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Method for preparing amphiprotic starch solution for papermaking

A technology of amphoteric starch and solution, which is applied in the direction of papermaking, textiles, papermaking, paper, etc., can solve the problems of long production time, gelation, inconvenient use, etc., and achieve less production time, enhanced burst resistance and ring pressure strength , Solve the effect of aging and retrograde

Active Publication Date: 2013-01-30
GUANGDONG PAPER IND RES INST
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, amphoteric starch needs to be heated and gelatinized before use, and the production time is longer (more than 4 hours), and it is prone to gelation when stored in solution at a higher concentration, which is inconvenient to use

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0008] Add 10g of sodium hydroxide and 50g of sodium hypochlorite solution (9% available chlorine) to 1000g of water, stir evenly until no insoluble matter exists, add 200g of tapioca starch while stirring, and obtain starch milk after stirring evenly, heat to 95°C, heat-preserve and gelatinize After 10 minutes, 20 g of 3-chloro-2-hydroxypropyltrimethylammonium chloride solution (concentration: 50 wt %) was added, and the reaction was continued at 95° C. for 60 minutes, and finally cooled to obtain the amphoteric starch solution.

Embodiment 2

[0010] Add 30g of sodium hydroxide and 10g of potassium persulfate to 1000g of water, stir well until there is no insoluble matter, add 150g of potato starch while stirring, and obtain starch milk after stirring evenly, heat to 80°C, keep warm and gelatinize for 20 minutes, then add 20g of 3-chloro-2-hydroxypropyltrimethylammonium chloride solution (concentration: 50wt%), continued to react at 80°C for 30 minutes, and finally cooled to obtain the amphoteric starch solution.

Embodiment 3

[0012] Add 10g of sodium hydroxide and 40g of sodium hypochlorite solution (9% available chlorine) to 1000g of water, stir evenly until no insoluble matter exists, add 200g of tapioca starch while stirring, and obtain starch milk after stirring evenly, heat to 70°C, heat-preserve and gelatinize After 30 minutes, 20 g of 3-chloro-2-hydroxypropyltrimethylammonium chloride solution (concentration: 50 wt %) was added, and the reaction was continued at 70° C. for 60 minutes, and finally cooled to obtain an amphoteric starch solution.

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PUM

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Abstract

The invention provides a method for preparing amphiprotic starch solution for papermaking, which belongs to the field of fine chemicals for papermaking. The amphiprotic starch solution is added at a papermaking wet end, and has a dry strengthening effect on paper. Starch is used as the basic material, water, sodium hydroxide, sodium hypochlorite or potassium persulfate and cationic etherifying agent are added. The amphiprotic starch solution is obtained after the aqueous solution is heated. The preparation method is fulfilled by the heating reaction of aqueous solution. The amphiprotic starch solution has high concentration, can be diluted by cold water to any concentration and cannot be aged, so the technical problem of starch aging is solved. When in use, the amphiprotic starch solution can be added at the wet end without being heated to gelatinize, the amphiprotic starch solution as dry-strengthening agent for papermaking can notably increase the dry strength indexes of paper, such as burst index and ring crush index, and under the circumstance of the same added amount, the amphiprotic starch solution has a better effect than the like product. The innovation of the invention is that a simple technique for producing the amphiprotic starch solution is provided, the production time is not longer than 2 hours, the aging and retrograding problems of the amphiprotic starch are solved, and the invented amphiprotic starch solution can be directly added at the papermaking wet end without going through the step of gelatinization by heating.

Description

Technical field: [0001] The invention relates to a preparation method of an amphoteric starch solution for papermaking, belonging to the field of papermaking fine chemicals. Background technique: [0002] Starch, the storage form of carbohydrates in green plants, is an important renewable and biodegradable natural resource with very important practical applications in the paper industry and other industries. Native starch produced from cereal and tuber crops is widely used in many industries. With the development of the paper industry, starch products are increasingly required to have specific functions, such as better film-forming properties, freeze-thaw stability, cold water solubility, shear resistance, aging resistance, salt resistance, etc. Starch molecules have many hydroxyl groups and are highly hydrophilic, but starch granules are insoluble in water. Even after fully gelatinizing, the starch paste solution will quickly undergo aging and retrogradation. This is becau...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L3/04C08L3/08C08L3/10C08B31/00C08B31/12C08B31/18D21H17/28
Inventor 钟广泉许桂红江锋李倩钰
Owner GUANGDONG PAPER IND RES INST
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