The invention belongs to the technical field of intelligent
response type hydrogel preparation, and particularly relates to temperature-
solvent dual-response
information processing hydrogel with subject-object recognition and regulation effects, a preparation method and application thereof. According to the invention, under the
catalysis of 2, 2-
azobisisobutyronitrile (AIBN), 2-methyl-2 adamantyl
methacrylate (Ad-MA) and N-isopropylacrylamide (NIPAM) are used as raw materials, and an
adamantane (Ad) group grafted poly N-isopropylacrylamide derivative (Ad-PNIPAm) is constructed. Then, under the action of auxiliary
polymerization and chemical crosslinking of the NIPAM, the semi-interpenetrating network composite hydrogel (Ad-PNIPAm gel) is constructed. The hydrophilic and hydrophobic balance of the Ad-PNIPAm is regulated and controlled by changing the
grafting degree of the Ad-MA in the Ad-PNIPAm, so that the stimulation response performance of the Ad-PNIPAm gel is regulated. The composite hydrogel has optical adjustable behaviors of sensitive temperature and
solvent stimulation in a wide
room temperature environment (4-40 DEG C), not only can quickly respond to external stimulation in a shorter time, but also has adjustable
encryption and decryption time, stable reversibility and
multiple encryption / decryption capability.