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Titanium alloy having excellent corrosion resistance in environment containing bromine ions

A technology of titanium alloy and bromide ion, applied in the field of titanium alloy, can solve the problems of insufficient corrosion resistance, not involving corrosion resistance, not considering corrosion resistance, etc., and achieving excellent corrosion resistance and reducing the cost of raw materials.

Active Publication Date: 2015-09-30
NIPPON STEEL CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, for applications requiring further improvement in properties in recent years, especially when the content of Pd is less than 0.05% by mass, the corrosion resistance becomes insufficient.
However, none of these Patent Documents 5 and 6 takes corrosion resistance into consideration, and does not relate to corrosion resistance in an environment containing bromide ions.

Method used

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  • Titanium alloy having excellent corrosion resistance in environment containing bromine ions
  • Titanium alloy having excellent corrosion resistance in environment containing bromine ions
  • Titanium alloy having excellent corrosion resistance in environment containing bromine ions

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0083] In order to confirm the crevice corrosion resistance and workability (flexibility and elongation) of the titanium alloy of the present invention, the following tests were carried out, and the results were evaluated.

[0084] 1. Test Method 1-1. Samples Table 1 shows the samples used in the test and their compositions (analytical values ​​for elements other than Ti, and the balance (bal.) for Ti).

[0085] [Table 1]

[0086]

[0087] As samples for the test, comparative materials (sample numbers 1 to 4) belonging to conventional materials, examples of the present invention (sample numbers 5 to 8 corresponding to claim 1, and samples corresponding to claim 1) were prepared in the form of plate samples. 2 corresponding to sample numbers 12 to 18), and titanium alloys that are not conventional materials but are examples outside the scope of the present invention (hereinafter simply referred to as "examples outside the scope of the present invention"; sample numbers 9 to ...

Embodiment 2

[0136] 2.1 Composition of the titanium alloy used in Example 2 In order to clarify the optimum rare earth element content and confirm that Ru has excellent bromine corrosion resistance among platinum group species, the following confirmation experiments were carried out. Table 6 shows the composition of the titanium alloy used in Example 2. According to the preparation method of the sample shown in Example 1, the alloys with the compositions shown in Table 6 were obtained.

[0137] [Table 6]

[0138] category

rare earth element

platinum group elements

Ni

Cr

co

Mo

W

V

O

C

H

N

Fe

margin

Comparative material 5

-

Ru; 0.02

<0.01

<0.01

<0.01

<0.01

<0.01

<0.01

0.05

0.004

0.0024

0.008

0.05

Ti+ impurity

Comparative material 6

Y; 4ppm

Ru; 0.02

<0.01

<0.01

<0.01

<0.01

<0.01

<0.01

0.08

0.006

0.0032

0.005 ...

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Abstract

[Object] To provide a titanium alloy having corrosion resistance that is as high as or higher than before, and high corrosion resistance in a bromine-ion-containing environment, the alloy being able to be manufactured at low cost. [Solution] Provided is a titanium alloy to be used in a bromine-ion-containing environment, the titanium alloy consisting of, in mass%, a platinum group element: greater than or equal to 0.01% and less than or equal to 0.10%, a rare earth element: greater than or equal to 0.001 % and less than 0.02%, O: greater than or equal to 0% and less than 0.1 %, and the balance: Ti and impurities. The titanium alloy may contain, instead of part of Ti, one or more selected from the group consisting of Ni, Co, Mo, V, Cr, and W. The platinum group element is desirably contained in, in mass%, greater than or equal to 0.01% and less than or equal to 0.05%. The rare earth element is desirably contained in, in mass%, greater than or equal to 0.001% and less than 0.02%.

Description

technical field [0001] The present invention relates to a titanium alloy, and particularly relates to a titanium alloy excellent in corrosion resistance (crevice corrosion resistance in an environment containing bromide ions, acid resistance, etc.) and economical efficiency. Background technique [0002] Titanium is actively used in the field of aircraft and the like, taking advantage of its light and hard properties. In addition, due to its excellent corrosion resistance, titanium is widely used as a material for chemical industry equipment, a material for thermal power / atomic power generation equipment, and a material for seawater desalination equipment. [0003] However, the environment where titanium can exhibit high corrosion resistance is limited to oxidizing acid (nitric acid) environment, neutral chloride environment such as seawater, while the crevice corrosion resistance in high temperature chloride environment, hydrochloric acid and other non-oxidizing acid Corro...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C14/00
CPCC22C14/00C22F1/183
Inventor 上仲秀哉神尾浩史阿部贤武内孝一
Owner NIPPON STEEL CORP
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