The invention discloses a high-efficiency organic fluorescent LED and a preparation method thereof, and belongs to the field of organic light emitting devices. The organic fluorescent LED is composedof a substrate, an anode, a cavity transmission layer, a spatial isolation layer of a broad band gap material, an electron transmission layer and a cathode laminated successively, and at least one ofthe cavity transmission layer and the electron transmission layer is doped with a fluorescent material. The spatial isolation layer is arranged between the cavity transmission layer and the electron transmission layer, an obtained exciplex within the long range under a non-contact condition serves as an excitation-stage energy donor, the efficiency roll-off under the external quantum efficiency, brightness and high current density of a device is higher than those of the device under the condition that the cavity transmission layer makes contact with the electron transmission layer, the high external quantum efficiency is not relied on utilization of a triplet state exciton of a fluorescence molecule, the structure of the fluorescence molecule is not designed specifically, and the application prospect is good.