The invention belongs to the technical field of
chemical synthesis, and particularly relates to a
halogen-free
flame retardant TPU (
Thermoplastic Urethane) glue
coating material and a preparation method thereof. The
halogen-free
flame retardant TPU glue
coating material is prepared from the following raw materials including polyhydric
alcohol, diisocyanate, chain expanding agents, antioxidants, light stabilizers, catalysts,
halogen-free main
flame retardants, cooperated flame retardants and plasticizing agents. The halogen-free main flame retardants are one or several kinds of materials from organic
hypophosphorous acid metal salts,
rare earth hypophosphorous acid salt or
melamine derivative series flame retardants; the cooperated flame retardants are one or several kinds of materials fromaluminum
hydroxide,
magnesium hydrate, aluminum
oxide or
magnesium oxide. The invention also provides the preparation method of the halogen-free flame retardant TPU glue
coating material. According to the method, the polyhydric
alcohol, the diisocyanate and the chain expanding agents are mixed; auxiliary agents dispersed by the plasticizing agents are continuously added through a lateral feedingopening; then,
extrusion processing and
granulation is performed through screw
extrusion; a finished product is obtained. The halogen-free flame retardant TPU glue coating material has the advantagesthat the flame retardant performance, the
mechanical property and the
processing performance are excellent; the self extinguishing effect can be realized; halogen
hydride gas with toxic and harmful effect on the environment is not generated during the
combustion in the air; the efficiency is high; the environment is protected.