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A kind of process method of cyanide-free silver plating

A technology of cyanide-free silver plating and process method, which is applied in the field of electrochemical silver plating process, can solve the problems of cumbersome silver plating process, high cost, and numerous procedures, and achieve the effects of reducing production cost, improving efficiency, and high circulation volume

Active Publication Date: 2018-04-03
YANGZHOU HY TECH DEV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] However, the above-mentioned silver plating process is relatively cumbersome, with many procedures and high cost, and the efficiency in the actual production process is also greatly reduced.

Method used

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  • A kind of process method of cyanide-free silver plating

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0060] Select the appropriate size of copper particles.

[0061] First of all, it is necessary to remove the oil, sweat and dust on the surface of the copper particles, and the copper particles can be wiped with paper towels or non-woven fabrics.

[0062] The copper pellets are then rinsed under running water.

[0063] Then put the copper particles into the silver-plating tank and drive the plated parts through the filter of the silver-plating tank to carry out uniform rolling cycle, so that the copper particles are uniformly electroplated in the cyanide-free solution. Wherein, include silver nitrate, conductive salt, complexing agent, potassium carbonate, potassium hydroxide and gloss agent in the described cyanide-free solution, described silver nitrate, described conductive salt, described complexing agent, described potassium carbonate, The contents of the potassium hydroxide and the gloss agent are respectively 20g / L, 120g / L, 120g / L, 25g / L, 80g / L and 15mL / L. The cyanide...

Embodiment 2

[0066] Select the appropriate size of copper particles.

[0067] First of all, it is necessary to remove the oil, sweat and dust on the surface of the copper particles, and the copper particles can be wiped with paper towels or non-woven fabrics.

[0068] The copper pellets are then rinsed under running water.

[0069] Then put the copper particles into the silver-plating tank and drive the plated parts through the filter of the silver-plating tank to carry out uniform rolling cycle, so that the copper particles are uniformly electroplated in the cyanide-free solution. Wherein, include silver nitrate, conductive salt, complexing agent, potassium carbonate, potassium hydroxide and gloss agent in the described cyanide-free solution, described silver nitrate, described conductive salt, described complexing agent, described potassium carbonate, The contents of the potassium hydroxide and the gloss agent are respectively 30g / L, 130g / L, 130g / L, 30g / L, 90g / L and 20mL / L. The cyanide...

Embodiment 3

[0072] Select the appropriate size of copper particles.

[0073] First of all, it is necessary to remove the oil, sweat and dust on the surface of the copper particles, and the copper particles can be wiped with paper towels or non-woven fabrics.

[0074] The copper pellets are then rinsed under running water.

[0075] Then put the copper particles into the silver-plating tank and drive the plated parts through the filter of the silver-plating tank to carry out uniform rolling cycle, so that the copper particles are uniformly electroplated in the cyanide-free solution. Wherein, include silver nitrate, conductive salt, complexing agent, potassium carbonate, potassium hydroxide and gloss agent in the described cyanide-free solution, described silver nitrate, described conductive salt, described complexing agent, described potassium carbonate, The contents of the potassium hydroxide and the gloss agent are respectively 40g / L, 140g / L, 140g / L, 35g / L, 100g / L and 25mL / L. The cyanid...

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Abstract

The invention provides a cyanogens-free silver plating process method and relates to the technical field of electrochemical silver plating processes. According to the process method, silver plating is conducted on a plating piece through a cyanogens-free solution under the action of the current, and a silver-plated product is obtained. The method includes the following steps that firstly, pretreatment is conducted on the plating piece; secondly, primary washing operation is conducted on the plating piece obtained in the first step; thirdly, cyanogens-free silver plating operation is conducted on the plating piece obtained in the second step; and fourthly, secondary washing operation is conducted on the plating piece obtained in the third step, so that the silver-plated product can be obtained. By the adoption of the silver plating process, the plating piece can be plated with silver through the cyanogens-free solution under the action of the current, no cyanide exists in the silver plating process, and the quality of products is not affected on the basis of environment protection. In addition, the silver plating process is simple, efficiency in the production process is improved greatly, and meanwhile production cost is lowered.

Description

technical field [0001] The invention relates to the technical field of electrochemical silver plating, in particular to a cyanide-free silver plating process. Background technique [0002] Silver plating was once mainly used for decorative purposes, but with the promotion and application of electroplating technology in electronic devices, semiconductors, and instruments, the amount of functional silver plating has soared. So far, cyanide silver plating is still the mainstream of industrial production in the silver plating industry at home and abroad. With the continuous improvement of environmental awareness, cyanide silver plating will be gradually eliminated. The research on cyanide-free silver plating has been carried out for more than ten years. Although some achievements have been made, the technology is still immature. [0003] Patent Publication No. CN1680630A discloses a cyanide-free silver plating process, which is a cyanide-free silver plating process under the a...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C25D3/46C25D5/34C25D5/00
CPCC25D3/46C25D5/00C25D5/34
Inventor 薛明峰
Owner YANGZHOU HY TECH DEV