Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Wastewater treatment filtering material, and preparation method and use thereof

A filter material and wastewater treatment technology, applied in water/sewage treatment, adsorbed water/sewage treatment, water/sludge/sewage treatment, etc., can solve the problems of reduced adsorption capacity, acute poisoning, inability to fix heavy metals, etc. The effect of using safety

Active Publication Date: 2014-11-19
SUZHOU MICRO CERAMICS HEAVY METAL FILTER TECH
View PDF1 Cites 1 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the single application of zero-valent iron brings the following problems: 1. The corrosion reaction can only occur in an environment with a pH less than 7. Adjusting and controlling the pH is the application limit of drinking water filtration; 2. There must be a certain amount of dissolved oxygen in the water (greater than 2 mg / L) to continue the reaction; 3. Harmful sludge is formed during the reaction process, which cannot fix heavy metals, and further harmless treatment is required; 4. A large amount of excess ferric or ferrous ions are produced during use, making the Water is red or orange and must be treated further
But the way of coating still has some problems, as the coating prepared by activated carbon mixing method is easy to come off when pH changes or water quality changes, and this can cause acute poisoning in drinking water; The problem of surface oxidation, which reduces its adsorption capacity
[0005] Chinese invention patent ZL200680052402.X discloses a method and composition for removing arsenic and heavy metals from water, in which the method of using kaolin ceramic particles for zero-valent iron coating can effectively remove arsenic and heavy metals and achieve heavy metal fixation on the ceramic surface , but this method can only use the ceramic surface structure, and the adsorption efficiency needs to be further improved
[0006] In summary, the main disadvantages of the prior art for the removal of arsenic are: 1. The traditional ceramic oxidation and calcination can only provide a porous structure to filter bacteria and macromolecules for physical filtration; 2. The application of zero-valent iron powder produces more iron Ions and hazardous waste; 3. The activated carbon iron powder coating has the problem of shedding; 4. The surface coating of ceramic particles can only use the surface structure

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Wastewater treatment filtering material, and preparation method and use thereof
  • Wastewater treatment filtering material, and preparation method and use thereof
  • Wastewater treatment filtering material, and preparation method and use thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0051] The present embodiment provides a filter material for wastewater treatment, the preparation method of which is as follows:

[0052] Step 1: prepare a soluble starch solution at room temperature, add an aqueous solution of ferrous sulfate, adjust the pH to 7.5-8.0 with sodium citrate, and obtain an aqueous solution with a starch content of 5% and a ferrous ion content of 4%;

[0053] The second step: soak the porous ceramic substrate completely in the solution prepared in the first step to make it completely wet, and take it out for more than 15 minutes and dry it for later use;

[0054] Step 3: Prepare 4wt% sodium borohydride aqueous solution, adjust the pH to 8.5-9.5 with 0.1% tartaric acid solution, and set aside;

[0055] Step 4: Quickly immerse the porous ceramic substrate dried in the second step in the sodium borohydride aqueous solution prepared in the third step. The ceramic filter element undergoes a surface chemical reaction, and takes it out for 5 minutes to ...

Embodiment 2

[0073] The present embodiment provides a filter material for wastewater treatment, the preparation method of which is as follows:

[0074] Step 1: Prepare glucose solution at room temperature, add ferrous sulfate aqueous solution, adjust pH to 7.5-8.0 with sodium citrate, and obtain an aqueous solution with 8% glucose content and 3% ferrous ion content;

[0075] The second step: soak the porous ceramic substrate completely in the solution prepared in the first step to make it completely wet, and take it out for more than 15 minutes and dry it for later use;

[0076] The third step: prepare 3.5wt% sodium borohydride aqueous solution, adjust the pH to 8.5-9.5 with 0.1% tartaric acid solution, and set aside;

[0077] Step 4: Quickly soak the porous ceramic substrate dried in the second step in the sodium borohydride aqueous solution prepared in the third step, the ceramic filter element undergoes a surface chemical reaction, and takes it out for 5 minutes to dry.

[0078] Step 5...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
lengthaaaaaaaaaa
porosityaaaaaaaaaa
porosityaaaaaaaaaa
Login to View More

Abstract

The invention relates to a wastewater treatment filtering material, and a preparation method and a use thereof. The filtering material is formed by a porous ceramic matrix having an amount of porosity of 35-85% and nanometer zerovalent iron particles in-situ generated in the porous ceramic matrix, the micropore size of the porous ceramic matrix is 2-10mum, a fuzzy amorphous silicon-iron-carbon structure is formed in the micropore and can form an adsorbing film after absorbing water, and the material of the porous ceramic matrix is composed of 55-65 parts by weight of diatomite, 12-15 parts by weight of calcium-based bentonite, 7-12 parts by weight of carbon powder, 2-3 parts by weight of starch, and 4-6 parts by weight of kaolin. The filtering material obtained in the invention forms a nose-like porous fluffy filtering structure in the microstructure and generates the adsorbing film, so the absorbing efficiency is greatly improved, and the filtering material can be adapted to the chemical environment change of water. The shedding or heavy metal precipitation of the used filtering material does not appear, and the use safety of the filtering material is good.

Description

technical field [0001] The invention belongs to the field of filter material preparation, and in particular relates to a filter material capable of absorbing and fixing arsenic and heavy metals, its preparation method and application. The filter material can effectively remove trivalent arsenic and pentavalent arsenic contained in fluid such as water. Background technique [0002] Arsenic is one of the highly toxic elements, and it is also the main inorganic toxin removed in the drinking water standards of various countries. It exists mostly in trivalent and pentavalent states in natural water bodies. However, as a metal element, it does not exist in the state of common cations, but mainly exists in the form of arsenite and arsenate. Even modern technologies such as reverse osmosis membrane (RO) have a removal rate of only about 50% for trivalent arsenic, which cannot meet the filtration requirements for arsenic. In addition, the filter material must take into account the ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Patents(China)
IPC IPC(8): B01D39/20B01J20/20B01J20/28B01J20/30C02F1/28C02F1/58C02F1/62
Inventor 董良杰
Owner SUZHOU MICRO CERAMICS HEAVY METAL FILTER TECH
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products