The invention relates to the technical field of secondary batteries, in particular to an electrode, an electrolyte thin layer and a preparation method thereof. An electrode is prepared from a halide solid electrolyte material, the solid electrolyte material is LiaMXb, M is one or more of Al, Ga, In, Sc, Y and La series, X is one or more of F, Cl and Br, a is greater than or equal to 0 and less than or equal to 10, and b is greater than or equal to 1 and less than or equal to 13. According to the invention, the ionic conductivity, the chemical/electrochemical stability and the plasticity can beremarkably improved; and in the manufacturing process of the electrode and the electrolyte, inert atmosphere protection is not needed, the method is very compatible with a traditional electrode manufacturing technology, the process is simple, the cost is low, the large-scale production capacity is extremely achieved, and therefore the commercial application value is extremely achieved.