Polyamide composition
A technology of composition and weighing, applied in the direction of household components, applications, household appliances, etc., can solve the problems of moisture ingress, reducing stress tolerance, etc.
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[0054] Numerous procedures have become known for the preparation of polyamides, in which different monomer units are used depending on the desired end product, different chain transfer agents are used to build up the desired molecular weight, or else there is a chain transfer agent for the intended subsequent work-up. The monomer of the reactive group.
[0055] The industrially relevant processes for producing polyamides are generally carried out by polycondensation in the molten state. In the context of the present invention, the hydrolytic polymerization of lactams is also considered polycondensation.
[0056] The PA 6 and PA 66 used as component A) are semicrystalline polyamides. According to DE 10 2011 084 519 A1, semicrystalline polyamides have an enthalpy of fusion measured by the DSC method according to ISO 11357 in the second heating operation and integrating the melting peak in the range from 4 to 25 J / g. In contrast, amorphous polyamides have an enthalpy of fusion ...
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[0258] In order to demonstrate the improvement of the properties described according to the invention, corresponding polymer compositions were first prepared by compounding. For this purpose, the individual components according to Table 2 were mixed in a twin-screw extruder (ZSK 25 mixer, from Coperion Werner & Pfleiderer (Coperion Werner & Pfleiderer) (Stuttgart, Germany) at a temperature between 240°C and 280°C, discharged as one strand, cooled until granulatable and granulated. After drying (usually at 70°C in a vacuum oven for two days), the pellets were processed at temperatures ranging from 240°C to 280°C to obtain standard test samples for corresponding tests.
[0259] Glow wire stability was determined using the GWFI (Glow Wire Flammability Index) glow wire test according to IEC 60695-2-12 using a round blank with a diameter of 80 mm and a thickness of 0.75 mm.
[0260] Izod impact resistance is determined according to ISO 180-1U on new injection molded test specimens...
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