Defluorination material regeneration device and waste gas defluorination equipment
By setting up a detachable fluorine removal unit and a quick disassembly structure in the fluorine removal equipment, and using alkali and sulfuric acid to chemically regenerate fluorine removal materials, the problems of poor fluorine removal effect and waste of resources in the prior art have been solved, and the problem of poor fluorine removal effect and waste of resources has been achieved. Efficient fluorine removal treatment and resource recycling.
Patent Information
- Application Number
- CN202421102149.6
- Authority / Receiving Office
- CN · China
- Patent Type
- Utility models(China)
- Current Assignee / Owner
- Filing Date
- 2024-05-20
- Publication Date
- 2025-01-14
- Estimated Expiration
- 2034-05-20
AI Technical Summary
The existing fluorine removal equipment has poor fluorine removal effect and cannot recycle and recycle the fluorine removal raw materials, resulting in waste of resources and high operating costs.
A fluorine removal material regeneration device and exhaust gas fluorine removal equipment are designed. By setting a detachable fluorine removal unit and a rapid disassembly structure in the reaction body, the fluorine removal material is regenerated by chemical reaction using alkali liquid and sulfuric acid to achieve fluorine removal material. Recycling.
The fluorine removal effect is improved, the service life of the fluorine removal unit is extended, the replacement frequency and cost are reduced, the operation flexibility is increased, and the regeneration and utilization of used fluorine removal units is realized.
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Figure CN222342482U_ABST
Abstract
Description
Technical Field
[0001] The utility model relates to the technical field of waste gas treatment, in particular to a defluorination material regeneration device and waste gas defluorination equipment. Background Art
[0002] The waste gas from the chemical, smelting and pharmaceutical industries contains a large amount of fluoride, which can cause serious harm to animals, plants, humans and production equipment. Therefore, the flue gas needs to be purified to meet the standards required by the national environmental protection department for enterprises.
[0003] Patent CN208055476U uses alumina for defluorination. The raw materials in the storage tank are transported to the reaction tank for defluorination through the electrolysis device installed on the discharge pipe. Because the alumina powder is easy to compact and cannot be discharged smoothly, the system loses its defluorination function. Patent CN105251337A performs a desulfurization and defluorination process by performing a primary and secondary adsorption reaction with an internally circulating calcium hydroxide adsorbent in an adsorption reaction separator. The calcium hydroxide is difficult to remove after adsorption saturation. The above devices generally have the problem of poor defluorination effect and inability to regenerate and recycle the defluorination raw materials. Utility Model Content
[0004] Therefore, in order to overcome at least some of the defects and shortcomings of the prior art, the embodiments of the present utility model propose a defluorination material regeneration device and a waste gas defluorination equipment to solve the problem that the defluorination effect of the existing defluorination equipment is poor and the defluorination raw materials cannot be regenerated and recycled.
[0005] On the one hand, an embodiment of the utility model proposes a fluorine removal material regeneration device, comprising: a reaction body, having an inner cavity, the reaction body being provided with a first quick-release structure; a fluorine removal unit, arranged in the inner cavity, the fluorine removal unit being provided with a second quick-release structure, the second quick-release structure being detachably connected to the first quick-release structure; the fluorine removal unit comprising a fluorine removal material; an alkali solution tank and a sulfuric acid tank, respectively arranged on the reaction body and respectively connected to the inner cavity; wherein the fluorine removal material regeneration device comprises a first reaction state and a second reaction state, the alkali solution tank being used for outputting alkali solution to the fluorine removal unit when the fluorine removal material regeneration device is in the first reaction state, and the sulfuric acid tank being used for outputting sulfuric acid to the fluorine removal unit when the fluorine removal material regeneration device is in the second reaction state.
[0006] In one embodiment of the utility model, it also includes: a first collecting tank and a second collecting tank, the first collecting tank and the second collecting tank are respectively arranged at the bottom of the reaction body and are respectively connected to the inner cavity; wherein, the first collecting tank is used for collecting the liquid after the reaction in the inner cavity when the defluorination material regeneration device is in the first reaction state, and the second collecting tank is used for collecting the liquid after the reaction in the inner cavity when the defluorination material regeneration device is in the second reaction state.
[0007] In one embodiment of the utility model, the alkali solution tank and the sulfuric acid tank are respectively arranged on opposite sides of the reaction body, the first collecting tank and the second collecting tank are respectively arranged on opposite sides of the reaction body, and the alkali solution tank and the second collecting tank are located on the same side of the reaction body.
[0008] In one embodiment of the utility model, the defluorination unit comprises: a shell, on which the second quick-release structure is arranged; a defluorination filler arranged inside the shell, and the defluorination filler comprises the defluorination material.
[0009] In one embodiment of the utility model, the defluorination filler further comprises a Raschig ring filler, the Raschig ring filler is arranged inside the shell, and the defluorination material is arranged on the surface of the Raschig ring filler.
[0010] In one embodiment of the present invention, the Raschig ring filler is a honeycomb filler.
[0011] In one embodiment of the present invention, the defluorination material includes basic zirconium sulfate material.
[0012] On the other hand, an embodiment of the utility model provides a waste gas defluorination device, including: an equipment body, the equipment body is provided with an air inlet and an air outlet, and the equipment body is provided with a third quick-release structure; a defluorination unit, the defluorination unit is located between the air inlet and the air outlet, and the defluorination unit is provided with a second quick-release structure, and the second quick-release structure is detachably connected to the third quick-release structure; the defluorination unit includes a defluorination material.
[0013] In one embodiment of the utility model, the defluorination unit includes: a shell, on which the second quick-release structure is arranged, the shell is a tubular structure, the shell is connected to the device body and the shell is a component of the device body; a defluorination filler is arranged in the tubular cavity of the shell, and the defluorination filler includes the defluorination material.
[0014] In one embodiment of the utility model, the defluorination filler further comprises a Raschig ring filler, the Raschig ring filler is arranged inside the shell, and the defluorination material is arranged on the surface of the Raschig ring filler; the defluorination material comprises a basic zirconium sulfate material.
[0015] It can be seen from the above that the above technical features of the utility model can have the following beneficial effects:
[0016] The embodiment of the utility model sets a defluorination unit in the inner cavity of the reaction body, and sets a first quick-release structure and a second quick-release structure, so that the defluorination unit can be detachably connected to the reaction body through the first quick-release structure and the second quick-release structure. When the defluorination unit is removed from the reaction body, the defluorination unit can be used in a defluorination device for defluorination treatment of waste gas to remove fluorine in the waste gas. For example, the defluorination unit includes a basic zirconium sulfate material. The basic zirconium sulfate can be used to chemically react with the fluorine in the fluorine-containing waste gas, and the generated products include, for example, zirconium fluoride solid and other fluorine-containing composite salt solutions. After the defluorination treatment is completed, the defluorination unit can be regenerated in the reaction body of the defluorination material regeneration device. Specifically, the defluorination unit after the defluorination treatment is completed is first connected to the reaction body through the first quick-release structure, and then the alkali solution tank is opened, so that the defluorination material regeneration device is in the first reaction state. In the first reaction state, the alkali solution tank outputs alkali solution to the defluorination unit, and the alkali solution reacts chemically with zirconium fluoride to generate zirconium dioxide and fluoride solution. Then open the sulfuric acid tank, so that the defluorination material regeneration device is in the second reaction state. In the second reaction state, the sulfuric acid tank outputs sulfuric acid to the defluorination unit, and zirconium dioxide can be acidified and transformed with sulfuric acid to generate regenerated alkaline washed zirconium sulfate and fluorozirconic acid solution, etc. The regenerated alkaline washed zirconium sulfate can continue to be used for defluorination of fluorine-containing waste gas, and the fluoride solution can be further processed and recycled. In this way, since the defluorination unit can be easily disassembled, the defluorination unit can not only be regenerated in the defluorination material regeneration device, but also can be disassembled from the defluorination material regeneration device and transferred to other defluorination equipment for defluorination of fluorine-containing waste gas, which increases the flexibility of operation and the scope of use of the defluorination unit, and can make the used defluorination unit be recycled, reducing the frequency and cost of replacing the defluorination unit. BRIEF DESCRIPTION OF THE DRAWINGS
[0017] In order to more clearly illustrate the technical solutions of the embodiments of the utility model, the drawings required for use in the description of the embodiments will be briefly introduced below. Obviously, the drawings described below are only some embodiments of the utility model. For ordinary technicians in this field, other drawings can be obtained based on these drawings without creative work.
[0018] Figure 1 A schematic structural diagram of a defluorination material regeneration device provided in an embodiment of the utility model.
[0019] Figure 2 A schematic structural diagram of a waste gas defluorination device provided in an embodiment of the utility model.
[0020] Figure 3 for Figure 1 Schematic diagram of the structure of the defluorination unit.
[0021] [Description of Reference Numerals]
[0022] 10: defluorination material regeneration device; 20: waste gas defluorination equipment; 100: reaction body; 101: inner cavity; 104: first quick-release structure; 110: defluorination unit; 1101: second quick-release structure; 111: outer shell; 112: defluorination filler; 120: alkali solution tank; 130: sulfuric acid tank; 140: first collecting tank; 150: second collecting tank; 200: equipment body; 202: air inlet; 203: air outlet; 210: third quick-release structure. DETAILED DESCRIPTION
[0023] The following will be combined with the drawings in the embodiments of the utility model to clearly and completely describe the technical solutions in the embodiments of the utility model. Obviously, the described embodiments are only part of the embodiments of the utility model, not all of the embodiments. Based on the embodiments of the utility model, all other embodiments obtained by ordinary technicians in this field without creative work are within the scope of protection of the utility model.
[0024] The embodiment of the utility model provides a defluorination material regeneration device 10 and a waste gas defluorination device 20. The waste gas defluorination device 20 is suitable for treating fluorine-containing waste gas and is easy to operate. The defluorination material regeneration device 10 can recycle the defluorination material and reduce the consumption of the defluorination material. In order to more clearly describe the defluorination material regeneration device 10 and the waste gas defluorination device 20 provided in this embodiment, the defluorination material regeneration device 10 and the waste gas defluorination device 20 are used as an example to specifically describe the defluorination of waste gas using the defluorination material as an alkaline washed zirconium sulfate material.
[0025] like Figure 1 As shown, the defluorination material regeneration device 10 provided in the embodiment of the utility model includes, for example, a reaction body 100 , a defluorination unit 110 , an alkaline solution tank 120 and a sulfuric acid tank 130 .
[0026] Specifically, the reaction body 100 has, for example, an inner cavity 101. The reaction body 100 is, for example, provided with a first quick-release structure 104, and the defluorination unit 110 is, for example, provided in the inner cavity 101. Figure 3As shown, the defluorination unit 110 is provided with a second quick-release structure 1101, and the first quick-release structure 104 is detachably connected to the second quick-release structure 1101. The alkali solution tank 120 and the sulfuric acid tank 130 are respectively provided on the reaction body 100 and are connected to the inner cavity 101 respectively.
[0027] Wherein, the defluorination unit 110 includes, for example, a defluorination material, and the defluorination material is, for example, a basic zirconium sulfate material. In order to remove fluorine from the fluorine-containing waste gas, the alkaline-washed zirconium sulfate reacts with the fluorine-containing waste gas to undergo a defluorination reaction. During the defluorination reaction, the alkaline-washed zirconium sulfate reacts chemically with the fluorine in the fluorine-containing waste gas, and the generated products include, for example, zirconium fluoride (ZrF4) solid and other fluorine-containing composite salt solutions. In order to regenerate the defluorination unit 110 after the defluorination treatment, it is necessary to first add an alkali solution to the defluorination unit 110 after the defluorination treatment for backwashing treatment. The products generated by the backwashing treatment include, for example, zirconium dioxide and a fluoride solution. After the backwashing treatment is completed, sulfuric acid is added to the defluorination unit 110 after the backwashing treatment. The zirconium dioxide can be acidified and transformed with sulfuric acid to generate regenerated alkaline-washed zirconium sulfate and fluorozirconic acid solution, etc., that is, the regeneration includes the process of backwashing treatment and acidification transformation treatment. The regenerated alkaline-washed zirconium sulfate can continue to be used for the defluorination treatment of the fluorine-containing waste gas, and the fluoride solution can be further treated for recycling.
[0028] Among them, the inner cavity 101 of the reaction body 100 is used to accommodate the defluorination unit 110 and provide a regeneration reaction space. The first quick-release structure 104 and the second quick-release structure 1101 are, for example, detachable structures that meet the needs of quick disassembly, such as quick cards, screw pins and flanges. The number and structure of the first quick-release structure 104 match the number and structure of the second quick-release structure 1101. The number of the first quick-release structure 104 and the second quick-release structure 1101 can be set according to actual needs and are not limited here. The design of the detachable connection allows the disassembly and installation of the defluorination unit 110, which is convenient for regeneration and replacement. The defluorination unit 110 is, for example, a defluorination unit after a defluorination reaction occurs. Specifically, the defluorination unit before the defluorination reaction is placed in a reaction device for defluorination, and the exhaust gas is passed into the interior of the reaction device and then undergoes a defluorination reaction with the defluorination unit. The defluorination unit 110 after the defluorination reaction is pulled out and placed in the defluorination material regeneration device 10 for a regeneration reaction. The defluorination unit 110 is, for example, filled with a specific defluorination material, where the defluorination material is an alkali-washed zirconium sulfate material. The defluorination unit 110 contacts the exhaust gas in the reaction tower and removes fluoride in the exhaust gas through chemical reactions. The alkali solution tank 120 is used to provide alkali solution to promote the aforementioned backwashing process. The sulfuric acid tank 130 is used to provide sulfuric acid to promote the aforementioned acidification transformation process. Specifically, the alkali solution tank 120 and the sulfuric acid tank 130 are, for example, respectively provided with valves, so that the operator can open and close the corresponding tanks and the flow rate of the liquid as needed, ensuring the reliability of the regeneration process and improving the flexibility of operation. In some embodiments, the alkali solution tank 120 and the sulfuric acid tank 130 are, for example, high-level tanks, and the liquid (such as alkali solution or sulfuric acid) stored in the high-level tank is transported to the device by gravity self-flow.
[0029] The defluorination material regeneration device 10 includes, for example, a first reaction state and a second reaction state. When the defluorination material regeneration device 10 is in the first reaction state, the alkali liquid tank 120 outputs alkali liquid to the defluorination unit 110. When the defluorination material regeneration device 10 is in the second reaction state, the sulfuric acid tank 130 outputs sulfuric acid to the defluorination unit 110. Specifically, in the first reaction state, the alkali liquid tank 120 outputs alkali liquid to the defluorination unit 110, and the alkali liquid reacts chemically with zirconium fluoride (ZrF4) to generate zirconium dioxide and fluoride solution. In the second reaction state, the sulfuric acid tank 130 outputs sulfuric acid to the defluorination unit 110, and zirconium dioxide can be acidified and transformed with sulfuric acid to generate regenerated alkali-washed zirconium sulfate and fluorozirconic acid solution, etc. The regenerated alkali-washed zirconium sulfate can continue to be used for defluorination treatment of fluorine-containing waste gas, and the fluoride solution can be further processed for recycling.
[0030] In the embodiment of the utility model, a defluorination unit 110 is arranged in the inner cavity 101 of the reaction body 100, and a first quick-detachment structure 104 and a second quick-detachment structure 1101 are arranged, so that the defluorination unit 110 is detachably connected to the reaction body 100 through the first quick-detachment structure 104 and the second quick-detachment structure 1101. When the defluorination unit 110 is removed from the reaction body 100, the defluorination unit 110 can be used in a defluorination device for defluorination treatment of waste gas to remove fluorine in the waste gas. For example, the defluorination unit 110 includes a basic zirconium sulfate material. The basic zirconium sulfate can be used to chemically react with fluorine in the fluorine-containing waste gas, and the generated products include, for example, zirconium fluoride solid and other fluorine-containing composite salt solutions. After the defluorination treatment is completed, the defluorination unit 110 can be regenerated in the reaction body 100 of the defluorination material regeneration device 10. Specifically, the defluorination unit 110 after the defluorination treatment is completed is first connected to the reaction body 100 through the first quick-detachment structure 104 and the second quick-detachment structure 1101, and then the alkali solution tank 120 is opened, so that the defluorination material regeneration device 10 is in the first reaction state. In the first reaction state, the alkali solution tank 120 outputs alkali solution to the defluorination unit 110, and the alkali solution reacts chemically with zirconium fluoride to generate zirconium dioxide and fluoride solution. Then the sulfuric acid tank 130 is opened, so that the defluorination material regeneration device 10 is in the second reaction state. In the second reaction state, the sulfuric acid tank 130 outputs sulfuric acid to the defluorination unit 110, and zirconium dioxide can be acidified and transformed with sulfuric acid to generate regenerated alkaline washed zirconium sulfate and fluorozirconic acid solution, etc. The regenerated alkaline washed zirconium sulfate can continue to be used for defluorination treatment of fluorine-containing waste gas, and the fluoride solution can be further processed for recycling. In this way, since the defluorination unit 110 can be easily disassembled, the defluorination unit 110 can not only be regenerated in the defluorination material regeneration device 10, but also can be disassembled from the defluorination material regeneration device 10 and transferred to other defluorination equipment (such as the waste gas defluorination equipment 20) to defluorinate the fluorine-containing waste gas, thereby increasing the operational flexibility and the scope of use of the defluorination unit 110, and allowing the used defluorination unit 110 to be recycled, reducing the frequency and cost of replacing the defluorination unit 110.
[0031] Specifically, the defluorination material regeneration device 10 further includes, for example, a first collecting tank 140 and a second collecting tank 150, which are respectively arranged at the bottom of the reaction body 100 and are respectively connected to the inner cavity 101. The first collecting tank 140 is used to collect the liquid after the reaction in the inner cavity 101 when the defluorination material regeneration device 10 is in the first reaction state, and the second collecting tank 150 is used to collect the liquid after the reaction in the inner cavity 101 when the defluorination material regeneration device 10 is in the second reaction state. Specifically, when the defluorination material regeneration device 10 is in the first reaction state, in the first reaction state, the alkali liquid tank 120 outputs the alkali liquid to the defluorination unit 110, and the alkali liquid reacts chemically with zirconium fluoride to generate zirconium dioxide and fluoride solution. After the reaction is complete, the first collecting tank 140 is opened, and the first collecting tank 140 is used to collect the fluoride solution so that the fluoride solution can be further processed and recycled. When the defluorination material regeneration device 10 is in the second reaction state, the sulfuric acid tank 130 outputs sulfuric acid to the defluorination unit 110, and zirconium dioxide can be acidified and transformed with sulfuric acid to generate regenerated alkaline washed zirconium sulfate and fluorozirconic acid solution, etc. The second collection tank 150 is used to collect waste solutions such as fluorozirconic acid solution, thereby reducing waste generation and meeting the requirements of environmental protection and sustainable development.
[0032] Specifically, the reaction body 100 has two opposite ends, the alkali liquid tank 120 and the sulfuric acid tank 130 are, for example, respectively arranged on opposite sides of the reaction body 100, the first collecting tank 140 and the second collecting tank 150 are, for example, respectively arranged on opposite sides of the reaction body 100, and the alkali liquid tank 120 and the second collecting tank 150 are, for example, located on the same side of the reaction body 100. That is, the alkali liquid tank 120 and the first collecting tank 140 are arranged diagonally, and the sulfuric acid tank 130 and the second collecting tank 150 are arranged diagonally, so that the flow path of the fluid is optimized, so that the reaction is more sufficient. Of course, the positions of the alkali liquid tank 120, the second collecting tank 150, the sulfuric acid tank 130 and the first collecting tank 140 can be set according to the actual structure of the product, and are not specifically limited here.
[0033] Specifically, the defluorination unit 110 includes, for example, a housing 111 and a defluorination filler 112. The housing 111 is, for example, a cylindrical structure made of plastic or metal with no covers at both ends. The second quick-release structure 1101 is, for example, disposed on the housing, and the housing 111 is, for example, detachably connected to the reaction body 100 through the first quick-release structure 104 and the second quick-release structure 1101. The defluorination filler 112 is, for example, disposed inside the housing 111, and the defluorination filler 112 is, for example, connected to the inside of the housing 111 by welding, and the specific connection method is not limited here.
[0034] Specifically, the defluorination filler 112 includes, for example, a Raschig ring filler and a defluorination material, the Raschig ring filler is arranged inside the shell 111, and the defluorination material is arranged on the surface of the Raschig ring filler. In the specific manufacturing process, the Raschig ring filler matrix is first manufactured and the defluorination material is pretreated, and then the pretreated defluorination material is evenly coated or impregnated on the surface of the Raschig ring filler matrix, or the material is directly sprayed on the filler surface by spraying technology, and then the manufactured defluorination filler 112 is fixed inside the shell 111. Of course, the manufacturing method of the defluorination filler 112 can be selected according to the different defluorination materials and actual needs, and is not specifically limited here.
[0035] Preferably, the Raschig ring filler is a honeycomb filler. The honeycomb structure provides more contact area for gas and liquid, which helps to improve the efficiency of chemical reaction. And the honeycomb filler can evenly disperse the gas and liquid, reduce local dead zones, and ensure that the active area of the entire filler layer is fully utilized. Of course, the Raschig ring filler can also be other shapes, which can be specifically designed according to different defluorination materials and actual needs, and is not limited here.
[0036] like Figure 2 As shown, an embodiment of the utility model provides a waste gas defluorination device 20 , which is suitable for treating fluorine-containing waste gas. The waste gas defluorination device 20 , for example, includes a device body 200 and a defluorination unit 110 .
[0037] Specifically, the device body 200, for example, has an outer shell, and the device body 200 is used to provide a space for the defluorination reaction of the waste gas. The device body 200, for example, is provided with an air inlet 202 for introducing waste gas and an air outlet 203 for discharging the defluorinated gas. The defluorination unit 110 is detachably connected to the device body 200, for example, through the third quick-release structure 210 and the second quick-release structure 1101. The outer shell 111 is, for example, a tubular structure. When the outer shell 111 is connected to the device body 200 through the third quick-release structure 210 and the second quick-release structure 1101, the outer shell 111 is, for example, connected to the shell of the device body 200 so that the outer shell 111 can be used as a component of the device body 200. The waste gas introduced by the air inlet 202 enters from one end of the lumen of the defluorination unit 110 and reacts with the defluorination material, and then passes through the other end of the lumen of the defluorination unit 110 and is discharged from the air outlet 203. The detachable connection design allows the defluorination unit 110 to be disassembled and installed, which is convenient for regeneration and replacement.
[0038] In some embodiments, after the used defluorination unit 110 is regenerated in the defluorination material regeneration device 10, the defluorination unit 110 can be easily disassembled from the reaction body 100 through the first quick-detachment structure 104 and the second quick-detachment structure 1101, and then connected to the equipment body 200 through the third quick-detachment structure 210 and the second quick-detachment structure 1101, and the fluorine-containing waste gas is defluorinated in the equipment body 200, which increases the flexibility of operation and the scope of use of the defluorination unit 110, and can make the used defluorination unit 110 be recycled, reducing the frequency and cost of replacing the defluorination unit 110. It should be noted that the number and structure of the third quick-detachment structure 210, for example, match the number and structure of the second quick-detachment structure 1101, and the number of the third quick-detachment structure 210 and the second quick-detachment structure 1101 can be set according to actual needs, which is not limited here.
[0039] In addition, it can be understood that the aforementioned embodiments are merely illustrative descriptions of the present invention. Under the premise that the technical features do not conflict, the structures do not contradict, and the purpose of the present invention is not violated, the technical solutions of the various embodiments can be arbitrarily combined and used in combination.
[0040] Finally, it should be noted that the above embodiments are only used to illustrate the technical solutions of the utility model, rather than to limit it. Although the utility model has been described in detail with reference to the aforementioned embodiments, those skilled in the art should understand that they can still modify the technical solutions described in the aforementioned embodiments, or make equivalent replacements for some of the technical features therein. However, these modifications or replacements do not deviate the essence of the corresponding technical solutions from the spirit and scope of the technical solutions of the various embodiments of the utility model.
Claims
1. A defluorination material regeneration device (10), characterized in that: include: A reaction body (100) having an inner cavity (101), wherein a first quick-release structure (104) is provided on the reaction body (100); A defluorination unit (110) is arranged in the inner cavity (101); a second quick-detachment structure (1101) is arranged on the defluorination unit (110); the second quick-detachment structure (1101) is detachably connected to the first quick-detachment structure (104); the defluorination unit (110) comprises a defluorination material; An alkali solution tank (120) and a sulfuric acid tank (130) are respectively arranged on the reaction body (100) and are respectively connected to the inner cavity (101); The defluorination material regeneration device (10) comprises a first reaction state and a second reaction state, the alkali solution tank (120) is used for outputting alkali solution to the defluorination unit (110) when the defluorination material regeneration device (10) is in the first reaction state, and the alkali solution tank (120) is used for outputting sulfuric acid to the defluorination unit (110) when the defluorination material regeneration device (10) is in the second reaction state.
2. The defluorination material regeneration device (10) according to claim 1, characterized in that: Also includes: A first collecting tank (140) and a second collecting tank (150), wherein the first collecting tank (140) and the second collecting tank (150) are respectively arranged at the bottom of the reaction body (100) and are respectively connected to the inner cavity (101); The first collecting tank (140) is used for collecting the liquid after the reaction in the inner cavity (101) when the defluorination material regeneration device (10) is in the first reaction state, and the second collecting tank (150) is used for collecting the liquid after the reaction in the inner cavity (101) when the defluorination material regeneration device (10) is in the second reaction state.
3. The defluorination material regeneration device (10) according to claim 2, characterized in that: The alkali solution tank (120) and the sulfuric acid tank (130) are respectively arranged on opposite sides of the reaction body (100), the first collecting tank (140) and the second collecting tank (150) are respectively arranged on opposite sides of the reaction body (100), and the alkali solution tank (120) and the second collecting tank (150) are located on the same side of the reaction body (100).
4. The defluorination material regeneration device (10) according to claim 1, characterized in that: The defluorination unit (110) comprises: A housing (111), wherein the housing (111) is provided with the second quick-release structure (1101); A defluorination filler (112) is arranged inside the housing (111), and the defluorination filler (112) comprises the defluorination material.
5. The defluorination material regeneration device (10) according to claim 4, characterized in that: The defluorination filler (112) further comprises a Raschig ring filler, the Raschig ring filler is arranged inside the housing (111), and the defluorination material is arranged on the surface of the Raschig ring filler.
6. The defluorination material regeneration device (10) according to claim 5, characterized in that: The Raschig ring filler is a honeycomb filler.
7. The defluorination material regeneration device (10) according to claim 5, characterized in that: The defluorination material includes a basic zirconium sulfate material.
8. A waste gas defluorination device (20), characterized in that: include: A device body (200), the device body (200) being provided with an air inlet (202) and an air outlet (203), and the device body (200) being provided with a third quick-release structure (210); A defluorination unit (110), the defluorination unit (110) being located between the air inlet (202) and the air outlet (203), the defluorination unit (110) being provided with a second quick-detachment structure (1101), the second quick-detachment structure (1101) being detachably connected to the third quick-detachment structure (210); the defluorination unit (110) comprising a defluorination material.
9. The exhaust gas defluorination equipment (20) according to claim 8, characterized in that: The defluorination unit (110) comprises: A shell (111), the shell (111) being provided with the second quick-release structure (1101), the shell (111) being a tubular structure, the shell (111) being connected to the device body (200) and the shell (111) being a component of the device body (200); A defluorination filler (112) is disposed in the tubular cavity of the housing (111), and the defluorination filler (112) comprises the defluorination material.
10. The exhaust gas defluorination equipment (20) according to claim 9, characterized in that: The defluorination filler (112) further comprises a Raschig ring filler, the Raschig ring filler is arranged inside the housing (111), and the defluorination material is arranged on the surface of the Raschig ring filler; the defluorination material comprises a basic zirconium sulfate material.
Citation Information
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