A mild plant surfactant and its application in shampoo

Abstract

The present invention provides a mild plant surfactant and its application in shampoo, and its components include: sea salt, plant extract, thickener, surfactant, hair conditioner, preservative, polyol, essence and water. The shampoo provided by the present invention can clean gently, and the hair is fluffy and shiny after use. At the same time, long-term use will not affect the use effect, and long-term use can be achieved; the present invention is combined with a specified production process, and the prepared shampoo can clean gently without excessively cleaning the sebum film, and can also reduce the problem of skin inflammation; the product has stable performance and delicate texture, and effectively removes cutin and grease without causing strong irritation to the skin.

Description

Technical Field

[0001] The invention relates to the technical field of daily chemicals, in particular to a mild plant surfactant and application thereof in shampoo. Background Art

[0002] The scalp skin is one of the skin tissues with the most hair follicles in the human epidermis. At the same time, the scalp skin is as sensitive as the facial skin. At the same time, due to living habits, diet, staying up late, genes and other factors, the scalp metabolites continue to increase, the scalp is full of oil and dirt, followed by hair loss, itching, and dandruff.

[0003] At present, daily chemicals use a lot of surfactants for cleaning. Common surfactants are chemical surfactants. However, chemical surfactants often cause more trouble to the skin due to excessive cleaning, and even damage the protective layer on the surface of the skin, causing more skin problems: excessive oil secretion, sensitivity, etc.

[0004] In response to the above situation, biosurfactants of pure natural cleaning products have appeared on the market, such as plant extracts, glycolipids, and biosurfactants produced by bacteria or fungi. Such surfactants often not only have a cleaning effect, but also are non-irritating to the skin, so they have very excellent prospects in the field of daily chemicals.

[0005] However, although there are many plants that can provide saponins, the content is relatively low; bacteria or fungi produce biosurfactants faster than those from animals or plants, and there are more types, but the production cost is high, the yield is low, and the downstream and recycling processes are expensive. At the same time, although biosurfactants are not irritating to the skin, the overall cleaning effect and stability are poor. Similarly, hair conditioners are often needed in shampoo products, which are used to protect the hair and repair the surface structure of the hair scales. Natural plant surfactants contain a large amount of triterpenoid saponins, which are mild and safe, and have antibacterial and anti-inflammatory, oil control and other effects. They have effective surface activity, are easy to rinse, and have no harmful residues. Summary of the invention

[0006] The object of the present invention is to provide a mild plant surfactant, which is a camellia oleifera kerogen extract.

[0007] Another aspect of the present invention provides a shampoo composition containing a mild plant surfactant, the components of which include:

[0008] Sea salt, plant extract, thickener, surfactant, hair conditioner, preservative, polyol, fragrance and water; wherein the plant extract comprises the camellia oleifera extract according to claim 1.

[0009] Preferably, the plant extract further comprises: rosemary extract, mirabilis leaf / stem extract, Bacillus fermentation product, cnidium monnieri extract, and peppermint extract.

[0010] Preferably, the thickener includes sodium chloride, polyacrylamide, C13-14 isoparaffin, laureth-7, and hydroxypropyl methylcellulose; the surfactant includes sodium coceth sulfate, cocamidopropyl betaine, sodium lauroyl sarcosinate, and sodium lauroyl glutamate.

[0011] Preferably, the preservatives include phenoxyethanol, sodium benzoate, and sodium acetate.

[0012] Preferably, the polyol includes isopropanol, butanediol, and 1,2-pentanediol.

[0013] Preferably, the hair conditioning agent includes decyl glucoside, guar hydroxypropyltrimonium chloride, quaternium-80, polyquaternium-10, and p-hydroxyacetophenone.

[0014] Preferably, the composition further comprises piroctone olamine salt.

[0015] Preferably, the particle size of the sea salt is 0.10-0.55 mm.

[0016] Another aspect of the present invention provides a shampoo cream, which is prepared from the shampoo composition containing a mild plant surfactant.

[0017] By adopting the above technical solution, the present invention has the following beneficial effects:

[0018] 1. The shampoo provided by the present invention can clean gently, and the hair becomes fluffy and shiny after use. At the same time, long-term use will not affect the use effect, and long-term use is possible;

[0019] 2. The present invention combines the specified production process to prepare a shampoo that can gently cleanse without excessively cleaning the sebum film, and can also reduce the problem of skin inflammation;

[0020] 3. This product has stable performance and fine texture. It can effectively remove dead skin and oil without causing strong irritation to the skin. BRIEF DESCRIPTION OF THE DRAWINGS

[0021] In order to more clearly illustrate the specific implementation methods of the present invention or the technical solutions in the prior art, the drawings required for use in the specific implementation methods or the description of the prior art will be briefly introduced below. Obviously, the drawings in the following description are some implementation methods of the present invention. For ordinary technicians in this field, other drawings can be obtained based on these drawings without paying creative work.

[0022] Figure 1 The condition of hair after three days of using a commercially available product;

[0023] Figure 2 This is the condition of the hair three days after using the product of Example 1. DETAILED DESCRIPTION

[0024] The technical solution of the present invention will be described clearly and completely below. Obviously, the described embodiments are only part of the embodiments of the present invention, not all of them. Based on the embodiments of the present invention, all other embodiments obtained by ordinary technicians in this field without creative work are within the scope of protection of the present invention.

[0025] The present invention provides a mild plant surfactant, wherein the surfactant is a camellia oleifera extract, namely a camellia (CAMELLIA JAPONICA) seed extract; the camellia (CAMELLIA JAPONICA) seed extract is purchased from the present invention, and the camellia (CAMELLIA JAPONICA) seed extract is purchased from Guangdong Jingcui Biotechnology Co., Ltd.

[0026] The invention provides a shampoo composition containing a mild plant surfactant, the components of which include sea salt, plant extract, thickener, surfactant, hair conditioner, preservative, polyol, essence and water.

[0027] In the present invention, the shampoo composition is named SJ1023.

[0028] Sea salt: Taking into account the user's experience, the particle size of the sea salt in the present invention is 0.10-0.8 mm; more preferably, considering the fluffy hair after use, the particle size of the sea salt is 0.10-0.55 mm; more preferably, it is 0.20-0.50 mm.

[0029] Plant extracts: including rosemary (ROSMARINUS OFFICINALIS) extract, MYROTHAMNUS FLABELLIFOLIA leaf / stem extract, Bacillus fermentation product, Cnidium monnieri (CNIDIUMMONNIERI) extract, and mint (MENTHA HAPLOCALYX) extract.

[0030] In the present invention, the rosemary (ROSMARINUS OFFICINALIS) extract was purchased from Shenzhen Zero One Biotechnology Co., Ltd., model: food grade; brand: Senyuan.

[0031] In the present invention, the MYROTHAMNUS FLABELLIFOLIA leaf / stem extract and Bacillus fermentation product are purchased from Guangzhou Shiming Chemical Co., Ltd.

[0032] In the present invention, the preparation method of the Cnidium monnieri extract is as follows:

[0033] Weigh sodium dodecylbenzenesulfonate and Cnidium monnieri powder, add 70% ethanol as an extraction solvent at a solid-liquid ratio of 1:20, extract for 2 hours, combine the extracts, filter to obtain a filtrate, and dry to obtain a Cnidium monnieri extract.

[0034] The mass ratio of sodium dodecylbenzene sulfonate to cnidium monnieri powder is 1:100.

[0035] In the present invention, the mint (MENTHA HAPLOCALYX) extract is purchased from Guangzhou Shengyuan Cosmetics Raw Materials Co., Ltd.

[0036] Thickener: In the present invention, the thickener includes sodium chloride, polyacrylamide, C13-14 isoparaffin, laureth-7, and hydroxypropyl methylcellulose.

[0037] Surfactant: The surfactant described in the present invention includes sodium cocoyl polyether sulfate, cocamidopropyl betaine, sodium lauroyl sarcosinate, and sodium lauroyl glutamate.

[0038] Preservatives: The preservatives described in the present invention include phenoxyethanol, sodium benzoate, and sodium acetate.

[0039] Polyol: The polyol described in the present invention includes isopropanol, butanediol, and 1,2-pentanediol.

[0040] Hair conditioning agent: The hair conditioning agent of the present invention includes decyl glucoside, guar hydroxypropyltrimonium chloride, quaternium-80, polyquaternium-10, and p-hydroxyacetophenone.

[0041] Preferably, the composition further comprises piroctone olamine salt.

[0042] Another aspect of the present invention provides a shampoo cream, which is prepared from the shampoo composition containing a mild plant surfactant.

[0043] In the present invention, the preparation method of the shampoo cream is as follows:

[0044] S01 first groups the components according to the preparation process requirements. The specific groups are as follows according to weight:

[0045] Component 1: 35 parts sea salt

[0046] Component 2: 25.67 parts water

[0047] Component 3: 13 parts of sodium chloride

[0048] Component 4: 4.9 parts water, 2.1 parts sodium cocoether sulfate

[0049] Component 5: 4.9 parts water, 0.35 parts sodium chloride, 1.75 parts cocamidopropyl betaine

[0050] Component 6: 1.84 parts water, 2.16 parts decyl glucoside

[0051] Component 7: 1.98 parts of water, 0.84 parts of sodium lauroyl sarcosinate, 0.12 parts of sodium chloride, 0.06 parts of sodium lauroyl glutamate

[0052] Component 8: 0.4 parts of polyacrylamide, 0.24 parts of C13-14 isoparaffin, 0.06 parts of laureth-7, 0.3 parts of water

[0053] Component 9: 0.297 parts of quaternary ammonium salt-80, 0.003 parts of isopropyl alcohol;

[0054] Component 10: 0.3 parts of flavor

[0055] Component 11: 0.2325 parts of guar hydroxypropyltrimonium chloride, 0.0175 parts of water

[0056] Component 12: 0.17064 parts of polyquaternium-10, 0.0054 parts of water, 0.0018 parts of sodium acetate, 0.0018 parts of sodium chloride, 0.00036 parts of isopropyl alcohol

[0057] Component 13: Hydroxypropyl methylcellulose 0.15 parts

[0058] Component 14: 0.0035 parts of rosemary (ROSMARINUS OFFICINALIS) extract, 0.0930 parts of water, 0.0030 parts of butylene glycol, and 0.005 parts of p-hydroxyacetophenone

[0059] Component 15: 2.676 parts of water, 0.3 parts of Camellia japonica extract, 0.018 parts of phenoxyethanol, and 0.006 parts of sodium benzoate

[0060] Component 16: 0.03 parts of MYROTHAMNUS FLABELLIFOLIA leaf / stem extract, 0.4639 parts of Bacillus fermentation product, 0.004 parts of p-hydroxyacetophenone, and 0.0021 parts of 1,2-pentanediol;

[0061] Component 17: 0.0175 parts of Cnidium monnieri extract, 0.465 parts of water, 0.015 parts of butylene glycol, and 0.0025 parts of p-hydroxyacetophenone;

[0062] Component 18: 0.0175 parts of Mentha HAPLOCALYX extract, 0.465 parts of water, 0.015 parts of butylene glycol, and 0.0025 parts of p-hydroxyacetophenone

[0063] Component 19: 0.15 parts of piroctone olamine salt

[0064] Component 21: 0.4 parts of phenoxyethanol.

[0065] S02 is preheated to dissolve components 4, 5, and 7, and heated with stirring at 50°C;

[0066] S03: Add component 1, component 14, component 17, and component 18 to the reaction pot in sequence, mix and stir at 60-65°C until they are completely dispersed; add the pre-treated component 2 and component 5 in sequence; stir evenly, and then add component 7 in sequence;

[0067] S04 starts low-speed homogenization and stirring, and adds component 2, component 8, component 9, and component 6 in step S03 in sequence; homogenize for 3-5 minutes, and stir and mix evenly;

[0068] S05: Add component 3, component 11, component 12, component 13, component 14 and component 16 into the above reaction pot, stir and emulsify for 10 minutes; after low-speed homogenization for 2 minutes, add the remaining components, stir and mix evenly.

[0069] The shampoo cream prepared by the above method can not only be stored stably for a long time, but also has a delicate skin feel, and the hair is fluffy and shiny after washing; and after the subject has used it for up to 1 year, it still has a good effect, and the effect will not be reduced due to long-term use. At the same time, the inventor of the present application found that the hair conditioner provided by the present invention combined with sea salt of a specific particle size has excellent wet combing and dry combing properties; the inventor speculated that the sea salt of a specific particle size plays a central role in the use process, and can play a role of "increasing charge density", so that the green surfactant and the remaining surfactants in the plant extract can form a large network structure, so that they can be attached to the surface of the hair. At the same time, in the subsequent cleaning process, the sea salt is easy to be rinsed clean, which also brings the overall hair easy to rinse, not easy to remain, non-sticky and other use feelings. At the same time, in conjunction with the above preparation method, the shampoo cream prepared by the present invention forms a multi-layer structure around the sea salt, and at the same time, water and oil form a coordination, so that the performance is stable.

[0070] The present invention is further explained below in conjunction with specific implementation modes.

[0071] Example 1: This example provides a shampoo composition, the components of which include: sea salt, plant extracts, thickeners, surfactants, hair conditioners, preservatives, polyols, fragrances, piroctone olamine salt and water.

[0072] The particle size of the sea salt is 0.20-0.50 mm.

[0073] Plant extracts: including rosemary (ROSMARINUS OFFICINALIS) extract, camellia oil (CAMELLIA JAPONICA) extract, MYROTHAMNUS FLABELLIFOLIA leaf / stem extract, Bacillus fermentation product, Cnidium monnieri (CNIDIUM MONNIERI) extract, and mint (MENTHA HAPLOCALYX) extract.

[0074] The rosemary (ROSMARINUS OFFICINALIS) extract was purchased from Shenzhen Zero One Biotechnology Co., Ltd., model: food grade; brand: Senyuan.

[0075] The Camellia japonica extract was purchased from Guangdong Jingcui Biotechnology Co., Ltd.

[0076] The MYROTHAMNUS FLABELLIFOLIA leaf / stem extract and Bacillus fermentation product were purchased from Guangzhou Shiming Chemical Co., Ltd.

[0077] The preparation method of the Cnidium monnieri extract is as follows:

[0078] Weigh sodium dodecylbenzenesulfonate and Cnidium monnieri powder, add 70% ethanol as an extraction solvent at a solid-liquid ratio of 1:20, extract for 2 hours, combine the extracts, filter to obtain a filtrate, and dry to obtain a Cnidium monnieri extract.

[0079] The mass ratio of sodium dodecylbenzene sulfonate to cnidium monnieri powder is 1:100.

[0080] In the present invention, the mint (MENTHA HAPLOCALYX) extract is purchased from Guangzhou Shengyuan Cosmetics Raw Materials Co., Ltd.

[0081] The thickener includes sodium chloride, polyacrylamide, C13-14 isoparaffin, laureth-7 and hydroxypropyl methylcellulose.

[0082] The surfactant includes sodium cocoyl sulfate, cocamidopropyl betaine, sodium lauroyl sarcosinate and sodium lauroyl glutamate.

[0083] The preservatives include phenoxyethanol, sodium benzoate and sodium acetate.

[0084] The polyols are isopropanol, butanediol and 1,2-pentanediol.

[0085] The hair conditioning agent includes decyl glucoside, guar hydroxypropyltrimonium chloride, quaternium-80, polyquaternium-10, and p-hydroxyacetophenone.

[0086] This embodiment also provides a shampoo cream and a preparation method thereof, the method is as follows:

[0087] S01 first groups the components according to the preparation process requirements. The specific groups are as follows according to weight:

[0088] Component 1: 35 parts of sea salt;

[0089] Component 2: 25.67 parts of water;

[0090] Component 3: 13 parts of sodium chloride;

[0091] Component 4: 4.9 parts of water, 2.1 parts of sodium cocoether sulfate;

[0092] Component 5: 4.9 parts of water, 0.35 parts of sodium chloride, 1.75 parts of cocamidopropyl betaine;

[0093] Component 6: 1.84 parts of water, 2.16 parts of decyl glucoside;

[0094] Component 7: 1.98 parts of water, 0.84 parts of sodium lauroyl sarcosinate, 0.12 parts of sodium chloride, 0.06 parts of sodium lauroyl glutamate;

[0095] Component 8: 0.4 parts of polyacrylamide, 0.24 parts of C13-14 isoparaffin, 0.06 parts of laureth-7, and 0.3 parts of water;

[0096] Component 9: 0.297 parts of quaternary ammonium salt-80, 0.003 parts of isopropyl alcohol;

[0097] Component 10: 0.3 parts of flavor;

[0098] Component 11: 0.2325 parts of guar hydroxypropyltrimonium chloride, 0.0175 parts of water;

[0099] Component 12: 0.17064 parts of polyquaternium-10, 0.0054 parts of water, 0.0018 parts of sodium acetate, 0.0018 parts of sodium chloride, and 0.00036 parts of isopropyl alcohol;

[0100] Component 13: 0.15 parts of hydroxypropyl methylcellulose;

[0101] Component 14: 0.0035 parts of rosemary (ROSMARINUS OFFICINALIS) extract, 0.0930 parts of water, 0.0030 parts of butylene glycol, and 0.005 parts of p-hydroxyacetophenone;

[0102] Component 15: 2.676 parts of water, 0.3 parts of Camellia japonica extract, 0.018 parts of phenoxyethanol, and 0.006 parts of sodium benzoate;

[0103] Component 16: 0.03 parts of MYROTHAMNUS FLABELLIFOLIA leaf / stem extract, 0.4639 parts of Bacillus fermentation product, 0.004 parts of p-hydroxyacetophenone, and 0.0021 parts of 1,2-pentanediol;

[0104] Component 17: 0.0175 parts of Cnidium monnieri extract, 0.465 parts of water, 0.015 parts of butylene glycol, and 0.0025 parts of p-hydroxyacetophenone;

[0105] Component 18: 0.0175 parts of mint (MENTHA HAPLOCALYX) extract, 0.465 parts of water, 0.015 parts of butylene glycol, and 0.0025 parts of p-hydroxyacetophenone;

[0106] Component 19: 0.15 parts of piroctone olamine salt;

[0107] Component 21: 0.4 parts of phenoxyethanol.

[0108] S02 is preheated to dissolve components 4, 5, and 7, and heated with stirring at 50°C;

[0109] S03: Add component 1, component 14, component 17, and component 18 to the reaction pot in sequence, mix and stir at 60-65°C until completely dispersed; add pre-treated component 4 and component 5 in sequence; stir evenly, and then add component 7 in sequence;

[0110] S04 starts low-speed homogenization and stirring, and adds component 2, component 8, component 9, and component 6 in step S03 in sequence; homogenize for 3-5 minutes, and stir and mix evenly;

[0111] S05: Add component 3, component 11, component 12, component 13, component 14 and component 16 into the above reaction pot, stir and emulsify for 10 minutes; after low-speed homogenization for 2 minutes, add the remaining components, stir and mix evenly.

[0112] Example 2: The difference from Example 1 is that the ingredients and weight parts are the same, but the preparation method is different. The preparation method of Example 2 is as follows:

[0113] S01 preheats the surfactant and thickener, and heats them at 50°C with stirring;

[0114] S02: Add sea salt and plant extracts to the reaction pot in sequence and mix and stir at 60-65°C until they are completely dispersed; add the pre-treated surfactant in sequence and stir evenly;

[0115] S03 starts low speed homogenization stirring, and water and hair conditioner are added in step S03 in sequence, and stirred to mix evenly;

[0116] S04 Add the remaining components to the above reaction pot, stir and emulsify for 10 minutes; homogenize at a low speed for 2 minutes, and stir and mix evenly.

[0117] Example 3: This example provides a shampoo composition, the components of which include: sea salt, plant extracts, thickeners, surfactants, hair conditioners, preservatives, polyols, fragrances, piroctone olamine salt and water.

[0118] The particle size of the sea salt is 0.8 mm.

[0119] Plant extracts: including rosemary (ROSMARINUS OFFICINALIS) extract, camellia oil (CAMELLIA JAPONICA) extract, MYROTHAMNUS FLABELLIFOLIA leaf / stem extract, Bacillus fermentation product, Cnidium monnieri (CNIDIUM MONNIERI) extract, and mint (MENTHA HAPLOCALYX) extract.

[0120] The rosemary (ROSMARINUS OFFICINALIS) extract was purchased from Shenzhen Zero One Biotechnology Co., Ltd., model: food grade; brand: Senyuan.

[0121] Camellia japonica extract was purchased from Guangdong Jingcui Biotechnology Co., Ltd.

[0122] The MYROTHAMNUS FLABELLIFOLIA leaf / stem extract and Bacillus fermentation product were purchased from Guangzhou Shiming Chemical Co., Ltd.

[0123] The preparation method of the Cnidium monnieri extract is as follows:

[0124] Weigh sodium dodecylbenzenesulfonate and Cnidium monnieri powder, add 70% ethanol as an extraction solvent at a solid-liquid ratio of 1:20, extract for 2 hours, combine the extracts, filter to obtain a filtrate, and dry to obtain a Cnidium monnieri extract.

[0125] The mass ratio of sodium dodecylbenzene sulfonate to cnidium monnieri powder is 1:100.

[0126] In the present invention, the mint (MENTHA HAPLOCALYX) extract is purchased from Guangzhou Shengyuan Cosmetics Raw Materials Co., Ltd.

[0127] The thickener includes sodium chloride, polyacrylamide, C13-14 isoparaffin, laureth-7 and hydroxypropyl methylcellulose.

[0128] The surfactant includes sodium cocoyl sulfate, cocamidopropyl betaine, sodium lauroyl sarcosinate and sodium lauroyl glutamate.

[0129] The preservatives include phenoxyethanol, sodium benzoate and sodium acetate.

[0130] The polyols are isopropanol, butanediol and 1,2-pentanediol.

[0131] The hair conditioning agent includes decyl glucoside, guar hydroxypropyltrimonium chloride, quaternium-80, polyquaternium-10, and p-hydroxyacetophenone.

[0132] This embodiment also provides a shampoo cream and a preparation method thereof, the method is as follows:

[0133] S01 first groups the components according to the preparation process requirements. The specific groups are as follows according to weight:

[0134] Component 1: 35 parts sea salt

[0135] Component 2: 25.67 parts water

[0136] Component 3: 13 parts of sodium chloride

[0137] Component 4: 4.9 parts water, 2.1 parts sodium cocoether sulfate

[0138] Component 5: 4.9 parts water, 0.35 parts sodium chloride, 1.75 parts cocamidopropyl betaine

[0139] Component 6: 1.84 parts water, 2.16 parts decyl glucoside

[0140] Component 7: 1.98 parts of water, 0.84 parts of sodium lauroyl sarcosinate, 0.12 parts of sodium chloride, 0.06 parts of sodium lauroyl glutamate

[0141] Component 8: 0.4 parts of polyacrylamide, 0.24 parts of C13-14 isoparaffin, 0.06 parts of laureth-7, 0.3 parts of water

[0142] Component 9: 0.297 parts of quaternary ammonium salt-80, 0.003 parts of isopropyl alcohol;

[0143] Component 10: 0.3 parts of flavor

[0144] Component 11: 0.2325 parts of guar hydroxypropyltrimonium chloride, 0.0175 parts of water

[0145] Component 12: 0.17064 parts of polyquaternium-10, 0.0054 parts of water, 0.0018 parts of sodium acetate, 0.0018 parts of sodium chloride, 0.00036 parts of isopropyl alcohol

[0146] Component 13: Hydroxypropyl methylcellulose 0.15 parts

[0147] Component 14: 0.0035 parts of rosemary (ROSMARINUS OFFICINALIS) extract, 0.0930 parts of water, 0.0030 parts of butylene glycol, and 0.005 parts of p-hydroxyacetophenone

[0148] Component 15: 2.676 parts of water, 0.3 parts of Camellia japonica extract, 0.018 parts of phenoxyethanol, and 0.006 parts of sodium benzoate

[0149] Component 16: 0.03 parts of MYROTHAMNUS FLABELLIFOLIA leaf / stem extract, 0.4639 parts of Bacillus fermentation product, 0.004 parts of p-hydroxyacetophenone, and 0.0021 parts of 1,2-pentanediol;

[0150] Component 17: 0.0175 parts of Cnidium monnieri extract, 0.465 parts of water, 0.015 parts of butylene glycol, and 0.0025 parts of p-hydroxyacetophenone;

[0151] Component 18: 0.0175 parts of Mentha HAPLOCALYX extract, 0.465 parts of water, 0.015 parts of butylene glycol, and 0.0025 parts of p-hydroxyacetophenone

[0152] Component 19: 0.15 parts of piroctone olamine salt

[0153] Component 21: 0.4 parts of phenoxyethanol.

[0154] S02 is preheated to dissolve components 4, 5, and 7, and heated with stirring at 50°C;

[0155] S03: Add component 1, component 14, component 17, and component 18 to the reaction pot in sequence, mix and stir at 60-65°C until completely dispersed; add pre-treated component 4 and component 5 in sequence; stir evenly, and then add component 7 in sequence;

[0156] S04 starts low-speed homogenization and stirring, and adds component 2, component 8, component 9, and component 6 in step S03 in sequence; homogenize for 3-5 minutes, and stir and mix evenly;

[0157] S05: Add component 3, component 11, component 12, component 13, component 14 and component 16 into the above reaction pot, stir and emulsify for 10 minutes; after low-speed homogenization for 2 minutes, add the remaining components, stir and mix evenly.

[0158] Example 4: This example provides a shampoo composition, the components of which include: sea salt, plant extracts, thickeners, surfactants, hair conditioners, preservatives, polyols, fragrances, piroctone olamine salt and water.

[0159] The particle size of the sea salt is 0.20-0.50 mm.

[0160] Plant extracts: including rosemary (ROSMARINUS OFFICINALIS) extract, camellia oil (CAMELLIA JAPONICA) extract, MYROTHAMNUS FLABELLIFOLIA leaf / stem extract, Bacillus fermentation product, Cnidium monnieri (CNIDIUM MONNIERI) extract, and mint (MENTHA HAPLOCALYX) extract.

[0161] The rosemary (ROSMARINUS OFFICINALIS) extract was purchased from Shenzhen Zero One Biotechnology Co., Ltd., model: food grade; brand: Senyuan.

[0162] The CAMELLIA JAPONICA seed extract was purchased from Guangdong Jingcui Biotechnology Co., Ltd.

[0163] The MYROTHAMNUS FLABELLIFOLIA leaf / stem extract and Bacillus fermentation product were purchased from Guangzhou Shiming Chemical Co., Ltd.

[0164] The preparation method of the Cnidium monnieri extract is as follows:

[0165] Weigh sodium dodecylbenzenesulfonate and Cnidium monnieri powder, add 70% ethanol as an extraction solvent at a solid-liquid ratio of 1:20, extract for 2 hours, combine the extracts, filter to obtain a filtrate, and dry to obtain a Cnidium monnieri extract.

[0166] The mass ratio of sodium dodecylbenzene sulfonate to cnidium monnieri powder is 1:100.

[0167] In the present invention, the mint (MENTHA HAPLOCALYX) extract is purchased from Guangzhou Shengyuan Cosmetics Raw Materials Co., Ltd.

[0168] The thickener includes sodium chloride, polyacrylamide, C13-14 isoparaffin, laureth-7 and hydroxypropyl methylcellulose.

[0169] The surfactant includes sodium cocoyl sulfate, cocamidopropyl betaine, sodium lauroyl sarcosinate and sodium lauroyl glutamate.

[0170] The preservatives include phenoxyethanol, sodium benzoate and sodium acetate.

[0171] The polyols are isopropanol, butanediol and 1,2-pentanediol.

[0172] The hair conditioning agent includes decyl glucoside, guar hydroxypropyltrimonium chloride, quaternium-80, polyquaternium-10, and p-hydroxyacetophenone.

[0173] This embodiment also provides a shampoo cream and a preparation method thereof, the method is as follows:

[0174] S01 first groups the components according to the preparation process requirements. The specific groups are as follows according to weight:

[0175] Component 1: 35 parts sea salt

[0176] Component 2: 25.67 parts water

[0177] Component 3: 13 parts of sodium chloride

[0178] Component 4: 4.9 parts water, 1.5 parts sodium cocoyl ether sulfate

[0179] Component 5: 4.9 parts water, 0.35 parts sodium chloride, 1.75 parts cocamidopropyl betaine

[0180] Component 6: 1.84 parts water, 1.62 parts decyl glucoside

[0181] Component 7: 1.98 parts of water, 0.84 parts of sodium lauroyl sarcosinate, 0.12 parts of sodium chloride, 0.06 parts of sodium lauroyl glutamate

[0182] Component 8: 0.4 parts of polyacrylamide, 0.24 parts of C13-14 isoparaffin, 0.06 parts of laureth-7, 0.3 parts of water

[0183] Component 9: 0.227 parts of quaternary ammonium salt-80, 0.003 parts of isopropyl alcohol;

[0184] Component 10: 0.3 parts of flavor

[0185] Component 11: 0.2325 parts of guar hydroxypropyltrimonium chloride, 0.0175 parts of water

[0186] Component 12: 0.17064 parts of polyquaternium-10, 0.0054 parts of water, 0.0018 parts of sodium acetate, 0.0018 parts of sodium chloride, 0.00036 parts of isopropyl alcohol

[0187] Component 13: Hydroxypropyl methylcellulose 0.15 parts

[0188] Component 14: 0.0035 parts of rosemary (ROSMARINUS OFFICINALIS) extract, 0.0930 parts of water, 0.0030 parts of butylene glycol, and 0.005 parts of p-hydroxyacetophenone

[0189] Component 15: 2.676 parts of water, 0.3 parts of Camellia japonica extract, 0.018 parts of phenoxyethanol, and 0.006 parts of sodium benzoate

[0190] Component 16: 0.03 parts of MYROTHAMNUS FLABELLIFOLIA leaf / stem extract, 0.4639 parts of Bacillus fermentation product, 0.004 parts of p-hydroxyacetophenone, and 0.0021 parts of 1,2-pentanediol;

[0191] Component 17: 0.0175 parts of Cnidium monnieri extract, 0.465 parts of water, 0.015 parts of butylene glycol, and 0.0025 parts of p-hydroxyacetophenone;

[0192] Component 18: 0.0175 parts of Mentha HAPLOCALYX extract, 0.465 parts of water, 0.015 parts of butylene glycol, and 0.0025 parts of p-hydroxyacetophenone

[0193] Component 19: 0.15 parts of piroctone olamine salt

[0194] Component 21: 0.4 parts of phenoxyethanol.

[0195] S02 is preheated to dissolve components 4, 5, and 7, and heated with stirring at 50°C;

[0196] S03: Add component 1, component 14, component 17, and component 18 to the reaction pot in sequence, mix and stir at 60-65°C until completely dispersed; add pre-treated component 4 and component 5 in sequence; stir evenly, and then add component 7 in sequence;

[0197] S04 starts low-speed homogenization and stirring, and adds component 2, component 8, component 9, and component 6 in step S03 in sequence; homogenize for 3-5 minutes, and stir and mix evenly;

[0198] S05: Add component 3, component 11, component 12, component 13, component 14 and component 16 into the above reaction pot, stir and emulsify for 10 minutes; after low-speed homogenization for 2 minutes, add the remaining components, stir and mix evenly.

[0199] Example 5: The difference from Example 1 is that the preparation method of the Cnidium monnieri extract is: weigh Cnidium monnieri powder, add 70% ethanol as an extraction solvent according to a solid-liquid ratio of 1:20, extract for 2 hours, combine the extracts, filter to obtain the filtrate, and dry to obtain the Cnidium monnieri extract.

[0200] Example 6: The difference from Example 1 is that the isopropanol in the formula is changed to n-propanol.

[0201] Performance test 1: Soothing effect test

[0202] Test method: copper sulfate was used to induce damage to the neuromast cells in the lateral line region of zebrafish embryos and cause neutrophil aggregation model for testing. 24 fish embryos were exposed to 0.16 mg / L copper sulfate pentahydrate and 10% formula added concentration of the combined sample solution provided in Examples 1-6, and a model control group was set up at the same time. After 40 minutes of exposure, the fish embryos were fixed and stained with Sudan black, and the number of neutrophils in the lateral line region was counted and statistically analyzed. The positive control group was 0.0036 mg / L indomethacin.

[0203] The test results are as follows:

[0204] Table 1 Test results of performance test 1

[0205]

[0206]

[0207] Performance test 2: Oil control efficacy test

[0208] Test method: It can be seen from performance test 1 that Example 1 has the best effect. 36 5-day-old zebrafish were divided into 3 groups and exposed to 10% of the formula added in Example 1. A blank control group was set up at the same time. After 24 hours of exposure, RNA extraction, cDNA synthesis, and real-time PCR amplification were performed on the zebrafish. β-actin was used as the housekeeping gene, and Ct was used as the amplification result. The relative expression of the 5α-reductase gene was calculated and statistically analyzed. After testing, the inhibition rates of the samples on the expression of zebrafish 5α-reductase genes srd5a1, srd5a2a, and srd5a2b were 38% (p=0.0022), 21% (p=0.031), and 30% (p=0.025) at the 10% added concentration of Example 1. Therefore, the samples can significantly inhibit the expression of zebrafish srd5a1, srd5a2a, and / or srd5a2b genes, have the effect of inhibiting fat secretion, and support the oil control efficacy claim.

[0209] Performance Test 3: Mild efficacy test.

[0210] By the closed patch test method, about 0.020g to 0.025g of the test substance was placed in the patch tester, and the test substance was applied to the back of the subject with a hypoallergenic tape. After 24 hours, the test substance was removed, and the skin reaction was observed at 0.5, 24, and 48 hours after removal, and the results were recorded according to the skin reaction grading standard in the "Safety Technical Specifications for Cosmetics" (2015 edition). The results of performance test 3 of Examples 1 to 6 were consistent, and there was no allergic reaction.

[0211] Table 2 Test results of performance test 3 of embodiment 1

[0212]

[0213] Performance test 4: Stability performance test

[0214] The shampoo cream prepared in Examples 1-6 was placed at 40°C and 10°C for 30 minutes each time for 10 cycles, and the relative humidity was kept at 60%. The shampoo cream was placed in an open 500 mL beaker and sealed with plastic wrap. After the experiment, the state of the shampoo cream was checked: unchanged, partially dissolved, and completely dissolved.

[0215] Table 3 Test results of performance test 4

[0216] Example Test 4 Example 1 Keep it the same Example 2 All dissolved Example 3 Partially dissolved Example 4 Partially dissolved Example 5 Partially dissolved Example 6 All dissolved

[0217] Finally, it should be noted that the above embodiments are only used to illustrate the technical solutions of the present invention, rather than to limit it. Although the present invention has been described in detail with reference to the aforementioned embodiments, those skilled in the art should understand that they can still modify the technical solutions described in the aforementioned embodiments, or replace some or all of the technical features therein with equivalents. However, these modifications or replacements do not cause the essence of the corresponding technical solutions to deviate from the scope of the technical solutions of the embodiments of the present invention.

Claims

1. A shampoo cream, characterized in that: The raw materials for its preparation include: Component 1: 35 parts of sea salt; Component 2: 25.67 parts of water; Component 3: 13 parts of sodium chloride; Component 4: 4.9 parts of water, 2.1 parts of sodium cocoether sulfate; Component 5: 4.9 parts of water, 0.35 parts of sodium chloride, 1.75 parts of cocamidopropyl betaine; Component 6: 1.84 parts of water, 2.16 parts of decyl glucoside; Component 7: 1.98 parts of water, 0.84 parts of sodium lauroyl sarcosinate, 0.12 parts of sodium chloride, 0.06 parts of sodium lauroyl glutamate; Component 8: 0.4 parts of polyacrylamide, 0.24 parts of C13-14 isoparaffin, 0.06 parts of laureth-7, and 0.3 parts of water; Component 9: 0.297 parts of quaternary ammonium salt-80, 0.003 parts of isopropyl alcohol; Component 10: 0.3 parts of flavor; Component 11: 0.2325 parts of guar hydroxypropyltrimonium chloride, 0.0175 parts of water; Component 12: 0.17064 parts of polyquaternium-10, 0.0054 parts of water, 0.0018 parts of sodium acetate, 0.0018 parts of sodium chloride, and 0.00036 parts of isopropyl alcohol; Component 13: 0.15 parts of hydroxypropyl methylcellulose; Component 14: 0.0035 parts of rosemary extract, 0.0930 parts of water, 0.0030 parts of butylene glycol, and 0.005 parts of p-hydroxyacetophenone; Component 15: 2.676 parts of water, 0.3 parts of camellia oleifera extract, 0.018 parts of phenoxyethanol, and 0.006 parts of sodium benzoate; Component 16: 0.03 parts of Milo leaf / stem extract, 0.4639 parts of Bacillus fermentation product, 0.004 parts of p-hydroxyacetophenone, and 0.0021 parts of 1,2-pentanediol; Component 17: 0.0175 parts of Cnidium monnieri extract, 0.465 parts of water, 0.015 parts of butylene glycol, and 0.0025 parts of p-hydroxyacetophenone; Component 18: 0.0175 parts of peppermint extract, 0.465 parts of water, 0.015 parts of butylene glycol, and 0.0025 parts of p-hydroxyacetophenone; Component 19: 0.15 parts of piroctone olamine salt; Component 21: 0.4 parts of phenoxyethanol; The particle size of the sea salt is 0.20-0.50 mm; The preparation method of the Cnidium monnieri extract is as follows: Weigh sodium dodecylbenzene sulfonate and cnidium monnieri powder, add 70% ethanol as an extraction solvent at a solid-liquid ratio of 1:20, extract for 2 h, combine the extracts, filter to obtain a filtrate, and dry to obtain a cnidium monnieri extract; The mass ratio of sodium dodecylbenzene sulfonate to cnidium monnieri powder is 1:100; The preparation method of the shampoo cream is as follows: Preheat and dissolve components 4, 5, and 7, and heat at 50°C with stirring; Add component 1, component 14, component 17, and component 18 to the reaction pot in sequence and mix and stir at 60-65°C until completely dispersed; add pre-treated component 4 and component 5 in sequence; stir evenly, and then add component 7 in sequence; Start low-speed homogenization and stirring, and add component 2, component 8, component 9, and component 6 in step S03 in sequence; Homogenize for 3-5 minutes, homogenize and disperse evenly, stir and mix evenly; Add component 3, component 11, component 12, component 13, component 14 and component 16 into the above reaction pot, stir and emulsify for 10 minutes; after low-speed homogenization for 2 minutes, add the remaining components, stir and mix evenly.

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