41results about How to "Weak side effects" patented technology

The invention discloses an industrial synthesis method of high-thermal-stability blocked binphenyl-structure-containing polyaryletherketone resin. The industrial synthesis method of the high-thermal-stability blocked binphenyl-structure-containing polyaryletherketone resin comprises the following steps: carrying out polymerization reaction based on paradioxybenzene, biphenol and 4,4'-difluoro diphenyl ketone or 4,4'-difluoro triphenyl diketone as reaction monomers, a high boiling point organic solvent as a solvent, alkali carbonate as a salt-forming agent and asymmetric aromatic ketone-based derivative as a blocking agent, so as to obtain polymerization mucosal fluid; cooling the polymerization mucosal fluid and smashing the cooled polymerization mucosal fluid into powder, filtering and boiling and washing with an organic solvent and deionized water for removing the solvent and byproduct salt, and drying, thus obtaining the binphenyl-structure-containing polyaryletherketone resin. The industrial synthesis method of the high-thermal-stability blocked binphenyl-structure-containing polyaryletherketone resin has the advantages that sodium carbonate alkali metal is individually adopted as a catalyst, and a good blocking effect is realized after the blocking agent is added; besides, no polymerization phenomenon is caused in a system, and the obtained blocked binphenyl-structure-containing polyaryletherketone resin has high temperature thermal stability.

The invention discloses glass fiber-enhanced chain-extending modified polyether sulphone resin and a preparation method therefor. The preparation method comprises the step of mixing and extruding the following: 50-90% of chain-extending polyether sulfone resin (PPSU, PES); 9-40% of fiber; 0.1-5% of carbon black or titanium dioxide; and 0.1-10% of various auxiliary agents. The synthetic process disclosed by the invention is simple and the production efficiency is high. The synthesized novel chain-extending modified polyether sulphone resin has higher mechanical strength and lower melt viscosity, and is more liable to be processed and moulded. Meanwhile, the fiber-modified and enhanced polyether sulphone resin is good in flowability and heat resistance, and the mechanical properties of the enhanced resin such as tensile strength, bending strength and toughness are improved to a great extent, so that the application field of the polyether sulphone material is widened.

The invention discloses an industrialized synthesis method of a high-heat-stability blocked polyether sulfone resin, which comprises the following steps: in a reaction kettle in a nitrogen protective atmosphere, adding a sulfolane solvent, heating to 60-80 DEG C while stirring, sequentially adding a water diversion agent, continuing heating to 200-210 DEG C while stirring, and carrying out salifying reaction for 1-2 hours; after the salifying reaction is finished, heating to 220-240 DEG C, carrying out constant-temperature polymerization reaction for 1-2 hours, adding a blocking agent, and continuing the reaction for 10-30 minutes to obtain a polymerization slurry; and cooling the polymerization slurry, pulverizing into powder, filtering, boiling and washing with deionized water to remove the solvent and byproduct salts, and drying to obtain the polyether sulfone resin. After adding the blocking agent, the polyether sulfone resin has favorable blocking effect, the system does not have the phenomenon of depolymerization, and the obtained blocked polyether sulfone resin has high heat stability; and the technique can greatly shorten the reaction time and enhance the productivity.