Novel industrial process for purifying dibutyl nylon acid ester

A technology of dibutyl nylon acid and nylon acid, which is applied in the field of new industrialization process for purifying dibutyl nylon acid, can solve the problems of high equipment cost, slow purification process, high energy consumption, etc., and achieve high production capacity, reduce energy consumption, equipment less investment

Pending Publication Date: 2019-07-09
谦信化工集团有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Rectification or distillation is a unit operation with high energy consumption. In addition, the purification process is slow and the equipment cost is high

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] The invention discloses a novel industrial process for purifying dibutyl nylon acid, which uses nylon acid and isobutanol or n-butanol as raw materials in a mass ratio of 2.6:1, and reacts under catalyst conditions to obtain dibutyl nylon acid The mixture is then purified, and the technological process includes the following steps:

[0038] S1, pretreatment: remove the catalyst in the dibutyl nylon acid mixture, stand-by;

[0039] S2. Distillation treatment: the dibutyl nylonate mixture after the pretreatment of step S1 is removed by vacuum distillation to remove excess or unreacted butanol and generated water to obtain the crude product of dibutyl nylonate; the condition of vacuum distillation is -0.075 MPa, 110°C.

[0040] S3. Purification treatment: Purify the crude dibutyl nylonate obtained in step S2 through an alkaline solid purification column to obtain a purified dibutyl nylonate. The conditions for the dibutyl nylon acid crude product to pass through the alka...

Embodiment 2

[0045] The invention discloses a novel industrial process for purifying dibutyl nylon acid, which uses nylon acid and isobutanol or n-butanol as raw materials in a mass ratio of 2.5:1, and reacts under catalyst conditions to obtain dibutyl nylon acid The mixture is then purified, and the technological process includes the following steps:

[0046] S1, pretreatment: remove the catalyst in the dibutyl nylon acid mixture, stand-by;

[0047] S2. Distillation treatment: the dibutyl nylonate mixture after the pretreatment of step S1 is removed by vacuum distillation to remove excess or unreacted butanol and generated water to obtain the crude product of dibutyl nylonate; the condition of vacuum distillation is -0.085 MPa, 90°C.

[0048]S3. Purification treatment: Purify the crude dibutyl nylonate obtained in step S2 through an alkaline solid purification column to obtain a purified dibutyl nylonate. The conditions for the dibutyl nylon acid crude product to pass through the alkali...

Embodiment 3

[0053] The invention discloses a new type of industrial process for purifying dibutyl nylon acid, using nylon acid and isobutanol or n-butanol as raw materials in a mass ratio of 2.4:1, and reacting under catalyst conditions to obtain dibutyl nylon acid The mixture is then purified, and the technological process includes the following steps:

[0054] S1, pretreatment: remove the catalyst in the dibutyl nylon acid mixture, stand-by;

[0055] S2. Distillation treatment: the dibutyl nylonate mixture after the pretreatment of step S1 is removed by vacuum distillation to remove excess or unreacted butanol and generated water to obtain the crude product of dibutyl nylonate; the condition of vacuum distillation is -0.095 MPa, 130°C.

[0056] S3. Purification treatment: Purify the crude dibutyl nylonate obtained in step S2 through an alkaline solid purification column to obtain a purified dibutyl nylonate. The conditions for the dibutyl nylon acid crude product to pass through the a...

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Abstract

The invention discloses a novel industrial process for purifying dibutyl nylon acid ester. Nylon acid and isobutanol or n-butanol are taken as raw materials and react under the condition of a catalystaccording to a mass ratio of (2.4-2.6):1, thus a dibutyl nylon acid ester mixture is obtained and then purified. The technological process comprises the following steps of pretreatment, distillationtreatment, purification treatment and decoloration treatment, so that a final dibutyl nylon acid ester product is obtained. The novel industrial process for purifying dibutyl nylon acid ester has thecharacteristics of high production stability, low acidity, high purity and low cost.

Description

technical field [0001] The invention relates to the technical field of dibutyl nylonate, in particular to a novel industrialized process for purifying dibutyl nylonate. Background technique [0002] Nylon acid is a mixed dibasic acid, which is a by-product produced during the industrial production of adipic acid. Dibutyl ester prepared from nylon acid can be used as a film-forming agent for water-based paints, or a cold-resistant plasticizer for plastics. Most of the current international environmental protection regulations believe that the boiling point is higher than 250 o Compounds of C are not included in the category of VOCs. The boiling range in dibutyl nylon acid is higher than 250 o C. With the tightening of environmental protection policies, the market application of dibutyl nylon acid will increase. The purification method of current industrial production dibutyl nylon all is to take the method for rectification or multiple distillation (as patent CN104945248 ...

Claims

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Application Information

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IPC IPC(8): C07C67/08C07C69/40C07C69/42C07C69/44C07C67/48
CPCC07C67/08C07C67/48C07C69/40C07C69/42C07C69/44
Inventor李庭忠赵楚榜于冬娥孙丰强
Owner谦信化工集团有限公司