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A kind of barbituric acid derivative of disubstituted thiophene and preparation method thereof

A technology of barbituric acid and disubstituted, which is applied in the field of barbituric acid derivatives of disubstituted thiophene and its preparation, can solve the problems of inconspicuous color contrast and low luminous efficiency, and achieve the effect of good solubility

Active Publication Date: 2020-11-13
QILU UNIV OF TECH
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Problems solved by technology

However, the fluorescence emission intensity of these traditional organic light-emitting materials is usually very weak in the solid state or aggregated state, that is, the ACQ phenomenon, which is unfavorable for the observation of the MFC phenomenon, resulting in low solid-state luminous efficiency of these materials, and the color contrast is not obvious

Method used

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  • A kind of barbituric acid derivative of disubstituted thiophene and preparation method thereof
  • A kind of barbituric acid derivative of disubstituted thiophene and preparation method thereof
  • A kind of barbituric acid derivative of disubstituted thiophene and preparation method thereof

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[0021] It should be pointed out that the following detailed description is exemplary and intended to provide further explanation to the present application. Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this application belongs.

[0022] It should be noted that the terminology used here is only for describing specific implementations, and is not intended to limit the exemplary implementations according to the present application. As used herein, unless the context clearly dictates otherwise, the singular is intended to include the plural, and it should also be understood that when the terms "comprising" and / or "comprising" are used in this specification, they mean There are features, steps, operations, means, components and / or combinations thereof.

[0023] The Suzuki reaction described in this application, also known as Suzuki coupling reaction, Suzuki-Miyaura...

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Abstract

The invention discloses a barbituric acid derivative of disubstituted thiophene and a preparation method thereof. The chemical structural formula of the barbituric acid derivative is as shown in the description. According to the invention, the thiophene-based barbituric acid derivative is synthesized for the first time, experiments prove that the derivative has higher solid-state luminescence efficiency and obvious color contrast.

Description

technical field [0001] The invention relates to the field of aggregation-induced fluorescence (AIE) compounds, in particular to a barbituric acid derivative of disubstituted thiophene and a preparation method thereof. Background technique [0002] In 2001, Professor Tang Benzhong's research group discovered a peculiar phenomenon: some silole molecules hardly emit light in solution, but the light emission is greatly enhanced in the aggregated state or solid film. Because this luminescence enhancement is caused by aggregation, this phenomenon is vividly defined as "aggregation-induced emission (AIE)". [0003] Stimuli-responsive materials are one of the future development trends of high-tech materials and play an important role in modern high-tech. Mechanochromic (MFC) materials change their solid-state emission colors in response to external mechanical stimuli (e.g., grinding, compression, shearing, stretching, friction), and may be used in pressure sensors, optoelectronic d...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C07D409/14C09K11/06C09K9/02
CPCC07D409/14C09K9/02C09K11/06C09K2211/1007C09K2211/1044C09K2211/1092
Inventor 崔月芝张汉君陶芙蓉李凯苏熙
Owner QILU UNIV OF TECH
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