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Method for calculating concentration of interfered element through calculated concentration of element

A technology for interfering elements and element concentrations, which is applied in the application field of spectral analysis technology, and can solve problems such as non-spectral interference, calculation errors, and loss of control.

Inactive Publication Date: 2014-02-19
TIANJIN JINGLIWEI SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0008] 2. Non-spectral interference
[0029] However, there are shortcomings in the above-mentioned traditional model. Since the intensity variable in the model itself is not a net signal, it has systematic errors. Therefore, in actual analysis, such calculations in the model may cause further errors, and sometimes even cause out of control

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  • Method for calculating concentration of interfered element through calculated concentration of element
  • Method for calculating concentration of interfered element through calculated concentration of element
  • Method for calculating concentration of interfered element through calculated concentration of element

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Embodiment Construction

[0053] The present invention is specifically described below in conjunction with accompanying drawing, as figure 1 It is an analysis flowchart of the method for calculating the concentration of disturbed elements by calculating the concentration of elements according to the present invention. As shown in the figure, a method for calculating the concentration of disturbed elements by calculating the concentration of elements includes the following two Calibration model:

[0054] (1) Line overlap correction model: Among them, C i is the calculated concentration of the interfered element, C 0 is the concentration of the interfered element in the standard sample, K j is the overlapping interference coefficient, C ij Be the jth concentration of interfering elements with overlapping interfering properties in the I block standard sample, m is the number of possible overlapping interfering elements in the same block of standard samples;

[0055] (2) Line overlap - self-absorptio...

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Abstract

The invention discloses a method for calculating a concentration of an interfered element through calculated concentration of an element. The method is characterized by comprising the following two correction models: (1) spectra overlap correction model and (2) spectra overlap-self-absorption correction model.

Description

technical field [0001] The invention relates to the application field of spectral analysis technology, in particular to a method for calculating the concentration of disturbed elements by calculating the concentration of elements. Background technique [0002] Under the action of external energy (electric energy), the electrons of the elements in the sample undergo transitions after absorbing energy. From a low energy level to a high energy level, electrons in a high energy state are in an unstable state, and energy is released during the process from a high energy state to a low energy state. , this energy will manifest itself in the form of light, forming the spectrum of the element. [0003] Namely: δE=E 2 -E 1 =hv=hc / λ [0004] The energy level of the spectrum corresponds to the level of the element concentration in the analyzed sample, and the composite light is decomposed into the spectrum of a single element through the optical component grating. Since the resolut...

Claims

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Application Information

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IPC IPC(8): G01N21/66
Inventor 马增
Owner TIANJIN JINGLIWEI SCI & TECH
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