This invention discloses a method for recycling TAIC
wastewater and extracting 1,3-diallylurea, belonging to the field of
industrial wastewater treatment and
resource recovery technology. The method comprises five steps:
alkaline hydrolysis,
vacuum distillation,
filtration, filtrate recycling, and filter residue refining. First, NaOH or KOH alkaline solution is added to the TAIC
wastewater, and
alkaline hydrolysis is performed by heating and
aeration at 60-80℃, with the escaping gas absorbed by acid. Then,
vacuum distillation is carried out at 60-70℃ and -0.05~-0.08 MPa, and the resulting distillate can be reused in production. The concentrated
mother liquor is cooled and filtered, and the filtrate is replenished with fresh
wastewater and alkaline solution before recycling for
alkaline hydrolysis. The filter residue is then dissolved and recrystallized at 45-50℃ to obtain high-purity 1,3-diallylurea. This process achieves closed-loop wastewater recycling, with virtually no external wastewater
discharge. It effectively degrades high COD and high
ammonia nitrogen pollutants in the wastewater while recovering high-value-added products. Both
water resources and refining water can be recycled, resulting in low operating costs, stable processes, and both environmental and
economic benefits.