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Crosslinkable silicone composition for the preparation of non-stick coatings for polymer films

A technology of polyorganosiloxane and composition, applied in the field of siloxane composition, to achieve excellent adhesion performance, good mechanical and physical properties, and sufficient peeling force

Active Publication Date: 2011-12-07
BLUESTAR SILICONES FRANCE SAS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0031] Current technical solutions do not solve the above problems, especially with regard to flexible polymer supports (especially made of polyesters such as PET)

Method used

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  • Crosslinkable silicone composition for the preparation of non-stick coatings for polymer films
  • Crosslinkable silicone composition for the preparation of non-stick coatings for polymer films

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1 to 14

[0285] A. Composition

[0286] Table 1.

[0287]

[0288] 1comp, 2comp and 12comp are comparative compositions without fraction F2 having one or more adhesion promoting polymers.

[0289] B. Tests and results

[0290] Table 2.

[0291]

[0292] illustrate:

[0293] Comp1 and Comp2:

[0294] Example with Alkenylsiloxane Component A Consisting Only of Moieties F1. Negligible results in "rub-off" (RO) adhesion due to excess crosslinker B in Comp2 were observed.

Embodiment 3-4-5

[0295] Example 3-4-5: Fraction F1 and long-chain silicone oil A2.1.

[0296] Improvement of RO, especially when the content of crosslinker B is high.

Embodiment 7

[0299] Example 7: Terminal Monoalkenylated Silicone Oil of Fraction F1 and Chain A2.2

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PUM

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Abstract

Silicon compositions with the silicon compound ingredient A alkenylated PolyOrganoSiloxane (POS) containing an F1 fraction and an F2 fraction that are different from each other; F2, an adherence enhancer comprising a linear monoalkenylated silicon oil (A2.1) at one of its ends and / or a long linear α,ω,-alkenylated silicon oil (A2.2) and / or a “weakly alkenylated linear oil. Applications: non-stick silicon coatings obtained from crosslinking / polyaddition for PET.

Description

technical field [0001] The technical field of the invention is crosslinkable or crosslinked silicone compositions, in particular coatings or waterproof non-adhesive films which can be used to form flexible supports, preferably natural or synthetic polymeric in the form of thin films. [0002] Such curable non-adhesive silicone compositions are applied to such supports for easy removal of adhesive material reversibly laminated to the support. [0003] More specifically, the silicone composition of the present invention contains: [0004] - Functionalized polyorganosiloxanes (POS) with Si-H on the same molecule or on different molecules [(M) a’≥0 (M H ) b’≥0 (D H ) c’≥0 (D) d’≥0 ] and Si-alkenyl units, preferably Si-vinyl (Vi) [(M) a”≥0 (M Vi ) b”≥0 (D Vi ) c”≥0 (D) d”≥0 ] unit; the Si-H unit can react with Si-alkenyl units; [0005] - a suitable metal catalyst, preferably platinum; [0006] - optionally, at least one adhesion regulating system, such as based on s...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L83/04C09D183/04C08J7/043C08J7/046C08J7/054
CPCC08G77/80C09D183/04C08J2483/00C08L83/04C08G77/12C08G77/70C08G77/20C08J7/047Y10T428/31663C08J7/0427C08J7/043C08J7/054C08J7/046C08L83/00C08L91/00C08J7/12
Inventor 约翰·怀特肖恩·迪菲米歇尔·费德尔阿兰·普谢隆
Owner BLUESTAR SILICONES FRANCE SAS
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