Flue gas adsorbent and preparation method thereof

A technology of adsorbent and flue gas, which is applied in the field of flue gas adsorbent and the preparation of the above-mentioned adsorbent, can solve the problems of high equipment operation and maintenance costs, secondary pollution of the environment, and cumbersome removal process, etc., to achieve enhanced chemical adsorption capacity, The effect of low equipment requirements and simple process

Pending Publication Date: 2020-03-27
西安润川环保科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

These raw materials and methods are not only limited by high cost, relatively cumbersome actual removal process, relatively low den

Method used

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preparation example Construction

[0022] A preparation method of a flue gas adsorbent, comprising the following steps:

[0023] Step 1, drying and carbonizing the straw in turn;

[0024] Step 2. After the fly ash, metakaolin, carbide slag, and carbonized straw are respectively dried and crushed, they are added to a planetary ball mill and ground to a particle size of less than 0.074 mm to obtain a mixed sample;

[0025] Step 3. Mix and stir the mixed sample with sulfate to obtain a mixed slurry;

[0026] Step 4. After mixing and stirring the mixed slurry with magnesium hydroxide, filter and retain the filter cake, and vacuum-dry the filter cake under the conditions of a vacuum degree of -80 to -100 kPa and a temperature of 100 to 150 °C to obtain an adsorbent. powder.

[0027] Through the above methods, the flue gas adsorbent of the present invention uses fly ash, metakaolin, straw, and calcium carbide slag as the main raw materials, and the four raw materials are industrial solid wastes. It also solves the...

Embodiment 1

[0029] A preparation method of a flue gas adsorbent, comprising the following steps:

[0030] Step 1. The wheat straw and the sorghum straw are dried, carbonized and mixed;

[0031] Step 2. After drying and crushing 30 parts of fly ash, 25 parts of metakaolin, 10 parts of calcium carbide slag, and 20 parts of carbonized straw respectively, they are added to a planetary ball mill and ground to a particle size of 0.06 mm to obtain a mixed sample;

[0032] Step 3, mixing and stirring the mixed sample with the ferrous sulfate and ferric sulfate mixed solution with a volume ratio of 2:1 to obtain a mixed slurry;

[0033] Step 4. After mixing and stirring the mixed slurry with magnesium hydroxide, filter and retain the filter cake, and vacuum-dry the filter cake under the conditions of a vacuum degree of -80 kPa and a temperature of 100° C. to obtain adsorbent powder.

Embodiment 2

[0035] A preparation method of a flue gas adsorbent, comprising the following steps:

[0036] Step 1. Drying and carbonizing dry branches and sorghum stalks and mixing;

[0037] Step 2. After drying and crushing 32 parts of fly ash, 25 parts of metakaolin, 6 parts of calcium carbide slag, and 21 parts of carbonized straw respectively, they are added to a planetary ball mill and ground to a particle size of 0.07 mm to obtain a mixed sample;

[0038] Step 3, mixing and stirring the mixed sample with the ferrous sulfate and ferric sulfate mixed solution with a volume ratio of 2:1 to obtain a mixed slurry;

[0039] Step 4. After mixing the mixed slurry with magnesium hydroxide and stirring, filter and retain the filter cake, and vacuum-dry the filter cake under the conditions of a vacuum degree of -85kPa and a temperature of 110° C. to obtain adsorbent powder.

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Abstract

The invention discloses a flue gas adsorbent and a preparation method thereof. The flue gas adsorbent is prepared from the following raw materials in parts by weight: fly ash, metakaolin, straw, sulfate, magnesium hydroxide and carbide slag. The method comprises the steps of sequentially drying and carbonizing straws; drying and crushing the fly ash, the metakaolin, the carbide slag and the carbonized straw, and adding above materials into a planetary ball mill for grinding to obtain a mixed sample; mixing and stirring the mixed sample and the sulfate to obtain mixed slurry; and mixing the mixed slurry with the magnesium hydroxide, stirring, filtering to reserve a filter cake, and carrying out vacuum drying on the filter cake to obtain adsorbent powder. The four raw materials are industrial solid wastes and are wide in source and large in quantity, so that the cost of the raw materials can be reduced, and the pollution problem caused by stacking treatment of crop straws is also solved.

Description

technical field [0001] The invention belongs to the technical field of adsorbents, relates to a flue gas adsorbent, and also relates to a preparation method of the above adsorbent. Background technique [0002] Air pollution in my country is a serious problem. Taking the problem of flue gas emissions from factories as an example, the main pollutants SO2 and NOx in the sintering flue gas emitted by iron and steel enterprises are one of the sources of polluting gases that have great harm to human, animal and plant health, and a large amount of SO2 and NOx will directly Causes air pollution problems such as acid rain, photochemical smog and smog. Therefore, reasonable control and treatment of the emission of harmful gases in flue gas is not only a practical problem that enterprises urgently need to solve, but also an important development direction to protect the ecological environment. [0003] With the continuous improvement of my country's industrialization level, a large ...

Claims

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Application Information

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IPC IPC(8): B01J20/24B01D53/02B01J20/30
CPCB01J20/24B01J20/08B01J20/103B01D53/02B01J20/041B01J20/12B01D2258/0283
Inventor李伟
Owner西安润川环保科技有限公司