The invention belongs to the technical field of coatings, and particularly relates to a low-temperature
extinction transparent
polyester resin composition as well as a preparation method and application thereof. The
polyester resin composition comprises carboxyl-terminated
polyester resin with a high
acid value and carboxyl-terminated
polyester resin with a low
acid value, the high-acid-value carboxyl-terminated
polyester resin is prepared from the following
raw material components: dihydric
alcohol A, polyhydric
alcohol,
nitrogen-containing dihydric
alcohol, polyatomic acid A, an acidolysis agent A and an esterification catalyst, the low-acid-value carboxyl-terminated
polyester resin is prepared from the following
raw material components: dihydric alcohol B,
nitrogen-containing dihydric alcohol, polyacid B, an acidolysis agent B and an esterification catalyst, the
polyol does not include a
diol. After the carboxyl-terminated polyester resin with the high
acid value and the low acid value is applied to a
powder coating, the
powder coating can have
extinction and low-temperature curing (140-160 DEG C curing) performance at the same time and has good spraying powdering rate, and an obtained
coating is low in gloss (lower than 40 GU), high in transparency and excellent in
impact resistance.