Recording medium
A recording medium, recording layer technology, applied in the direction of copying/marking method, printing, coating, etc., which can solve the problems of insufficient gloss, insufficient improvement effect of ozone resistance, etc., and achieve good ink absorption and excellent image density , Excellent gas resistance
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[0318] The present invention will be specifically described below by way of examples, but the present invention is not limited to these examples. In addition, "parts" and "%" in the examples represent "parts by mass" and "% by mass" unless otherwise specified, and "average molecular weight" and "degree of polymerization" represent "weight average molecular weight" and "weight average molecular weight". Average degree of polymerization".
Synthetic example 1
[0321] 13.5 parts of polybutadiene (NISSO-PB G1000: manufactured by Nippon Soda Co., Ltd.), 15.6 parts of 2-mercaptoethanol, and 2.84 parts of aminoethanethiol hydrochloride were dissolved in 13.5 parts of ethyl acetate / isopropanol = 1 / 1wt mixture. It was heated to 70° C. under a nitrogen stream, 0.062 parts of 2,2-azobis(2,4-dimethylvaleronitrile) [trade name: V-65, manufactured by Wako Pure Chemical Industries, Ltd.] was added, and the Heating and stirring at ℃. After 2 hours, 0.062 parts of V-65 was added, followed by heating and stirring at 70° C. for 4 hours.
[0322] 128 parts of ion-exchanged water was uniformly added thereto and emulsified, and then the solvent was distilled off to obtain an emulsion of polymer 1 (exemplary compound: P-6, sulfur equivalent: 7.18 meq / g, I / O value: 1.17).
Synthetic example 2
[0324] Polymer 2 (exemplary compound: P-7, sulfur equivalent: 5.47meq / g , I / O value: 1.74) aqueous solution.
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