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A kind of water residual chlorine adsorbent and preparation method thereof

An adsorbent and residual chlorine technology, applied in chemical instruments and methods, adsorption water/sewage treatment, water pollutants, etc., can solve problems such as corrosion bearing structure, low removal efficiency, affecting water taste and odor, etc., and achieve reduction Residual chlorine concentration, the effect of reducing the risk of cancer

Active Publication Date: 2022-04-12
GUANGZHOU EP ENVIROMENTAL ENG
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Chlorine disinfection of tap water can ensure the safety of drinking water, but excessive residual chlorine in water will affect the taste and smell of water on the one hand, and on the other hand, it can react with natural organic matter in water to form disinfection by-products, threatening human health
At present, there are few studies on the removal of residual chlorine, and the removal efficiency is not high, so it is not suitable for popularization and application.
In the prior art, activated carbon is generally used to absorb residual chlorine. For example, Chinese patents CN201959605U and CN102107994A both use activated carbon as the residual chlorine adsorption material, but after activated carbon absorbs residual chlorine, it will gradually become acidic, which may corrode the load-bearing structure used to carry the adsorption material.

Method used

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  • A kind of water residual chlorine adsorbent and preparation method thereof
  • A kind of water residual chlorine adsorbent and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] A kind of preparation method of water residual chlorine adsorbent, concrete steps are as follows:

[0028] S1. Grind diopside and diatomite in a ball mill respectively, pass through a 200-mesh sieve, and then dry in an oven at 90 to 110°C to constant weight to obtain diopside powder and diatomite powder; diopside The powder and diatomaceous earth powder are mixed in a mass ratio of 1:4 to obtain a mixture;

[0029] S2. Put the mixture in step S1. into a porcelain crucible, then put it into a muffle furnace and calcinate at 700° C. for 100 min, and cool naturally to obtain a pre-calcined product;

[0030] S3. Put the pre-calcined product of step S2. into a porcelain crucible, then put it into a muffle furnace for calcination at a temperature of 1000° C. for 50 minutes, and cool naturally to obtain an adsorbent for residual chlorine in water.

Embodiment 2

[0032] The concrete steps of the method for preparing water residual chlorine adsorbent in the present embodiment are as follows:

[0033] S1. Grind diopside and diatomite in a ball mill respectively, pass through a 200-mesh sieve, and then dry in an oven at 90 to 110°C to constant weight to obtain diopside powder and diatomite powder; diopside The powder and diatomaceous earth powder are mixed in a mass ratio of 1:3 to obtain a mixture;

[0034] S2. Put the mixture in step S1. into a porcelain crucible, then put it into a muffle furnace and calcinate at 800° C. for 100 min, and cool naturally to obtain a pre-calcined product;

[0035] S3. Put the pre-calcined product of step S2. into a porcelain crucible, then put it into a muffle furnace for calcination at a temperature of 900° C. for 50 minutes, and cool naturally to obtain an adsorbent for residual chlorine in water.

Embodiment 3

[0037] The concrete steps of the method for preparing water residual chlorine adsorbent in the present embodiment are as follows:

[0038] S1. Grind diopside and diatomite in a ball mill respectively, pass through a 200-mesh sieve, and then dry in an oven at 90 to 110°C to constant weight to obtain diopside powder and diatomite powder; diopside The powder and diatomaceous earth powder are mixed at a mass ratio of 1:5 to obtain a mixture;

[0039] S2. Put the mixture in step S1. into a porcelain crucible, then put it into a muffle furnace and calcinate at 800° C. for 120 minutes, and cool naturally to obtain a pre-calcined product;

[0040] S3. Put the pre-calcined product of step S2. into a porcelain crucible, then put it into a muffle furnace for calcination at a temperature of 900° C. for 70 minutes, and cool naturally to obtain an adsorbent for residual chlorine in water.

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Abstract

The invention discloses an adsorbent for residual chlorine in water and a preparation method thereof. The preparation method comprises the following steps: S1. Take dried diopside powder and diatomite powder and mix evenly to obtain a mixture; the diopside powder and diatomaceous earth powder through a 200-mesh sieve; S2. Calcining the mixture in step S1. at a temperature of 700-800° C. for 100-120 minutes, and then cooling naturally to obtain a pre-calcined product; S3. Pre-calcining the product in step S2. Calcining at 900-1000° C. for 50-70 minutes to obtain the adsorbent for residual chlorine in water. In the present invention, a mixture of diopside powder and diatomite powder passed through a 200-mesh sieve is calcined twice successively, and the temperature and time of calcination are controlled to successfully prepare a water residual chlorine adsorbent with excellent performance. Chlorine adsorbent can effectively reduce the concentration of residual chlorine in tap water, reduce the risk of human cancer caused by disinfection by-products, and remain weakly alkaline after absorbing a certain amount of residual chlorine. It is a safe and healthy adsorbent for residual chlorine in water .

Description

technical field [0001] The invention relates to the technical field of tap water treatment, in particular to a water residual chlorine adsorbent and a preparation method thereof. Background technique [0002] With the improvement of the quality of life, people's requirements for drinking water have also risen to the level of focusing on health and safety. Chlorination of tap water can ensure the safety of drinking water, but excessive residual chlorine in water will affect the taste and smell of water on the one hand, and on the other hand, it can react with natural organic matter in water to form disinfection by-products, threatening human health. At present, there are few studies on the removal of residual chlorine, and the removal efficiency is not high, so it is not suitable for popularization and application. In the prior art, activated carbon is generally used to adsorb residual chlorine. For example, Chinese patents CN201959605U and CN102107994A both use activated ca...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J20/14B01J20/30C02F1/28C02F101/12
CPCB01J20/103B01J20/14C02F1/281C02F2101/12
Inventor 王文静阳重阳曹姝文李锐敬许嘉辉刘晓永周文栋杨炜雯黄逸龙刘诚钟华东
Owner GUANGZHOU EP ENVIROMENTAL ENG