A kind of modified bamboo charcoal fiber-rubber composite shoe sole material and its preparation method and application
A technology of bamboo charcoal fiber and composite shoe sole, which is applied in the field of materials, can solve the problems of high density and serious dust pollution in the processing process, and achieve the effects of increasing tensile strength, improving compatibility, and improving interface adhesion
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Embodiment 1
[0034] Present embodiment adopts maleic anhydride to carry out modification to bamboo charcoal fiber according to the following steps, makes maleic anhydride modified bamboo charcoal fiber, and step comprises:
[0035] S1. Weighing: Weigh the bamboo charcoal fiber and maleic anhydride according to the ratio of parts by weight of 1:1-1:2.
[0036] S2, the preparation of modifying agent: the maleic anhydride taken in the step (S1) is completely dissolved in the DMF solvent; Simultaneously take xylene according to 6-8 times of maleic anhydride weight, and add to maleic anhydride - In the DMF solution, all the components are dissolved under stirring conditions to obtain a modifier solution.
[0037] S3, bamboo charcoal fiber modification: adding the bamboo charcoal fiber weighed in step (S1) to the modifier solution obtained in step (S2), this step is stirred and modified at 30°C, and the reaction time is 4h; Suction filtration is carried out after the reaction is finished, and t...
Embodiment 2
[0040] The present embodiment adopts silane coupling agent to modify bamboo charcoal fiber according to the following steps to obtain silane coupling agent modified bamboo charcoal fiber. The steps include:
[0041] S1. Surface passivation treatment of bamboo charcoal fibers: soak the dried bamboo charcoal fibers in a sufficient amount of NaOH solution with a mass concentration of 10% for 48 hours, take out the soaked bamboo charcoal fibers and dry them at 105°C to obtain bamboo charcoal fibers Pre-processing material.
[0042] S2, the preparation of coupling modification liquid: according to the weight ratio of silane coupling agent and bamboo charcoal fiber is 1: 30-1: 40, take silane coupling agent KH570 and dissolve in absolute ethanol, the obtained silane coupling agent is in The concentration in absolute ethanol is 2.5%-3.5% to obtain a coupling modification solution.
[0043] S3. Coupling modification of bamboo charcoal fiber: soak the bamboo charcoal fiber pretreatmen...
Embodiment 3
[0045] The sole material of the present embodiment is mainly formulated by the raw material of following weight portion: 30 parts of the maleic anhydride modified bamboo charcoal fiber that make with embodiment 1, other components are as follows: 50 parts of butadiene rubber, 50 parts of styrene-butadiene rubber , 30 parts of maleic anhydride modified bamboo charcoal fiber, 1.5 parts of sulfur, 3 parts of zinc oxide, 1 part of stearic acid, and 1.5 parts of accelerator TMTD.
[0046] In the preparation of the above-mentioned maleic anhydride modified bamboo charcoal fiber, the weight ratio of bamboo charcoal fiber, maleic anhydride and xylene is 1:2:14.
[0047] The preparation method of present embodiment raw material, realizes by following steps:
[0048] (1) Weighing: Weigh the above raw materials in parts by weight.
[0049] (2) Mixing: Mix the above-mentioned combined rubber weighed in the step (1) in an open mill to mix evenly. In this step, the operating parameters of...
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