified resin is good fluorescence property and wide in ultraviolet absorption peak that the range stretch across the ultraviolet and near-ultraviolet areas; as the coating prepared by the above materials has the characteristics of being quick in photocuring speed, good in film property and friendly to environment; the film can be used for ultraviolet cured paint and luminous paint.

The invention discloses a design method for assisting in highway tunnel lighting through energy-storage luminous paint. Specific design schemes are provided for highway tunnels with different lengths, and according to the lengths, the tunnels are mainly divided into three kinds, namely the tunnels with the length smaller than 200 m, the tunnels with the length ranging from 200 m to 300 m and the tunnels with the length larger than 300 m. By means of the method for assisting in highway tunnel lighting through the energy-storage luminous paint, lighting lamps do not need to be arranged for the tunnels with the length smaller than 200 m, and the energy-storage luminous paint can be directly used for lighting. Lighting intensifying lamps can be omitted for the tunnels with the length ranging from 200 m to 300 m, basic lighting lamps are combined with the energy-storage luminous paint for lighting in daytime, and the lighting lamps can be closed and the energy-storage luminous paint is directly used for lighting at night. The energy-storage luminous paint is used for assisting in lighting for the tunnels with the length larger than 300 m, and at least 25% of original lighting design load power can be reduced. By means of the design method, continuous lighting and emergency lighting can be ensured, and the purpose of saving electric energy can be achieved.

The invention relates to a road isolating afforestation trough which comprises afforestation trough bodies. Planting troughs are arranged in the afforestation trough bodies; air inlet pipes are arranged in the planting troughs; the two sides of each afforestation trough body are coated with luminous paint; isolating troughs can be formed by aligning the front ends and the rear ends of the afforestation trough bodies; fence netting can further be arranged on the afforestation trough bodies, a lower frame of the fence netting is connected with fixing pieces which are prearranged on the afforestation trough bodies, and frames on the two sides of the fence netting are respectively connected and fixed through bolts. According to the road isolating afforestation trough, nutrient soil for planting is placed into the planting troughs, and then flowers and plants can be planted in the planting troughs.

The invention relates to a novel method for preparing anti-settling luminous acrylic resin by in-situ polymerization technology. For overcoming the defect that inorganic salt fluorescent powder (alkaline earth aluminates) is susceptible to settlement after being added in paint resin because of higher density, the method adopts a vinylsilane agent to modify the surface of the fluorescent powder first, and then prepares the acrylic resin with the fluorescent powder by using the in-situ polymerization technology. The invention has the advantages that: the luminous resin prepared by the in-situ polymerization technology makes the fluorescent powder bonded with macromolecular chains in the resin through chemical bonds so that the fluorescent powder is uniformly distributed and agglomeration is avoided and the anti-settling performance is obviously improved; and simultaneously the instability of a luminous paint is effectively improved, and the problem of nonuniform luminous brightness of the luminous coating sprayed on the surface of a product.