Silicone composition, release paper and release film

A technology of siloxane and composition, applied in the field of siloxane composition, can solve the problem of not mentioning residual adhesive strength, etc., and achieve the effect of excellent non-adhesive property and high adhesive strength

Active Publication Date: 2021-08-06
SHIN ETSU CHEM CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, in the examples, only the Q unit (SiO 4 / 2 ) and alkenyl specific organopolysiloxanes using this reaction product, and there is no mention of the residual bond strength after peeling the bonding material from the release layer

Method used

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  • Silicone composition, release paper and release film
  • Silicone composition, release paper and release film
  • Silicone composition, release paper and release film

Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0116] The preparation method of the silicone composition is not particularly limited, and the method of adding the component (C) just before use after uniformly mixing the components (A), (B) and optional components in advance is preferable from the viewpoint of storage time. .

[0117] A cured film is formed on the surface of a substrate by applying and curing the silicone composition of the present invention on the surface of the substrate. Thereby, the substrate release property (the property that the substrate can be perfectly peeled off from the adhesive material) is imparted. When the base material having the peeling layer of the cured product of the silicone composition of the present invention is bonded to the adhesive material, the adhesive material can be peeled off without reducing the residual adhesion rate of the adhesive material. Layers peeled off. The step of coating the silicone composition on the surface of the substrate may be performed by a conventionall...

Embodiment 1~10

[0182]

[0183] The above-mentioned (A), (B) and (D) components were taken into a flask according to the compounding ratio described in the following Tables 1 to 3, and 0.3 part of (E) component was further added and dissolved under stirring. (C) catalyst was added to the obtained mixture so that it might become 100 ppm in terms of platinum mass with respect to the total of (A) component and (B) component, and it stirred and mixed, and obtained the siloxane composition. Using this siloxane composition, a coated product (release film) was produced and evaluated by the method described later.

[0184]

[0185] [Peel force]

[0186] Using a bar coater, the obtained composition was coated on a PET film with a thickness of 38 μm so that the solid content was 0.5 g / m 2 , Heat and cure in a hot air dryer at 120°C for 40 seconds to form a peeling layer. The peeling layer was evaluated according to the FINAT method in the following procedure.

[0187] A tape with a width of 25 m...

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Abstract

The object of the present invention is to provide a cured film that can provide excellent adhesion to substrates, especially plastic film substrates, and can leave a high adhesive strength on the adhesive material after peeling off the adhesive material from the cured film. A solvent-free silicone composition, and a release paper and a release film having the cured film are provided. Provided is a silicone composition comprising (A) an organopolysiloxane having two or more alkenyl groups bonded to silicon atoms in one molecule, one or more aryl groups or no aryl group in one molecule, ( B1) There are three or more hydrogen atoms bonded to silicon atoms in one molecule, and the total number of aryl groups is relative to the total number of hydrogen atoms bonded to silicon atoms and groups bonded to silicon atoms The proportion (%) (hereinafter referred to as the proportion of aryl groups) is at least 8% of the number of SiH groups in the organohydrogenpolysiloxane (B1) having aryl groups relative to the number of olefins in the (A) component The ratio of the number of groups is 0.5 to 10, and the catalyst amount of (C) platinum group metal catalyst, [the ratio (%) of the above-mentioned aryl group in the component (B1)] - [the aromatic group in the component (A) The ratio (%) of the total number of groups to the total number of groups bonded to silicon atoms]≥8.

Description

technical field [0001] The present invention relates to a siloxane composition providing a cured product layer excellent in adhesion to a substrate, particularly a plastic film substrate such as a polyester film, particularly a solvent-free siloxane composition, and a siloxane composition having the same A release paper and a release film of a cured film of the composition. Background technique [0002] Conventionally, in order to impart peeling characteristics (for example, a property that can be perfectly peeled from the adhesive material) to the substrate, a cured product containing a silicone composition is formed on the surface of a sheet-shaped substrate such as paper or plastic. film. As a method for forming a cured film of a silicone composition on the surface of a substrate, for example, Patent Document 1 describes that an alkenyl group-containing organopolysiloxane and an organohydrogenpolysiloxane are present on the surface of a substrate in the presence of a pla...

Claims

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Application Information

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Patent Type & AuthorityPatents(China)
IPC IPC(8): C08L83/07B32B27/00C08K5/56C08L83/05D21H27/00
CPCC08L83/04D21H27/001D21H17/59D21H19/32C09D183/04C08G77/12C08G77/20C08G77/80C08G77/14C08L83/00C08K5/56C08G77/08C08J7/04C08J2483/04C09J2400/283C09J2483/005C09J7/201C09J7/21C09J7/401B32B27/00D21H27/00
Inventor中山健
OwnerSHIN ETSU CHEM CO LTD