Hybrid modified EG preparation method

Abstract

The invention relates to a hybrid modified EG preparation method. The preparation method comprises the following steps: mixing a citric acid aqueous solution, indium vanadate, cerium oxide, montmorillonite, a hydrobromic acid aqueous solution, graphene oxide, and tin oxide and performing a hydrothermal reaction, grinding a mixture, and performing steps of filtering, calcining, washing and drying to obtain an EG anti-aging agent; mixing glycol, propylene glycol, butylene glycol, a lactic acid cosolvent and the obtained EG anti-aging agent, magnesium oxide, and titanium dioxide, grinding the mixture, and performing steps of dispersing and filtering to obtain the hybrid modified EG mother liquor; and adding the hybrid modified EG mother liquor in EG in a spray form to obtain the hybrid modified EG. The product has the long lasting anti-aging effect.

Description

technical field

[0001] The invention belongs to the technical field of EG variety development, and in particular relates to a preparation method of hybrid modified EG. Background technique

[0002] EG is called ethylene glycol in Chinese and ethylene glycol in English, also known as "glycol", "1,2-ethylene glycol", or EG for short. Its chemical formula is (CH2OH) 2 , is the simplest diol. EG is a colorless, odorless, sweet liquid that can be mixed with water in any proportion and used as a raw material for solvents, antifreeze agents, and synthetic resins. In resin synthesis, the most common method is to use EG and purified terephthalic acid as monomer raw materials for synthesis. The synthetic material prepared by it has the characteristics of high strength, good rigidity, high hardness and toughness, and is widely used in industrial production and In people's life, such as engineering plastics, building materials, mechanical parts, beverage bottles, packaging films, fil...

Examples

Embodiment 1

[0043] A preparation method of hybrid modified EG, comprising the steps of:

[0044] (1) the concentration of 70 parts by weight is 10 wt% aqueous citric acid, 10 parts of indium vanadate, 10 parts of cerium oxide, 3.5 parts of montmorillonite, 17 parts of hydrobromic acid with a concentration of 3 wt%. Aqueous solution, 3.5 parts of graphene oxide and 2 parts of tin oxide were mixed, moved to a hydrothermal reactor, continuously stirred and reacted for 5 hours at a temperature of 115°C and a pressure of 0.4MPa, then cooled naturally under stirring, and used at 42°C Grind with liquid in a high-energy ball mill for 3 hours, filter, and then calcined at 490°C for 5 hours, fully washed with deionized water, vacuum-dried at 87°C, and then ground for 3.5 hours with a ball mill, and sieved through a 250-mesh EG special anti-aging agent;

[0045] (2) Add successively 10.5% propylene glycol, 1.5% butanediol, 0.9% lactic acid and 8% EG special anti-aging agent prepared by (1) by EG wei...

Embodiment 2

[0049] A preparation method of hybrid modified EG, comprising the steps of:

[0050] (1) the concentration of 67 parts by weight is the hydrobromic acid of 5wt% the concentration of 5wt% citric acid aqueous solution, 8 parts of indium vanadate, 8 parts of cerium oxide, 3 parts of montmorillonite, 10 parts Aqueous solution, 3 parts of graphene oxide and 1 part of tin oxide were mixed, moved to a hydrothermal reactor, continuously stirred and reacted for 6 hours at a temperature of 120°C and a pressure of 0.3MPa, then cooled naturally under stirring, and used at 45°C Grind with liquid in a high-energy ball mill for 2 hours, filter, and then calcined at 500°C for 6 hours, fully washed with deionized water, vacuum-dried at 85°C, and then ground for 5 hours with a ball mill, and sieved through a 300-mesh EG special anti-aging agent;

[0051] (2) Add successively 10% propylene glycol, 2% butanediol, 0.8% lactic acid and 12% EG special anti-aging agent prepared by (1), 5% oxidation ...

Embodiment 3

[0055] A preparation method of hybrid modified EG, comprising the steps of:

[0056] (1) the concentration of 60 parts by weight is 10 wt% aqueous citric acid solution, 10 parts of indium vanadate, 8 parts of cerium oxide, 3 parts of montmorillonite, 14 parts of hydrobromic acid with a concentration of 3 wt%. Aqueous solution, 3 parts of graphene oxide and 2 parts of tin oxide were mixed, moved to a hydrothermal reactor, continuously stirred and reacted at 115°C and 0.4MPa pressure for 5h, then cooled naturally under stirring, and used at 45°C Grind with liquid in a high-energy ball mill for 3 hours, filter, then calcinate at 490°C for 5 hours, fully wash with deionized water, dry in vacuum at 90°C, grind for 5 hours with a ball mill, and pass through a 300-mesh sieve to obtain EG special anti-aging agent;

[0057] (2) Add successively 11% propylene glycol, 1% butanediol, 1% lactic acid and 8% EG special anti-aging agent prepared by (1) by EG weight, 3% oxidation Magnesium, 1...

technical field

[0001] The invention belongs to the technical field of EG variety development, and in particular relates to a preparation method of hybrid modified EG. Background technique

[0002] EG is called ethylene glycol in Chinese and ethylene glycol in English, also known as "glycol", "1,2-ethylene glycol", or EG for short. Its chemical formula is (CH2OH) 2 , is the simplest diol. EG is a colorless, odorless, sweet liquid that can be mixed with water in any proportion and used as a raw material for solvents, antifreeze agents, and synthetic resins. In resin synthesis, the most common method is to use EG and purified terephthalic acid as monomer raw materials for synthesis. The synthetic material prepared by it has the characteristics of high strength, good rigidity, high hardness and toughness, and is widely used in industrial production and In people's life, such as engineering plastics, building materials, mechanical parts, beverage bottles, packaging films, fil...

Examples

Embodiment 1

[0043] A preparation method of hybrid modified EG, comprising the steps of:

[0044] (1) the concentration of 70 parts by weight is 10 wt% aqueous citric acid, 10 parts of indium vanadate, 10 parts of cerium oxide, 3.5 parts of montmorillonite, 17 parts of hydrobromic acid with a concentration of 3 wt%. Aqueous solution, 3.5 parts of graphene oxide and 2 parts of tin oxide were mixed, moved to a hydrothermal reactor, continuously stirred and reacted for 5 hours at a temperature of 115°C and a pressure of 0.4MPa, then cooled naturally under stirring, and used at 42°C Grind with liquid in a high-energy ball mill for 3 hours, filter, and then calcined at 490°C for 5 hours, fully washed with deionized water, vacuum-dried at 87°C, and then ground for 3.5 hours with a ball mill, and sieved through a 250-mesh EG special anti-aging agent;

[0045] (2) Add successively 10.5% propylene glycol, 1.5% butanediol, 0.9% lactic acid and 8% EG special anti-aging agent prepared by (1) by EG wei...

Embodiment 2

[0049] A preparation method of hybrid modified EG, comprising the steps of:

[0050] (1) the concentration of 67 parts by weight is the hydrobromic acid of 5wt% the concentration of 5wt% citric acid aqueous solution, 8 parts of indium vanadate, 8 parts of cerium oxide, 3 parts of montmorillonite, 10 parts Aqueous solution, 3 parts of graphene oxide and 1 part of tin oxide were mixed, moved to a hydrothermal reactor, continuously stirred and reacted for 6 hours at a temperature of 120°C and a pressure of 0.3MPa, then cooled naturally under stirring, and used at 45°C Grind with liquid in a high-energy ball mill for 2 hours, filter, and then calcined at 500°C for 6 hours, fully washed with deionized water, vacuum-dried at 85°C, and then ground for 5 hours with a ball mill, and sieved through a 300-mesh EG special anti-aging agent;

[0051] (2) Add successively 10% propylene glycol, 2% butanediol, 0.8% lactic acid and 12% EG special anti-aging agent prepared by (1), 5% oxidation ...

Embodiment 3

[0055] A preparation method of hybrid modified EG, comprising the steps of:

[0056] (1) the concentration of 60 parts by weight is 10 wt% aqueous citric acid solution, 10 parts of indium vanadate, 8 parts of cerium oxide, 3 parts of montmorillonite, 14 parts of hydrobromic acid with a concentration of 3 wt%. Aqueous solution, 3 parts of graphene oxide and 2 parts of tin oxide were mixed, moved to a hydrothermal reactor, continuously stirred and reacted at 115°C and 0.4MPa pressure for 5h, then cooled naturally under stirring, and used at 45°C Grind with liquid in a high-energy ball mill for 3 hours, filter, then calcinate at 490°C for 5 hours, fully wash with deionized water, dry in vacuum at 90°C, grind for 5 hours with a ball mill, and pass through a 300-mesh sieve to obtain EG special anti-aging agent;

[0057] (2) Add successively 11% propylene glycol, 1% butanediol, 1% lactic acid and 8% EG special anti-aging agent prepared by (1) by EG weight, 3% oxidation Magnesium, 1...