High molecular absorption polymer, preparation method and use thereof
A polymer and polymer technology, applied in the field of materials, can solve the problems of easy discomfort and infection, slow (salt) water absorption rate, easy reverse osmosis of moisture in the hygroscopic layer, etc., to reduce slippage and liquid penetration time , High water retention ratio, good air permeability and water absorption and water locking effect
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[0032] The preparation method of high-molecular absorption polymer includes: providing diatomaceous earth / carboxymethylcellulose sodium superabsorbent resin; glue, the above-mentioned cross-linking agent includes hydrazine hydrate, aspartic acid and diethylaminoethanol with a weight ratio of 1:0.03-0.05:0.02-0.05; Homogeneous under pressure to obtain a three-dimensional network polymer absorption polymer. The polymer prepared by the preparation method uses the hydrophilic groups in the structure to bind water molecules in its three-dimensional network structure, which significantly improves the adsorption efficiency of fluids and the water absorption and water retention performance, and increases the antibacterial and antibacterial properties. At the same time, after homogenization, a disordered bridging structure is formed between the superabsorbent resin and the hydrogel, which enriches the diversity of channels in the polymer, not only enhances the air permeability and skin...
Embodiment 1
[0047] The preparation method of polymer absorption polymer, concrete steps are as follows:
[0048] (1) Acrylic acid is neutralized to 80% with a concentration of 30wt% sodium hydroxide at 0°C, and then 2-acrylamide-2-methylpropanesulfonic acid, diatomaceous earth and N,N- Methylbisacrylamide was stirred at room temperature for 30 minutes to obtain a mixed solution of acrylic acid;
[0049] (2) Disperse sodium carboxymethyl cellulose in 15 times the amount of water, stir in a water bath at 75°C for 45min, and then 2 Under protection, potassium persulfate of 2.5% by weight of sodium carboxymethylcellulose was added thereto, and after incubation for 10 minutes, acrylic acid mixed solution was added, and the reaction was incubated for 4.5 hours. The precipitate was taken out, soaked in methanol overnight, washed with ethanol, and Dry and pulverize at 85°C to obtain diatomaceous earth / sodium carboxymethyl cellulose superabsorbent resin. The weight ratio of sodium cellulose, acr...
Embodiment 2
[0053] The preparation method of polymer absorbent polymer, the difference between this embodiment and embodiment 1 is that: the cross-linking agent used in step 3) is hydrazine hydrate, aspartic acid and diethylaminoethanol, and the above-mentioned aspartic acid contains 92 wt% L-aspartic acid and 8 wt% D-aspartic acid.
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