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Negative electrode material of flexible sodium metal battery and preparation method thereof

The invention relates to a negative electrode material of a flexible sodium metal battery and a preparation method thereof and belongs to the technical field of sodium metal batteries. The negative electrode material is characterized in that graphene aerogel is adopted as a skeleton, and sodium metal is distributed in a skeleton structure; the hole diameter range of the skeleton is 20-200mu m, andthe mass percentage of the sodium metal in the negative electrode material is 90-98%. The preparation method of the negative electrode material comprises the following steps of: adding a conducting material into water, then adding a reducing agent, and reacting for 6-24 hours at the temperature of 50-200 DEG C to obtain an intermediate product; washing with water, freezing drying under 5-10 MPa to form the graphene aerogel; then adopting the graphene aerogel as a skeleton, and compounding with liquid metal sodium to obtain the negative electrode material. The negative electrode material has good flexibility, uniform porosity and large specific surface area; as a negative electrode of the sodium metal battery, uniform nucleation of sodium ions is ensured, the volume expansion in the circulating process is relieved, and due to higher conductivity, the overpotential is effectively reduced.
Owner:BEIJING INSTITUTE OF TECHNOLOGYGY
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