The invention belongs to the technical field of
chemical engineering separation, and provides a natural eutectic
solvent and a preparation method and application thereof, the natural eutectic
solvent comprises the following components:
caprolactam,
citric acid and water; wherein the
molar ratio of
caprolactam to
citric acid is (1-4): (1-2); the
mass of the water is 20-40% of the sum of the
mass of the
caprolactam and the
mass of the
citric acid. By introducing water as a third component, the
viscosity of the
system is effectively reduced, the
mass transfer performance is improved, and the
denitrification efficiency is improved. The eutecticevaporate
solvent provided by the invention can provide more reaction sites, has relatively strong removal capacity and selectivity on nitrogenous organic matters, and can realize efficient
denitrification under mild conditions. The natural deep-eutectic solvent prepared by the preparation method disclosed by the invention is applied to removal of basic nitrides of oil products, and has the advantages of short time consumption and low dosage, namely high removal efficiency.