The invention belongs to the technical field of
lithium ion batteries, and discloses a carboxyl-containing copolyimide binder, a
lithium ion battery
silicon negative
electrode, a
lithium ion battery and a preparation method, and
polyamide acid is prepared by using a carboxyl-containing
diamine monomer, an amino-terminated long aliphatic chain
diamine monomer and an anhydride
monomer as raw materials; and carrying out chemical imidization,
precipitation and washing on the
polyamide acid to obtain the carboxyl-containing copolyimide binder. The prepared carboxyl-containing copolyimide binder has good
solubility in a conventional
electrode manufacturing
solvent, and the
solution system of the obtained carboxyl-containing copolyimide binder is uniform and stable. When the carboxyl-containing copolyimide binder is applied to preparation of a
silicon negative
electrode of a
lithium ion battery, the carboxyl-containing copolyimide binder can generate dual covalent interface interaction with
silicon active material particles and conductive material particles, so that the migration efficiency of lithium ions in an electrode
system is remarkably improved, the transmission dynamics performance is enhanced, and the high-rate charge-
discharge capacity of the battery is effectively improved.