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Quinoline quaternary ammonium salt compound and its preparation method and application

A technology for quaternary ammonium salts and compounds, applied in the field of quinoline quaternary ammonium salts and their preparation, can solve problems such as affecting oilfield production and exploitation, inability to operate normally, and increasing water treatment costs, and achieve good killing and inhibiting effects , good bactericidal and bacteriostatic function, excellent corrosion inhibition effect

Active Publication Date: 2020-12-04
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, oil extraction wastewater contains a large number of microorganisms, Ca 2+ , Mg 2+ , Cl - , SO 4 2- and other corrosive scaling ions, which can easily cause corrosion and scaling of facilities; oilfield sewage also contains a variety of microorganisms, among which sulfate reducing bacteria (SRB) are the main hazards, because the water quality conditions of oilfield wastewater are suitable for the growth of SRB, The reproduction of microorganisms increases the concentration of corrosive ions and accelerates the corrosion of water injection equipment. The corrosion products of microorganisms will also block the water injection pipeline, which not only makes the oil well pipeline and supporting facilities severely corroded and cannot operate normally, but also blocks the pores of the oil layer and reduces the permeability of the oil layer. , seriously affecting the production and exploitation of oilfields
[0003] At present, although there is a certain gap between domestic and foreign countries in the research on corrosion inhibitors for oilfield gathering and transportation systems, they have also researched and developed organic amines, organic ammonium salts, quaternary ammonium salts, phosphate esters, amides, imidazolines and other nitrogen- and phosphorus-containing corrosion inhibitors. , Sulfur corrosion inhibitor, fungicides generally use fungicide 1227 to inhibit the growth and reproduction of SRB, but due to the long-term use of fungicides, SRB in many oil fields have developed resistance to it, resulting in greatly increased water treatment costs

Method used

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  • Quinoline quaternary ammonium salt compound and its preparation method and application
  • Quinoline quaternary ammonium salt compound and its preparation method and application
  • Quinoline quaternary ammonium salt compound and its preparation method and application

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preparation example Construction

[0027] The second aspect of the present invention provides a kind of preparation method of quinoline quaternary ammonium salt compound, the method comprises: under the quaternization reaction condition, in organic solvent, the compound shown in formula (2) and formula (3) The shown compound carries out quaternization reaction, thereby obtains the compound shown in formula (1);

[0028] Formula (3) X-R 1 -X;

[0029] Among them, A is -O-(CH 2 CH 2 O) n -R 2 , n is an integer above 1, R 2 is H or C1-C6 alkyl; R is H or C1-C10 alkyl; R 1 C1-C10 alkylene, -L 1 -O-L 2 -, -(CH 2 CH 2 O) m -L 3 -or-(CH 2 O) m -L 4 -, where L 1 , L 2 , L 3 and L 4 Each is independently selected from C1-C6 alkylene groups, m is an integer of 2 or more; X is halogen.

[0030] Wherein, the above-mentioned groups can be selected as described above, and the present invention will not repeat them here.

[0031] According to the present invention, specific examples of compounds represe...

preparation example 1

[0060] 19.2g 2-methyl-5-hydroxyquinoline (purchased from Tissier (Shanghai) Chemical Industry Development Co., Ltd.), catalyst (sodium hydroxide, 0.1 gram) joins in the reactor, closes the reactor, replaces with nitrogen The air in the kettle was stirred, and the temperature was raised to 120° C., and about 44 g of ethylene oxide was slowly pressed in, and then the reaction was continued for 2 hours. After cooling down, the product was terminated by oxalic acid, which was identified as a compound represented by formula (2), wherein the average n of the ethylene oxide repeating unit of the group A was about 8.

preparation example 2

[0062] 19.2g 4-methyl-7-hydroxyquinoline (purchased from Tissier (Shanghai) Chemical Industry Development Co., Ltd.), catalyst (sodium hydroxide, 0.1 gram) joins in the reactor, closes the reactor, replaces with nitrogen Air in the kettle, stirred, and the temperature was raised to 120° C., and about 88 g of ethylene oxide was slowly pressed in, and then the reaction was continued for 2 hours. After cooling down, the product was terminated by oxalic acid, which was identified as a compound represented by formula (2), wherein the average n of the ethylene oxide repeating unit of the group A was about 16.

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Abstract

The invention relates to the field of water treatment agents, in particular to a quinoline quaternary ammonium salt compound and a preparation method and application thereof. The quinoline quaternaryammonium salt compound is a compound represented by a formula (1). The quinoline quaternary ammonium salt compound has good corrosion inhibition and bacteriostasis functions, and can have excellent corrosion inhibition performance and good bactericidal and bacteriostatic functions on an oilfield reinjection water system in high chlorine, high salt, high temperature and high pressure environments at a lower dosage.

Description

technical field [0001] The invention relates to the field of water treatment agents, in particular to quinoline quaternary ammonium salt compounds and their preparation methods and applications. Background technique [0002] At present, most of my country's oil fields have entered the middle and late stages of development, and water injection is generally used for oil recovery. In the case of serious shortage of water resources, the reinjection of oil production sewage not only solves the problem of water shortage, but also solves the problem of environmental pollution caused by the discharge of oil production sewage. However, oil extraction wastewater contains a large number of microorganisms, Ca 2+ , Mg 2+ , Cl - , SO 4 2- and other corrosive scaling ions, which can easily cause corrosion and scaling of facilities; oilfield sewage also contains a variety of microorganisms, among which sulfate reducing bacteria (SRB) are the main hazards, because the water quality cond...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C07D215/20A01N43/42A01P1/00C02F5/12C02F1/50C02F103/10
CPCA01N43/42C02F1/50C02F5/12C02F2103/10C07D215/20
Inventor 王秀
Owner CHINA PETROLEUM & CHEM CORP
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