Rubber laminates, run-flat tires and pneumatic tires
A rubber layer and rubber technology, used in pneumatic tires, rubber layered products, special tires, etc., can solve the problem of insufficient adhesion of the coloring layer to the pollution resistance of the coloring layer and the adjacent rubber, and achieve excellent run-flat durability. The effect of high adhesion, high adhesion, and excellent stain resistance
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Embodiment 1 to 10、 comparative example 1 to 6
[0095] The rubber composition for the side reinforcing rubber layer was prepared based on the formulation shown in Table 1. In addition, the rubber composition for an inner liner was prepared based on the formulation shown in Table 2. The air permeability coefficient of the rubber composition thus prepared was measured according to the following method. Table 2 shows the results.
[0096] (1) Air permeability coefficient
[0097] The air permeability coefficient at 60° C. of a sample obtained by vulcanizing the rubber composition at 160° C. for 30 minutes was measured by using an air permeability tester M-C1 (manufactured by TOYOSEIKI Co., Ltd.).
[0098] [Table 1]
[0099] Rubber composition for side reinforcing rubber layer
[0100]
[0101] *1 Polybutadiene rubber, "BR01" manufactured by JSR Corporation
[0102] *2 "N550" manufactured by Asahi Carbon Co., Ltd.
[0103] *3N-(1,3-Dimethyl-butyl)-N'-phenyl-p-phenylenediamine, "Nocrac6C" manufactured by Ouchi Shinko ...
Embodiment 11 to 17、 comparative example 7 to 11
[0128] The components shown in Table 5 other than the vulcanization and vulcanization accelerator were mixed and kneaded at about 130° C. for 3.0 minutes using a kneader. Then, sulfur and a vulcanization accelerator were added, and the components were mixed and kneaded for an additional 2.0 minutes at about 100° C. using biaxial open rolls, and taken out as a sheet of predetermined thickness including a barrier layer and a rubber layer. Sample sheets for Examples and Comparative Examples were prepared from the sheets.
[0129] (evaluate)
[0130] (1) Pollution resistance
[0131] The rubber laminates each including the samples prepared for the respective examples and comparative examples between the stained rubber containing a certain amount of pollutants and the white rubber were vulcanized, and the thus vulcanized laminates were placed in a constant temperature bath at 100° C. Before and after 48 hours, the stain resistance was evaluated by measuring the color difference o...
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