Antiviral flame-retardant weather-resistant coating

Abstract

The invention discloses antiviral flame-retardant weather-resistant coating. The coating is characterized in that the coating comprises, by weight, 2 to 5 parts of epoxy hexamethylene tetramine salt,30-40 parts of a 4-propenylthiosemicarbazide / 1-allyl-3-methylimidazolium chloride / zeatin nucleoside / isobornyl acrylate copolymer, 5-8 parts of modified Ti-Cu-Hf-O, 1-3 parts of antiviral Chinese herbal medicine powder, 10-15 parts of an inorganic filler, 10-15 parts of a solvent, 1-3 parts of a dispersing agent and 0.5-1.5 parts of a defoaming agent. The invention also discloses a preparation method of the antiviral flame-retardant weather-resistant coating. The antiviral flame-retardant weather-resistant coating disclosed by the invention is excellent in comprehensive performance, remarkablein antiviral effect, good in weather resistance and flame resistance, high in bonding strength with a base material and long in service lifetime.

Description

Technical field

[0001] The invention relates to the technical field of coatings, in particular to an anti-virus, flame-retardant and weather-resistant coating and a preparation method thereof. Background technique

[0002] In recent years, the emergence of highly pathogenic viruses such as influenza virus and enterovirus and some bacteria that are highly resistant to common fungicides have made public places such as hospitals, schools and other crowded places extremely vulnerable to outbreaks. In places with sexual diseases, especially in public health facilities such as hospitals, the possibility of the emergence of viruses and germs is extremely high, which is harmful to public health. Especially with the extensive development of modern industry, the environmental air quality is poor, and the number of people who suffer from viral infections is huge each year. In the season of high incidence of viral infections, students are suspended due to the virus and workers are suspended ...

Examples

Embodiment 1

[0036] An anti-virus, flame-retardant and weather-resistant paint, which is composed of the following components in parts by weight: 2 parts of epoxy hexamethylenetetramine salt, 4-propenylthiosemicarbazide / 1-allyl-3-methyl Imidazole chloride / zeatin nucleoside / isobornyl acrylate copolymer 30 parts, modified Ti-Cu-Hf-O 5 parts, anti-viral Chinese herbal medicine powder 1 part, sepiolite powder 10 parts, cyclohexanone 10 parts, 1 part of sodium hexametaphosphate and 0.5 part of tributyl phosphate.

[0037] The preparation method of the epoxy hexamethylenetetramine salt includes the following steps: adding hexamethylenetetramine and epichlorohydrin to chloroform, then adding sodium hydroxide to it, and stirring at 60°C After reacting for 3 hours, the insoluble matter was removed by filtration, and the chloroform was removed by rotary evaporation to obtain epoxy hexamethylenetetramine salt; the molar ratio of the hexamethylenetetramine, epichlorohydrin, chloroform, and sodium hydroxi...

Embodiment 2

[0045] An anti-viral, flame-retardant and weather-resistant coating consisting of the following components in parts by weight: 3 parts of epoxy hexamethylenetetramine salt, 4-propenylthiosemicarbazide / 1-allyl-3-methyl 33 parts of chloroimidazole / zeatin nucleoside / isobornyl acrylate copolymer, 6 parts of modified Ti-Cu-Hf-O, 1.5 parts of anti-viral Chinese herbal medicine powder, 11 parts of light calcium carbonate, methyl isobutyl 11 parts of ketones, 1.5 parts of sodium polycarboxylate, 0.7 parts of defoamer Deqian 3100.

[0046] The preparation method of the epoxy hexamethylenetetramine salt includes the following steps: adding hexamethylenetetramine and epichlorohydrin to chloroform, then adding potassium hydroxide to it, and stirring at 62°C Reacted for 3.5 hours, then filtered to remove the insoluble matter, and then rotated to remove the chloroform to obtain epoxy hexamethylenetetramine salt; the molar ratio of the hexamethylenetetramine, epichlorohydrin, chloroform, and po...

Embodiment 3

[0054] An anti-virus, flame-retardant and weather-resistant paint, which is composed of the following components in parts by weight: 3.5 parts of epoxy hexamethylenetetramine salt, 4-propenyl thiosemicarbazide / 1-allyl-3-methyl Imidazole chloride / zeatin nucleoside / isobornyl acrylate copolymer 35 parts, modified Ti-Cu-Hf-O 6.5 parts, antiviral Chinese herbal medicine powder 2 parts, titanium dioxide 13 parts, N-methylpyrrolidone 13 parts , 2 parts of sodium hexametaphosphate, 1 part of defoamer BYK088.

[0055] The preparation method of the epoxy hexamethylenetetramine salt includes the following steps: adding hexamethylenetetramine and epichlorohydrin to chloroform, then adding sodium carbonate to it, and stirring and reacting at 65°C After 4 hours, filter to remove insoluble matter, and then rotate to remove chloroform to obtain epoxy hexamethylenetetramine salt; the molar ratio of hexamethylenetetramine, epichlorohydrin, chloroform, and sodium carbonate is 1 :4:18:1.

[0056] Th...

Technical field

[0001] The invention relates to the technical field of coatings, in particular to an anti-virus, flame-retardant and weather-resistant coating and a preparation method thereof. Background technique

[0002] In recent years, the emergence of highly pathogenic viruses such as influenza virus and enterovirus and some bacteria that are highly resistant to common fungicides have made public places such as hospitals, schools and other crowded places extremely vulnerable to outbreaks. In places with sexual diseases, especially in public health facilities such as hospitals, the possibility of the emergence of viruses and germs is extremely high, which is harmful to public health. Especially with the extensive development of modern industry, the environmental air quality is poor, and the number of people who suffer from viral infections is huge each year. In the season of high incidence of viral infections, students are suspended due to the virus and workers are suspended ...

Examples

Embodiment 1

[0036] An anti-virus, flame-retardant and weather-resistant paint, which is composed of the following components in parts by weight: 2 parts of epoxy hexamethylenetetramine salt, 4-propenylthiosemicarbazide / 1-allyl-3-methyl Imidazole chloride / zeatin nucleoside / isobornyl acrylate copolymer 30 parts, modified Ti-Cu-Hf-O 5 parts, anti-viral Chinese herbal medicine powder 1 part, sepiolite powder 10 parts, cyclohexanone 10 parts, 1 part of sodium hexametaphosphate and 0.5 part of tributyl phosphate.

[0037] The preparation method of the epoxy hexamethylenetetramine salt includes the following steps: adding hexamethylenetetramine and epichlorohydrin to chloroform, then adding sodium hydroxide to it, and stirring at 60°C After reacting for 3 hours, the insoluble matter was removed by filtration, and the chloroform was removed by rotary evaporation to obtain epoxy hexamethylenetetramine salt; the molar ratio of the hexamethylenetetramine, epichlorohydrin, chloroform, and sodium hydroxi...

Embodiment 2

[0045] An anti-viral, flame-retardant and weather-resistant coating consisting of the following components in parts by weight: 3 parts of epoxy hexamethylenetetramine salt, 4-propenylthiosemicarbazide / 1-allyl-3-methyl 33 parts of chloroimidazole / zeatin nucleoside / isobornyl acrylate copolymer, 6 parts of modified Ti-Cu-Hf-O, 1.5 parts of anti-viral Chinese herbal medicine powder, 11 parts of light calcium carbonate, methyl isobutyl 11 parts of ketones, 1.5 parts of sodium polycarboxylate, 0.7 parts of defoamer Deqian 3100.

[0046] The preparation method of the epoxy hexamethylenetetramine salt includes the following steps: adding hexamethylenetetramine and epichlorohydrin to chloroform, then adding potassium hydroxide to it, and stirring at 62°C Reacted for 3.5 hours, then filtered to remove the insoluble matter, and then rotated to remove the chloroform to obtain epoxy hexamethylenetetramine salt; the molar ratio of the hexamethylenetetramine, epichlorohydrin, chloroform, and po...

Embodiment 3

[0054] An anti-virus, flame-retardant and weather-resistant paint, which is composed of the following components in parts by weight: 3.5 parts of epoxy hexamethylenetetramine salt, 4-propenyl thiosemicarbazide / 1-allyl-3-methyl Imidazole chloride / zeatin nucleoside / isobornyl acrylate copolymer 35 parts, modified Ti-Cu-Hf-O 6.5 parts, antiviral Chinese herbal medicine powder 2 parts, titanium dioxide 13 parts, N-methylpyrrolidone 13 parts , 2 parts of sodium hexametaphosphate, 1 part of defoamer BYK088.

[0055] The preparation method of the epoxy hexamethylenetetramine salt includes the following steps: adding hexamethylenetetramine and epichlorohydrin to chloroform, then adding sodium carbonate to it, and stirring and reacting at 65°C After 4 hours, filter to remove insoluble matter, and then rotate to remove chloroform to obtain epoxy hexamethylenetetramine salt; the molar ratio of hexamethylenetetramine, epichlorohydrin, chloroform, and sodium carbonate is 1 :4:18:1.

[0056] Th...