Fluidizer and method for preparing ethylene with ethanol dehydration

A technology of ethanol dehydration and fluidization equipment, which is applied in the field of equipment for preparing hydrocarbons from non-hydrocarbon compounds. It can solve the problems of ethylene purity reduction and side reaction increase, and achieve the effects of improving purity, ensuring heat balance, and optimal reaction temperature range

Active Publication Date: 2012-10-10
CHINA PETROLEUM & CHEM CORP +1
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  • Abstract
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  • Claims
  • Application Information

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Problems solved by technology

[0010] The main problem of using a fluidized bed reactor for ETE is that the regenerated catalyst entrains flue gas, which contains a large amount of impurity gases such as nitrogen, oxygen, carbon dioxide, carbon monoxide, etc., and the regenerated catalyst entrained with flue gas returns to the fluidized bed for reaction The device will increase the side reaction and greatly reduce the purity of ethylene in the product, requiring expensive cryogenic separation to improve its purity

Method used

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  • Fluidizer and method for preparing ethylene with ethanol dehydration
  • Fluidizer and method for preparing ethylene with ethanol dehydration
  • Fluidizer and method for preparing ethylene with ethanol dehydration

Examples

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Embodiment

[0047] The relevant tests in the examples were carried out on a medium-sized device integrating ethanol dehydration to ethylene (ETE) and catalytic cracking (FCC) controlled in real time by a computer. The processing capacity of this device is 0.4t / d, and the raw material is 5% water content The ethanol, the feed rate of ethanol is, the weight hourly space velocity is 1.2h -1 , the fluidized bed reaction temperature is 380°C, and the reaction pressure is 0.2MPa. The catalyst is FCC catalyst GOR-2 catalyst (800° C., 100% steam aging for 17 hours) developed by Sinopec Petrochemical Research Institute.

[0048] The product distribution is shown in Table 1. From Table 1, it can be seen that the conversion rate of ethanol is 99.5%, and the purity of ethylene is as high as 99.0v%.

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Abstract

A fluidizing device for preparing ethylene by ethanol dehydration comprises a fluidized bed reactor, a regenerator, a catalyst riser, a stripper and a catalyst mixing degassing tank. The stripper and the regenerator are connected via a to-be-regenerated catalyst delivery pipeline. The fluidized bed reactor is directly connected with a catalyst riser. The catalyst mixing degassing tank and the regenerator are connected via a regenerated catalyst delivery pipeline. The catalyst mixing degassing tank and the stripper are connected via a catalyst internal recycling pipeline. By adding the catalyst mixing degassing tank, the fluidizing device can effectively remove flue gas carried by the regenerated catalyst to greatly increase the ethylene purity in the product. The regenerator can be arranged separately, or the catalytic cracking regenerator of a catalytic cracking device in a petroleum refining field can be shared.

Description

technical field [0001] The present invention pertains to an apparatus and method for the preparation of hydrocarbons from a non-hydrocarbon compound, and more particularly to an apparatus and method for the dehydration of an oxygenate to prepare ethylene. Background technique [0002] Ethylene is the most important basic raw material in the petrochemical industry. At present, about 75% of petrochemical products come from ethylene. At present, the world's ethylene production capacity has reached 112.9055 million tons per year, and it is expected that the world's ethylene production capacity will reach 144.455 million tons per year in 2012. In 2010, my country's ethylene equivalent demand is expected to be 25.7 million tons per year, the production capacity is 13.89 million tons per year, and the self-sufficiency rate is only 54%. Therefore, whether it is domestic or foreign, there is still a lot of room for the development of the ethylene market. [0003] There are many ways...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C07C1/24C07C11/04
CPCY02P20/584
Inventor 杨克勇李强常学良鲁维民邢波郭湘波张久顺龙军舒兴田谢文华吴治国
Owner CHINA PETROLEUM & CHEM CORP
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