Relief layer and imprint method for making the same

a relief layer and imprint technology, applied in the field of relief layer and imprint method for making the same, can solve the problem of layer becoming not patternable, and achieve the effects of maintaining shape fidelity, low shrinkage, and relatively high stability of relief layer comprising such groups

Inactive Publication Date: 2016-08-25
KONINKLIJKE PHILIPS NV
View PDF3 Cites 2 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The patent is about a way to make a layer with very few holes, using a method called embossing. The goal is to make this layer effective for its intended use.

Problems solved by technology

These requirements however cause the partially dried siliconoxide compound layer to form a highly viscous solution.
Therewith causing the layer to become not patternable especially with flexible or brittle stamps.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Relief layer and imprint method for making the same
  • Relief layer and imprint method for making the same
  • Relief layer and imprint method for making the same

Examples

Experimental program
Comparison scheme
Effect test

example 1

[0040]A first siliconoxide compound solution according to the invention is prepared by mixing together 8 gram of Ludox™ TM-50, comprising 50 weight % silica nanoparticles having a particle diamter inbetween 20 nm and −40 nm in water with 1.2 gram of formic acid under stirring. Subsequently, 0.9 gram of Methyltrimethoxysilane (MTMS) is added and the resulting mixture stirred at room temperature for 15 minutes. An additional 6.9 grams of MTMS is added under stirring and the resulting solution is left to stand for 30 minutes at room temperature. Finally 1.7 gram of ethyleneglycolmonobutylether is added. The PH of the resulting silicon compound solution as measured with litmus paper is in between 3.5 and 4.5.

example 2

[0041]A second silicon compound solution according to the invention is prepared by mixing together the silicon compounds precursors MTMS and tetramehoxysilane (TMOS) in a molar ratio as given in table I. In a second step 1M formic acid in water is added to the mixture to an amount of 1 mole water per mole of methoxy-groups of the total added amount of silicon compound precursors. The resulting mixture is allowed to react, undergoing hydrolysis and condensation for period of 10 min. to 30 min. at a temperature between 20° C. and 30° C. in order to form a siliconoxide compound. Then to the mixture is added n-propanol such that the resulting silicon compound solution contains a total Silicon atom concentration of 0.8 mol per kilogram solution. In a final step, water is added to the mixture to an amount of 9 times the total silicon atom content in moles to obtain the silicon compound solution according to the invention.

TABLE ITMOSMTMSWeight % CH3Volume % CH3ExperimentmoleMolein relief l...

example 3

[0043]A third siliconoxide compound solution according to the invention is prepared by mixing together the silicon compounds precursors MTMS and TMOS in a molar ratio as given in table I. Then n-propanol is added to dilute the mixture before in a second step 1M formic acid in water is added to the mixture to an amount of 1 mole water per mole of methoxy-groups of the total added amount of silicon compound precursors. After the addition the resulting mixture is allowed to react, undergoing hydrolysis and condensation for period of 10 min. to 60 min. at a temperature between 20° C. and 30° C. in order to form a siliconoxide compound. In a third step additional n-propanol is added such that the resulting siliconoxide compound solution contains a total silicon atom concentration of 0.8 mol per kilogram solution. In a final step water is added to the mixture to an amount of 9 times the total silicon atom content in moles within the mixture to obtain the siliconoxide compound solution acc...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
average diameteraaaaaaaaaa
temperaturesaaaaaaaaaa
temperatureaaaaaaaaaa
Login to View More

Abstract

The invention relates to a method for forming a relief layer employing a stamp having a stamping surface including a template relief pattern. A solution comprising a siliconoxide compound is sandwiched between a substrate surface and the stamp surface and dried while sandwiched. After removal of the template relief pattern the relief layer obtained has a high inorganic mass content making it robust and directly usable for a number of applications such as semiconductor, optical or micromechanical.

Description

CROSS-REFERENCE TO RELATED APPLICATIONS[0001]This patent application is divisional of U.S. patent application Ser. No. 12 / 447,536, filed Apr. 28, 2009, which claims benefit under 35 U.S.C. §371 of International Application No. PCT / IB2007 / 054361 filed on Oct. 26, 2007, which claims the foreign priority to European Patent Application No EP06123325.0 filed on Nov. 1, 2006.FIELD OF THE INVENTION[0002]The invention relates to a Method for forming a relief layer employing a stamp having a stamping surface including a template relief pattern. The invention also relates to a relief layer as prepared by the method and the use of such a relief layer in semiconductor, optical and micromechanical devices.BACKGROUND OF THE INVENTION[0003]Providing material layers having a relief pattern can be done using an embossing or imprinting method such as imprinting lithography. In US 2004 / 0264019 A1 an exemplary method is disclosed. In the method, a relatively soft sol-gel layer is provided to a hard sur...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & AuthorityApplications(United States)
IPC IPC(8): G03F7/00
CPCB29C2059/023B82Y10/00Y10T428/24479G03F7/0002B82Y40/00
InventorVERSCHUUREN, MARCUS ANTONIUS
OwnerKONINKLIJKE PHILIPS NV