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This application provides a modified photocurable oligomer, its preparation method, and a photocurable 3D printing resin. The preparation method of the modified photocurable oligomer includes the following steps: providing an acrylic monomer, a triblock thermoplastic elastomer, a coupling agent, and a polyurethane acrylate; dissolving the triblock thermoplastic elastomer in the acrylic monomer to obtain a block copolymer mixed solution; adding the coupling agent to the block copolymer mixed solution to obtain a modified block copolymer mixed solution; adding the polyurethane acrylate to the modified block copolymer mixed solution, and mixing to obtain the modified photocurable oligomer. The modified photocurable oligomer, its preparation method, and the photocurable 3D printing resin provided in this application use a triblock thermoplastic elastomer as a toughening reinforcing phase, and chemically modify its surface using a coupling agent, enabling it to form a strong chemical bond interface with the polyurethane acrylate after pre-dispersion in the acrylic monomer.